Advertisement

From Metalloligand to Extended 3D Network: Synthesis, Crystal Structure and Magnetic Property of {[Cu(en)2][Cu(μ3-pydc)2]·6H2O} n

  • Fatih Semerci
  • Okan Zafer Yeşilel
  • Ertan Şahin
  • Yusuf Yerli
  • Ramazan Topkaya
Article

Abstract

A novel 2D coordination polymer, {[Cu(en)2][Cu(μ3-pydc)2]·6H2O} n (1) pyridine-2,3-dicarboxylic acid (pydcH2); ethylenediamine (en), based on the metalloligand [Cu(μ-pydcH)2] n , has been prepared and characterized by IR, UV–Vis and ESR spectroscopy, thermal analysis, differential scanning calorimetry and single crystal X-ray diffraction techniques. The temperature dependent magnetic properties have also been studied. The pydc ligand exhibits tetradentate-μ3 bridging mode, being coordinated through three carboxylate oxygens and one nitrogen atom. The complex contains two copper(II) ions that exhibit two different coordination environment with two en and two pydc ligands. The single crystal structure shows that the complex forms a 3D framework with 2D layers along the c-axis. Van der Waals interactions are responsible for the self-assembly of the layer into a 3D network.

Keywords

Pyridine-2,3-dicarboxylate complex Copper Coordination polymer Magnetic properties Metalloligand approach 

Notes

Acknowledgment

This work has been supported by The Scientific and Technological Research Council of Turkey (TUBITAK, No: 109T201).

References

  1. 1.
    Z. He, C. He, E. Gao, Z. Wang, X. Yang, C. Liao, C. Yan, Inorg. Chem. 42, 2206 (2003)CrossRefGoogle Scholar
  2. 2.
    S. Decurtins, M. Gross, H. Schmalle, S. Ferlay, Inorg. Chem. 37, 2443 (1998)CrossRefGoogle Scholar
  3. 3.
    O. Evans, W. Lin, Chem. Mater. 13, 3009 (2001)CrossRefGoogle Scholar
  4. 4.
    O. Evans, W. Lin, Acc. Chem. Res. 35, 511 (2002)CrossRefGoogle Scholar
  5. 5.
    B. Kesanli, W. Lin, Coord. Chem. Rev. 246, 305 (2003)CrossRefGoogle Scholar
  6. 6.
    J. Ma, J. Yang, G. Zheng, L. Li, J. Liu, Inorg. Chem. 42, 7531 (2003)CrossRefGoogle Scholar
  7. 7.
    O. Yaghi, M. O’Keeffe, N. Ockwig, H. Chae, M. Eddaoudi, J. Kim, Nature 423, 705 (2003)CrossRefGoogle Scholar
  8. 8.
    L. Han, M. Hong, Inorg. Chem. Commun. 8, 406 (2005)CrossRefGoogle Scholar
  9. 9.
    L. Wen, Z. Lu, J. Lin, Z. Tian, H. Zhu, Q. Meng, Cryst. Growth Des. 7, 93 (2007)CrossRefGoogle Scholar
  10. 10.
    C. Xia, C. Lu, D. Yuan, Q. Zhang, X. Wu, J. Zhang, D. Wu, J. Mol. Struct. 831, 195 (2007)CrossRefGoogle Scholar
  11. 11.
    Y. Qi, F. Luo, Y. Che, J. Zheng, Cryst. Growth Des. 8, 606 (2008)CrossRefGoogle Scholar
  12. 12.
    J. Seo, R. Matsuda, H. Sakamoto, C. Bonneau, S. Kitagawa, J. Am. Chem. Soc. 131, 12792 (2009)CrossRefGoogle Scholar
  13. 13.
    C. Janiak, Dalton Trans. 14, 2781 (2003)CrossRefGoogle Scholar
  14. 14.
    C.J. Oconnor, Prog. Inorg. Chem. 29, 203 (1982)CrossRefGoogle Scholar
  15. 15.
    O. Kahn, Acc. Chem. Res. 33, 647 (2000)CrossRefGoogle Scholar
  16. 16.
    S. Batten, K. Murray, Coord. Chem. Rev. 246, 103 (2003)CrossRefGoogle Scholar
  17. 17.
    D. Maspoch, D. Ruiz-Molina, J. Veciana, J Mater Chem 14, 2713 (2004)CrossRefGoogle Scholar
  18. 18.
    X. Li, L. Zhu, D. Liao, Inorg. Chim. Acta 18, 42 (2010)Google Scholar
  19. 19.
    F. Terenziani, A. Painelli, Phys Rev B 68, 165405 (2003)CrossRefGoogle Scholar
  20. 20.
    K. Youm, M. Kim, J. Ko, M. Jun, Polyhedron 26, 929 (2007)CrossRefGoogle Scholar
  21. 21.
    P. Teo, L. Koh, T. Hor, Chem. Commun. 2007, 2225 (2007)CrossRefGoogle Scholar
  22. 22.
    G. Wang, Z. Li, H. Jia, N. Hu, J. Xu, Acta Cryst. E65, m1568 (2009)Google Scholar
  23. 23.
    G. Wang, Z. Li, H. Jia, N. Hu, J. Xu, Acta Cryst. E65, m333 (2009)Google Scholar
  24. 24.
    Y. Sun, Y. Kim, S. Zhang, J. Am. Chem. Soc. 129, 12606 (2007)CrossRefGoogle Scholar
  25. 25.
    S. Noro, H. Miyasaka, S. Kitagawa, T. Wada, T. Okubo, M. Yamashita, T. Mitani, Inorg. Chem. 44, 133 (2005)CrossRefGoogle Scholar
  26. 26.
    K. Youm, S. Huh, Y. Park, S. Park, M. Choi, M. Jun, Chem. Commun. 21, 2384 (2004)CrossRefGoogle Scholar
  27. 27.
    K. Gurunatha, T. Maji, Eur. J. Inorg. Chem. 12, 1592 (2009)CrossRefGoogle Scholar
  28. 28.
    M. Fuentealba, A. Trujillo, J. Hamon, D. Carrillo, C. Manzur, J. Mol. Struct. 76, 881 (2008)Google Scholar
  29. 29.
    S. Halper, L. Do, J. Stork, S. Cohen, J. Am. Chem. Soc. 128, 15255 (2006)CrossRefGoogle Scholar
  30. 30.
    V. Vreshch, A. Chernega, J. Howard, J. Sieler, K. Domasevitch, Dalton Trans. 9, 1707 (2003)CrossRefGoogle Scholar
  31. 31.
    J.Q. Liu, Y.N. Zhang, Y.Y. Wang, J.C. Jin, E.K. Lermontova, Q.Z. Shi, Dalton Trans. 27, 5365 (2009)CrossRefGoogle Scholar
  32. 32.
    B.L. An, J.Q. Ye, M.L. Gong, X.H. Yin, Y.S. Yang, X.G. Zheng, S.Z. Deng, N.Z. Xu, Mater. Res. Bull. 36, 1335 (2001)CrossRefGoogle Scholar
  33. 33.
    Y.B. Xie, Q. Gao, C.Y. Zhang, J.H. Sun, J. Solid State Chem. 182, 1761 (2009)CrossRefGoogle Scholar
  34. 34.
    Q. Gao, F.L. Jiang, M.Y. Wu, Y.G. Huang, D.Q. Yuan, W. Wei, M.C. Hong, CrystEngComm. 11, 918 (2009)CrossRefGoogle Scholar
  35. 35.
    S.M. Humphrey, G.F. Weldon, P.T. Wood, J. Nanosci. Nanotechnol. 10, 34 (2010)CrossRefGoogle Scholar
  36. 36.
    M. Li, J. Xiang, L. Yuan, S. Wu, S. Chen, J. Sun, Cryst. Growth Des. 6, 2036 (2006)CrossRefGoogle Scholar
  37. 37.
    Z. Yu, G. Li, Y. Jiang, J. Xu, J. Chen, Dalton Trans. 22, 4219 (2003)CrossRefGoogle Scholar
  38. 38.
    L. Wen, Y. Li, Z. Lu, J. Lin, C. Duan, Q. Meng, Cryst. Growth Des. 6, 530 (2006)CrossRefGoogle Scholar
  39. 39.
    Y. Zhou, X. Shen, C. Du, B. Wu, H. Zhang, Eur. J. Inorg. Chem. 27, 4280 (2008)CrossRefGoogle Scholar
  40. 40.
    M. Frisch, C.L. Cahill, Dalton Trans. 39, 4679 (2006)CrossRefGoogle Scholar
  41. 41.
    M. Frisch, C. Cahill, Cryst. Growth Des. 8, 2921 (2008)CrossRefGoogle Scholar
  42. 42.
    Q. Yue, J. Yang, G. Li, G. Li, W. Xu, J. Chen, S. Wang, Inorg. Chem. 44, 5241 (2005)CrossRefGoogle Scholar
  43. 43.
    J.D. Wang, S.M. Han, Acta Cryst. E66, M206 (2010)Google Scholar
  44. 44.
    T. Suga, N. Okabe, Acta Cryst. C52, 1410 (1996)Google Scholar
  45. 45.
    B.O. Patrick, C.L. Stevens, A. Storr, R.C. Thompson, Polyhedron 22, 3025 (2003)CrossRefGoogle Scholar
  46. 46.
    A. Robin, K. Fromm, Coord. Chem. Rev. 250, 2127 (2006)CrossRefGoogle Scholar
  47. 47.
    L.J. Hao, C.H. Mu, B.B. Kong, Acta Cryst. E64, M1229 (2008)Google Scholar
  48. 48.
    S. Shit, J. Chakraborty, S. Sen, G. Pilet, C. Desplanches, S. Mitra, J. Mol. Struct. 19, 891 (2008)Google Scholar
  49. 49.
    D.R. Turner, S.R. Batten, Acta Cryst. E63, M452 (2007)Google Scholar
  50. 50.
    T.K. Maji, G. Mostafa, R. Matsuda, S. Kitagawa, J. Am. Chem. Soc. 127, 17152 (2005)CrossRefGoogle Scholar
  51. 51.
    H. Yin, S.X. Liu, J. Mol. Struct. 918, 165 (2009)CrossRefGoogle Scholar
  52. 52.
    J.F. Xiang, M. Li, S.M. Wu, L.J. Yuan, J.T. Sun, Acta Cryst. E62, M1122 (2006)Google Scholar
  53. 53.
    S. Martinez-Vargas, R.A. Toscano, J. Valdes-Martinez, Acta Cryst. E63, M1975 (2007)Google Scholar
  54. 54.
    H. Aghabozorg, R. Khadivi, M. Ghadermazi, H. Pasdar, S. Hooshmand, Acta Cryst. E64, M267 (2008)Google Scholar
  55. 55.
    E.E. Sileo, D. Vega, R. Baggio, M.T. Garland, M.A. Blesa, Aust. J. Chem. 52, 205 (1999)CrossRefGoogle Scholar
  56. 56.
    F. Semerci, O. Yeşilel, E. Şahin, J. Inorg. Organomet. Polym. 20, 334 (2010)CrossRefGoogle Scholar
  57. 57.
    A. Çolak, D. Akduman, O. Yesilel, O. Büyükgüngör, Z. Kristallogr. 224, 207 (2009)CrossRefGoogle Scholar
  58. 58.
    A. Çolak, D. Akduman, O. Yesilel, O. Büyükgüngör, Transit. Metal Chem. 34, 861 (2009)CrossRefGoogle Scholar
  59. 59.
    A.T. Colak, O.Z. Yesilel, O. Buyukgungor, J. Inorg. Organomet. Polym. 20, 26 (2010)CrossRefGoogle Scholar
  60. 60.
    A. Çolak, F. Çolak, O. Yesilel, D. Akduman, F. Yılmaz, M. Tümer, Inorg. Chim. Acta 363, 2149 (2010)CrossRefGoogle Scholar
  61. 61.
    A. Çolak, O. Yeşilel, T. Hökelek, E. Şahin, Struct. Chem. 19, 285 (2008)CrossRefGoogle Scholar
  62. 62.
    O. Yesilel, I. Ilker, M. Refat, H. Ishida (Polyhedron, 2010 in press)Google Scholar
  63. 63.
    A. Çolak, F. Çolak, O. Yesilel, O. Büyükgüngör, J. Mol. Struct. 67, 936 (2009)Google Scholar
  64. 64.
    A.T. Colak, F. Colak, O.Z. Yesilel, O. Buyukgungor, J. Coord. Chem. 62, 1650 (2009)CrossRefGoogle Scholar
  65. 65.
    O. Yesilel, A. Mutlu, O. Büyükgüngör, Polyhedron 28, 437 (2009)CrossRefGoogle Scholar
  66. 66.
    O. Yesilel, A. Mutlu, O. Büyükgüngör, Polyhedron 27, 2471 (2008)CrossRefGoogle Scholar
  67. 67.
    O. Yesilel, A. Mutlu, C. Darcan, O. Büyükgüngör, J. Mol. Struct. 39, 964 (2009)Google Scholar
  68. 68.
    O. Yesilel, I. Ilker, O. Büyükgüngör, Polyhedron 28, 3010 (2009)CrossRefGoogle Scholar
  69. 69.
    O. Yesilel, O. Büyükgüngör, Solid State Sci. 9, 485 (2007)CrossRefGoogle Scholar
  70. 70.
    O. Yesilel, M. Soylu, H. Ölmez, O. Büyükgüngör, Polyhedron 25, 2985 (2006)CrossRefGoogle Scholar
  71. 71.
    O. Yesilel, H. Pasaoglu, K. Akdag, O. Büyükgüngör, Polyhedron 26, 2761 (2007)CrossRefGoogle Scholar
  72. 72.
    M. Soylu, O. Yesilel, B. Karabulut, O. Büyükgüngör, Polyhedron 28, 2487 (2009)CrossRefGoogle Scholar
  73. 73.
    H. Erer, O. Yesilel, C. Darcan, O. Büyükgüngör, Polyhedron 28, 3087 (2009)CrossRefGoogle Scholar
  74. 74.
    O. Yesilel, H. Olmez, H. Icbudak, J. Therm. Anal. Cal. 89, 555 (2007)CrossRefGoogle Scholar
  75. 75.
    O. Yesilel, G. Kastas, B. Orhan, Inorg. Chem. Commun. 10, 936 (2007)CrossRefGoogle Scholar
  76. 76.
    D. Harris, M. Bertolucci, Symmetry and spectroscopy: an introduction to vibrational and electronic spectroscopy. (Dover Publication, New York, 1989)Google Scholar
  77. 77.
    K. Nakamoto, Infrared and Raman spectra of ınorganic and coordination compounds, 5th edn. (Wiley-Interscience, New York, 1997)Google Scholar
  78. 78.
    R. Dudley, B. Hathaway, J. Chem. Soc. A Inorg. Phys. Theor. 1970, 2799 (1970)CrossRefGoogle Scholar
  79. 79.
    E. Di Mauro, S. Mara Domiciano, J. Phys. Chem. Solids 60, 1849 (1999)CrossRefGoogle Scholar
  80. 80.
    Y. Yerli, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 66, 1288 (2007)CrossRefGoogle Scholar
  81. 81.
    S. Blundell, D. Thouless, Magnetism in condensed matter (Oxford University Press, Oxford, 2001)Google Scholar
  82. 82.
    B. Hathaway, D. Billing, Coord. Chem. Rev. 5, 143 (1970)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, LLC 2011

Authors and Affiliations

  • Fatih Semerci
    • 1
    • 2
  • Okan Zafer Yeşilel
    • 1
  • Ertan Şahin
    • 3
  • Yusuf Yerli
    • 4
  • Ramazan Topkaya
    • 4
  1. 1.Faculty of Arts and Sciences, Department of ChemistryEskişehir Osmangazi UniversityEskişehirTurkey
  2. 2.Faculty of Arts and Sciences, Department of ChemistryKırklareli UniversityKırklareliTurkey
  3. 3.Faculty of Arts and Sciences, Department of ChemistryAtatürk UniversityErzurumTurkey
  4. 4.Department of PhysicsGebze Institute of TechnologyGebzeTurkey

Personalised recommendations