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A Novel 3D Photoactive Coordination Polymer with Alternate Cd(H2O)2+ and Mg(Hen)3+ Units and Sandwich-Shaped Cluster Linkages

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Abstract

A novel organic–inorganic hybrid, cadmium(II)-magnesium(II)-molybdenum(V) phosphate, {Cd[(PO4)2(HPO4)2Mo6O11(OH)4]2}[Cd(H2O)]2[Mg(Hen)]2{Cd[(PO4)3(HPO4)Mo6O10(OH)3Cl2]2}·(H2en)4·(Hen)2·(en)2·9H2O (en = ethylenediamine), was prepared under hydrothermal conditions and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, elemental analysis, inductively coupled plasma (ICP) analysis, thermogravimetric analysis, fluorescence, FT-IR and bond valence sum calculations. As revealed by single-crystal X-ray diffraction studies, the sandwich-shaped clusters of [Cd(Mo6P4)2] are interconnected by additional [Mg(Hen)] units and [Cd(H2O)] fragments to form an extended three-dimensional supramolecular framework with channels occupied by ethylenediamine molecules, protonated ethylenediamine cations and water molecules. Luminescent measurement of the title compound exhibits intensive blue and greenish-blue radiation emission upon excitation with ultraviolet light.

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Acknowledgment

Financial support from the Key Subject (Laboratory) Research Foundation of Shandong Province is gratefully acknowledged.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, University of Jinan, No. 106, Jiwei Road, 250022, Jinan, Shandong, People’s Republic of China

    Qi-Bing Bo, Dong Ma & Guo-Xin Sun

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  1. Qi-Bing Bo
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  2. Dong Ma
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  3. Guo-Xin Sun
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Correspondence to Qi-Bing Bo.

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Bo, QB., Ma, D. & Sun, GX. A Novel 3D Photoactive Coordination Polymer with Alternate Cd(H2O)2+ and Mg(Hen)3+ Units and Sandwich-Shaped Cluster Linkages. J Inorg Organomet Polym 20, 53–60 (2010). https://doi.org/10.1007/s10904-009-9318-0

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  • DOI: https://doi.org/10.1007/s10904-009-9318-0

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