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Synthesis, Spectroscopic Characterization and Structures of Tributyltin(IV) 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoates. Toxicity Studies on the Second Larval Instar of the Anopheles stephensi Mosquito Larvae

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Abstract

A series of tributyltin(IV) complexes of 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoates have been investigated by 1H, 13C, 119Sn NMR, IR and 119Sn Mössbauer spectroscopic techniques in combination with elemental analyses. Single crystal X-ray crystallography of Bu3Sn[O2CC6H4{N=C(H)C6H3-2-OH(N=NC6H4CH3-4)}-p] reveals a distorted tetrahedral structure which is further supported by 119Sn Mössbauer data. Toxicity studies of the tributyltin(IV) complexes along with their ligands 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoic acids on the second larval instar of the Anopheles stephensi mosquito larvae are also reported.

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Acknowledgments

The financial support of the Department of Science & Technology, New Delhi, India (Grant No. SR/S1/IC-03/2005, TSBB) and National Institute of Health Minority Biomedical Research Support Program (MBRS/SCORE, GM08005, GE) are gratefully acknowledged. ER is indebted to the Università di Palermo, Italy for financial support. Authors are grateful to the Laboratory of Malaria and Vector Research of the National Institutes of Health for supplying the mosquito larvae.

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Authors and Affiliations

  1. Department of Chemistry, North-Eastern Hill University, NEHU Permanent Campus, Umshing, Shillong, 793-022, India

    Tushar S. Basu Baul & Pradip Das

  2. Dipartimento di Chimica Inorganica e Analitica “Stanislao Cannizzaro” Università degli Studi di Palermo, Viale delle Scienze, Parco D’Orleans II, Edificio 17, 90128, Palermo, Italy

    Eleonora Rivarola

  3. Department of Chemistry and Physics, University of the District of Columbia, Washington, DC, 20008, USA

    Xueqing Song & George Eng

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  1. Tushar S. Basu Baul
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Correspondence to Tushar S. Basu Baul.

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Basu Baul, T.S., Das, P., Rivarola, E. et al. Synthesis, Spectroscopic Characterization and Structures of Tributyltin(IV) 4-[((E)-1-{2-hydroxy-5-[(E)-2-(aryl)-1-diazenyl]phenyl}methylidene)amino]benzoates. Toxicity Studies on the Second Larval Instar of the Anopheles stephensi Mosquito Larvae. J Inorg Organomet Polym 20, 61–68 (2010). https://doi.org/10.1007/s10904-009-9308-2

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