The First Organometallic Version of Polyaniline in its Emaraldine Form
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The reaction of bis(para-ethynylbenzene)-2,3,5,6-tetramethoxyquinone diimine and bis(para-ethynylbenzene)-2,3,5,6-tetramethoxyquinone diamine and trans-Pt(PEt3)2Cl2 in a 1:1:2 ratio in the presence of CuI and iPrNH2 generates the polydispersed material poly(bis(para-ethynylbenzene)-2,3,5,6-tetramethoxy-quinone diimine)-trans-bis(triethyl-phosphine)platinum(II)-(bis(para-ethynylbenzene)-2,3,5, 6-tetramethoxyquinone diamine)-trans-bis(triethylphosphine)platinum(II). Based on the luminescence decay traces, the distribution of the diimine and diamine residues is statistic.
KeywordsPolyaniline Luminescence Emaraldine Platinum Organometallic
This work was supported by the Natural Science and Engineering Research Council of Canada (NSERC). The Egyptian government and the Egyptian Cultural Bureau in Montreal are also acknowledged for the scholarship offered to Shawkat M. Aly.