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Synthesis and Characterization of Nanostructure BPO4

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Abstract

Boron phosphate (BPO4) is a well known catalyst for a range of organic chemical reactions. In this paper, we report the preparations and characterizations of nano-sized BPO4 and nano-BPO4-based core-shell spheres. The samples were synthesized hydrothermally using H3BO3, H3PO4 and short chain n-alkylamines (n = 3, 4) as starting materials. The resulting products were characterized by powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scan electron microscopy (SEM) and transmission electron microscopy (TEM), respectively. A possible mechanism for the formation of the materials is also discussed.

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Acknowledgements

This work was supported by the Major Basic Research Programs of Shanghai (No. 07DJ14001) and State ‘973’ project (2007CB936704), the Hundred Talents Program from the Chinese Academy of Sciences and fund for Young Leading Researchers from Shanghai municipal government.

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Authors and Affiliations

  1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, People’s Republic of China

    Shuang Chen, Hao-Hong Chen, Xin-Xin Yang & Jing-Tai Zhao

  2. Graduate School of Chinese Academy of Sciences, Beijing, People’s Republic of China

    Shuang Chen & Ming Ye

  3. Single Molecule Detecting and Manipulating Lab, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, People’s Republic of China

    Ming Ye

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  1. Shuang Chen
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  2. Ming Ye
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  3. Hao-Hong Chen
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  4. Xin-Xin Yang
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Correspondence to Jing-Tai Zhao.

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Chen, S., Ye, M., Chen, HH. et al. Synthesis and Characterization of Nanostructure BPO4 . J Inorg Organomet Polym 19, 139–142 (2009). https://doi.org/10.1007/s10904-008-9245-5

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  • DOI: https://doi.org/10.1007/s10904-008-9245-5

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