Skip to main content
SpringerLink
Log in

Syntheses and Crystal Structures of Two Inorganic–Organic Hybrid Frameworks Constructed from Pyridine-2,5-Dicarboxylic Acid

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

Two novel inorganic–organic hybrid frameworks of [Co(2,5-pydc)(4,4′-bipyo)0.5(H2O)3 · 3H2O] n (1) and [Cu1.5Gd(2,5-pydc)3(2,2′-bipyo)(H2O)4 · 2H2O] n (2) (2,5-pydc = pyridine-2,5-dicarboxylic acid; 4,4′-bipyo = 4,4′-bipyridine-N,N′-dioxide; 2,2′-bipyo = 2,2′-bipyridine-N,N′-dioxide) were prepared. Both compounds have been characterized by the elemental analyses, IR spectra, TG analysis and the single crystal diffraction. The salient structural feature for both compounds 1 and 2 is that the 1D chain and the mononuclear fragment are connected by strong hydrogen bond interactions to form 2D structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. C. Janiak, Angew. Chem. Int. Ed. 36, 1431 (1997)

    Article  CAS  Google Scholar 

  2. S.R. Batten, R. Robson, Angew. Chem. Int. Ed. 37, 1461 (1998)

    Article  CAS  Google Scholar 

  3. B. Moulton, M.J. Zaworotko, Chem. Rev. 101, 1629 (2001)

    Article  CAS  Google Scholar 

  4. C. Janiak, Dalton Trans. 2781 (2003)

  5. L. Carlucci, G. Ciani, D.M. Proserpio, Coord. Chem. Rev. 246, 247 (2003)

    Article  CAS  Google Scholar 

  6. L.L. Wen, D.B. Dang, C.Y. Duan, Y.Z. Li, Z.F. Tian, Q.J. Meng, Inorg. Chem. 44, 7161 (2005)

    Article  CAS  Google Scholar 

  7. L.L. Wen, Y.Z. Li, Z.D. Lu, J.G. Lin, C.Y. Duan, Q.J. Meng, Cryst. Growth Des. 6, 530 (2006)

    Article  CAS  Google Scholar 

  8. E.J. Jung, U.k Lee, B.K. Koo, Inorg. Chem. Acta 361, 2962 (2008)

    Article  CAS  Google Scholar 

  9. W.F. Yeung, W.L. Man, W.Y. Wong, T.C. Lau, S. Gao, Angew. Chem. Int. Ed. 40, 3031 (2001)

    Article  CAS  Google Scholar 

  10. K. Inoue, H. Imai, P.S. Ghalsasi, K. Kikuchi, M. Ohba, H. Okawa, J.V. Yakhmi, Angew. Chem. Int. Ed. 40, 4242 (2001)

    Article  CAS  Google Scholar 

  11. H. Li, M. Eddaoudi, M. O’Keeffe, O.M. Yaghi, Nature 402, 276 (1999)

    Article  CAS  Google Scholar 

  12. S.S.-Y. Chui, S.M.-F. Lo, J.P.H. Charmant, A.G. Orpen, I.D. Williams, Science 283, 1148 (1999)

    Article  CAS  Google Scholar 

  13. J. Kim, B. Chen, T.M. Reineke, H. Li, M. Eddaoudi, D.B. Moler, M. O’Keeffe, O.M. Yaghi, J. Am. Chem. Soc. 123, 8239 (2001)

    Article  CAS  Google Scholar 

  14. N.L. Rosi, J. Eckert, M. Eddaoudi, D.T. Vodak, J. Kim, M. O’Keeffe, O.M. Yaghi, Science 300, 1127 (2003)

    Article  CAS  Google Scholar 

  15. Z.Q. Wang, V. Ch. Kravtsov, M.J. Zaworotko, Angew. Chem. Int. Ed. 44, 2877 (2005)

  16. K. Barthelet, J. Marrot, D. Riou, G. Férey, Angew. Chem. Int. Ed. 41, 281 (2002)

    Article  CAS  Google Scholar 

  17. F. Millange, C. Serre, G. Férey, Chem. Commun. 822 (2002)

  18. D.N. Dybtsev, H. Chun, K. Kim, Angew. Chem. Int. Ed. 43, 5033 (2004)

    Article  CAS  Google Scholar 

  19. J.L. Song, C. Lei, J.G. Mao, Inorg. Chem. 43, 5630 (2004)

    Article  CAS  Google Scholar 

  20. Z.M. Sun, J.G. Mao, Y.Q. Sun, H.Y. Zeng, A. Clearfield, Inorg. Chem. 43, 336 (2004)

    Article  CAS  Google Scholar 

  21. L.L. Wen, Z.D. Lu, J.G. Lin, Z.F. Tian, H.Z. Zhu, Q.J. Meng, Cryst. Growth Des. 7, 93 (2007)

    Article  CAS  Google Scholar 

  22. Y. Liang, R. Cao, M. Hong, Q. Shi, D. Sun, J. Weng, Acta Crystallogr. Sect. E 57, m382 (2001)

    Article  Google Scholar 

  23. Y.C. Liang, M.C. Hong, R. Cao, Acta Crystallogr. Sect. E 57, m145 (2001)

    Article  Google Scholar 

  24. R.C. Zhang, C.H. Yu, Acta Crystallogr. Sect. E 62, m807 (2006)

    Article  Google Scholar 

  25. Q. Chao, X.L. Wang, E.B. Wang, Z.M. Su, Inorg. Chem. 44, 7122 (2005)

    Article  Google Scholar 

  26. D. Min, S.S. Yoon, D.Y. Jung, C.Y. Lee, Y. Kim, W.S. Han, S.W. Lee, Inorg. Chim. Acta 324, 293 (2001)

    Article  CAS  Google Scholar 

  27. R. Garcίa-Zarracino, H. Höpfl, Angew. Chem. Int. Ed. 43, 1507 (2004)

    Article  Google Scholar 

  28. S.M. Humphrey, P.T. Wood, J. Am. Chem. Soc. 126, 13236 (2004)

    Article  CAS  Google Scholar 

  29. Y.L. Liu, V.C. Kravtsov, D.A. Beauchamp, J.F. Eubank, M. Eddaoudi, J. Am. Chem. Soc. 127, 7266 (2005)

    Article  CAS  Google Scholar 

  30. Y.L. Wei, H.W. Hou, L.K. Li, Y.T. Fan, Y. Zhou, Cryst. Growth Des. 15, 1405 (2005)

    Article  Google Scholar 

  31. R.J. Hill, D.L. Long, M.S. Turvey, A.J. Blake, N.R. Champness, P. Hubberstey, C. Wilson, M. Schroder, Chem. Commun. 1792 (2004)

  32. B.Q. Ma, H.L. Sun, S. Gao, Chem. Commun. 2164 (2003)

  33. D.L. Long, A.J. Blake, N.R. Champness, C. Wilson, M. Schröder, Angew. Chem. Int. Ed. 40, 2443 (2001)

    Article  Google Scholar 

  34. I. Wolfle, J. Lodaya, B. Sauerwein, G.B. Schuster, J. Am. Chem. Soc. 114, 9304 (1992)

    Article  CAS  Google Scholar 

  35. P.G. Simpson, A. Vinciguerra, J.V. Quagliano, Inorg. Chem. 2, 282 (1963)

    Article  CAS  Google Scholar 

  36. G.M. Sheldrick, SHEXTL(Xprep, SADABS, XS, XL) Crystallographic Software Package Version 5.1 (Bruker-AXS, Madison, WI, 1998)

    Google Scholar 

  37. Y. Xu, L. Han, B.Y. Lou, M.C. Hong, Acta Crystallogr. Sect. E60, m585 (2004)

    CAS  Google Scholar 

  38. M. Eddaoudi, D.B. Moler, H. Li, B. Chen, T.M. Reineke, M. O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 34, 319 (2001)

    Article  CAS  Google Scholar 

  39. O.R. Evans, W. Lin, Acc. Chem. Res. 35, 511 (2002)

    Article  CAS  Google Scholar 

  40. Y.C. Liang, M.C. Hong, W.P. Su, R. Cao, W.J. Zhang, Inorg. Chem. 40, 4574 (2001)

    Article  CAS  Google Scholar 

  41. G.B. Deacon, R.J. Phillips, Coord. Chem. Rev. 33, 227 (1980)

    Article  CAS  Google Scholar 

  42. S.L. Ma, W.X. Zhu, G.H. Huang, D.Q. Yuan, X. Yan, J. Mol. Struct. 646, 89 (2003)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Nature Science Foundation of China (Nos. 20801021 and 20802022) and the Program for Chenguang Young Scientists of Wuhan (200850731361).

Author information

Authors and Affiliations

  1. Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan, 430079, People’s Republic of China

    Dong-E Wang, Feng Wang, Li-Li Wen & Dong-Feng Li

  2. College of Chemistry and Applied Chemistry, Huanggang Normal University, Huanggang, 438000, People’s Republic of China

    Zheng-Fang Tian

Authors
  1. Dong-E Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zheng-Fang Tian
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Feng Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Li-Li Wen
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Dong-Feng Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Li-Li Wen or Dong-Feng Li.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, DE., Tian, ZF., Wang, F. et al. Syntheses and Crystal Structures of Two Inorganic–Organic Hybrid Frameworks Constructed from Pyridine-2,5-Dicarboxylic Acid. J Inorg Organomet Polym 19, 196–201 (2009). https://doi.org/10.1007/s10904-008-9244-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-008-9244-6

Keywords

Search

Navigation