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Cobalt(ethylenediamine)sulfate: A Pillared Layered Coordination Polymer

Journal of Inorganic and Organometallic Polymers and Materials volume 18, pages 352–357 (2008)Cite this article

Abstract

A pillared-layered coordination polymer of formula Co(H2NCH2CH2NH2)SO4 (1) has been synthesized under solvothermal condition, and fully characterized. The three-dimensional structure of 1 is built up from cobalt sulfate sheets, each of which is composed of regularly alternating CoO4N2 octahedra and SO4 tetrahedra, with ethylenediamine pillars connecting the adjacent sheets. The coordinate covalent and hydrogen bonds have been revealed to exhibit an important role in the organization of the structure. The compound is found to be thermally stable up to, and above, 573 K and exhibits paramagnetic behavior at room temperature.

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Acknowledgments

The Thailand Research Fund and the Commission for Higher Education are acknowledged for financial support, the Department of Chemistry, Khon Kaen University, for access to the VSM magnetometer, and the Synchrotron Radiation Source, STFC CCLRC Daresbury Laboratory for access to microcrystal diffraction facilities. Additionally, S. Lauchan thanks the Commission for Higher Education and the Graduate School of Chiang Mai University for graduate scholarships.

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Authors and Affiliations

  1. Department of Physics, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand, ROC

    Sanchai Lauchan

  2. Department of Chemistry, University of Hull, Kingston upon Hull, HU6 7RX, UK

    Timothy J. Prior

  3. Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen, 40002, Thailand, ROC

    Santi Meansiri

  4. Inorganic Materials Research Unit, Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand, ROC

    Apinpus Rujiwatra

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  1. Sanchai Lauchan
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  2. Timothy J. Prior
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  3. Santi Meansiri
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  4. Apinpus Rujiwatra
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Correspondence to Apinpus Rujiwatra.

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Lauchan, S., Prior, T.J., Meansiri, S. et al. Cobalt(ethylenediamine)sulfate: A Pillared Layered Coordination Polymer. J Inorg Organomet Polym 18, 352–357 (2008). https://doi.org/10.1007/s10904-008-9208-x

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  • DOI: https://doi.org/10.1007/s10904-008-9208-x

Keywords

  • Cobalt
  • Sulfate
  • Pillaring
  • Crystal structure
  • Thermal properties
  • Magnetic properties