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Novel Assemblies of Sn(II) Coordinated Polyimide Supported by a Ligand Containing N-Heterocyclic Phenantroline Unit

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Abstract

The purpose of this work is to investigate the possibility of the production of novel metal coordinated polyimides. This research primarily focuses on novel metal complex assemblies of Sn(II) linked to the polymer molecule by a ligand containing an N-heterocyclic phenantroline unit in the main chain. Polyimide with phenantroline units in the main chain was synthesized utilizing condensation polymerization of aromatic dianhyrides and the bis(5-aminophenantroline)dichlorotin(II) to yield metal coordinated polyimides. Characterization by thermal analysis, refractive index, and dielectric analysis revealed distinct differences between these new materials and the classical polyimides.

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Authors and Affiliations

  1. Faculty of Science, Chemistry Department, Inonu University, Malatya, 44280, Turkey

    Süleyman Köytepe, Nevin Gürbüz, Ismail Özdemir & Turgay Seckin

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  1. Süleyman Köytepe
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  2. Nevin Gürbüz
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  3. Ismail Özdemir
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  4. Turgay Seckin
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Correspondence to Turgay Seckin.

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Köytepe, S., Gürbüz, N., Özdemir, I. et al. Novel Assemblies of Sn(II) Coordinated Polyimide Supported by a Ligand Containing N-Heterocyclic Phenantroline Unit. J Inorg Organomet Polym 18, 290–295 (2008). https://doi.org/10.1007/s10904-008-9203-2

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  • DOI: https://doi.org/10.1007/s10904-008-9203-2

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