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An Infinite Sandwich-Type Copper (I) Coordination Polymer Containing 2-D Double Chains Layers Structure Intercalated with the Terephthalic Acid Layers

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Abstract

A high-quality single crystal structure of a new coordination polymer having the formula [Cu2(μ-SO4)(μ-bpy)2 · (H2ta)] n (1) (H2ta = terephthalic acid; bpy = 4,4′-bipyridine) was obtained when the in situ reaction of CuSO4 · 5H2O with H2ta and bpy ligands under solvothermal conditions (H2O/ethanol) were carried out. The results of the structural characterization show that Cu(I) ions are bridged by 4,4′-bipyridine to form infinite 1-D chains, which are further linked through the sulfate groups to form a 1-D double chain structure. The extensive hydrogen-bonding interactions between the sulfate anions and free terephthalic acid molecules have an important effect in generating the 2-D layer structures and finally an infinite 3-D sandwich-type coordination polymer. In addition, the luminescent properties of coordination polymer 1 are also discussed.

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References

  1. (a) L. Carlucci, G. Ciani, D.M. Proserpio, Coord. Chem. Rev. 246, 247 (2003); (b) D.-R. Xiao, E.-B. Wang, H.-Y. An, Y.-G. Li, Z.-M. Su, C.-Y. Sun, Chem. Eur. J. 12, 6528 (2006) (c) M. Hong, Cryst. Growth Des. 7, 10 (2007)

  2. (a) W.-J. Shi, L. Hou, D. Li, Y.-G. Yin, Inorg. Chim. Acta 360, 588 (2007); (b) P.J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. Int. Ed. 38, 2638 (1999); (c) T.N.G. Row, Coord. Chem. Rev. 183, 81 (1999); (d) F.H. Allen, J.A.K. Howard, V.J. Hoy, G.R. Desiraju, D.S. Reddy, C.C. Wilson, J. Am. Chem. Soc. 118, 4081 (1996)

  3. K. Biradha, M. Sarkar, L. Rajput. Chem. Commun. 4169 (2006)

  4. (a) C.Y. Chen, P.P. Chu, K.H. Li. Chem. Commun. 1473 (1999); (b) M.D. Vaira, M. Guerra, F. Mani, P. Stoppioni, J. Chem. Soc. Dalton Trans. 1173 (1996); (c) A.B. Goel, E.C. Ashby, R.C. Mehrotra, Inorg. Chim. Acta 63, 161 (1982)

  5. (a) A. Rahmami, M.A. Romero, J.M. Salas, M. Quiros, G.A. de Cienfuegos, Inorg. Chim. Acta 247, 51 (1996); (b) S.D. Huang, R.-G. Xiong, P.H. Sotero, J. Solid State Chem. 138, 361 (1998); (c) S.D. Huang, R.-G. Xiong, J.D. Han, B.R. Weiner, Inorg. Chim. Acta 294, 95 (1999); (d) Y. Xu, W. Bi, X. Li, D. Sun, R. Cao, M. Hong, Inorg. Chem. Commun. 6, 495 (2003)

  6. (a) D. Li, H.K. Yip, C.M. Che, Z.Y. Zhou, T.C.W. Mak, S.T. Liu, J. Chem. Soc. Dalton Trans. 2445 (1992); (b) M. Henry, J.L. Wotton, S.I. Khan, J.I. Zink, Inorg. Chem. 36, 796 (1997); (c) V.W. Yam, W. Lee, T.F. Lai, J. Chem. Soc. Chem. Commun. 1571 (1993); (d) V.W.-W. Yam, K.K.-W. Lo, Chem. Soc. Rev. 28, 323 (1999)

  7. Q.-B. Bo, Z.-X. Sun, W. Forsling, Cryst. Eng. Comm. 10, 232 (2008)

    CAS  Google Scholar 

  8. (a) I.D. Brown, Acta Cryst. B 33, 1305 (1977); (b) Software, Bond Valence Calculator, version 2.0, (1993)

  9. (a) M.St.C. Flett, J. Chem. Soc. 962 (1951); (b) S. Bratoz, D. Hadzi, N. Sheppard, Spectrochim. Acta 8, 249 (1956)

  10. C.A. Tellez, E. Hollauer, M.A. Mondragon, V.M. Castano, Spectrochim. Acta Part A 57A(5), 993 (2001)

    CAS  Google Scholar 

  11. (a) L. Wasylina, E. Kucharska, Z. Weglinski, A. Puszko, Chem. Heterocycl. Compd. 35, 186 (1999); (b) M. Szafran, Z.D. Szafran, G. Buczak, A. Katrusiak, M.J. Potrzebowski, A. Komasa, J. Mol. Struct. 416, 145 (1997); (c) H. Aghabozorg, A. Moghimi, F. Manteghi, M. Ranjbar, Z. Anorg. Allg. Chem. 631, 909 (2005)

  12. A. Eapen, I.H. Joe, J. Solid State Chem. 133, 423 (1997)

    Article  CAS  Google Scholar 

  13. (a) S. Banerjee, M.G.B. Drew, A. Ghosh, Polyhedron, 22, 2933 (2003); (b) M.-S. Wang, G.-C. Guo, L.-Z. Cai, W.-T. Chen, B. Liu, A.-Q. Wu, J.-S. Huang, Dalton Trans. 2230 (2004)

  14. (a) M. Henary, J.L. Wootton, S.I. Khan, J.I. Zink, Inorg. Chem. 36, 796 (1997); (b) S. Ranjan, S.K. Dikshit, Polyhedron 17, 3071 (1998); (c) R.-N. Yang, D.-M. Wang, Y.-F. Liu, D.-M. Jin, Polyhedron 20, 585 (2001)

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Acknowledgements

The authors thank the Doctoral Foundation of Jinan University for financial support (B0404) and Science Study Plan Foundation of Educational Bureau of Shandong Provience (J200A02).

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  1. School of Science, University of Jinan, No.106, Jiwei Road, Jinan, 250022, Shandong, P.R. China

    M. J. Ren, J. Zhang, P. Zhao & Z. Zhang

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  1. M. J. Ren
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  2. J. Zhang
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Ren, M.J., Zhang, J., Zhao, P. et al. An Infinite Sandwich-Type Copper (I) Coordination Polymer Containing 2-D Double Chains Layers Structure Intercalated with the Terephthalic Acid Layers. J Inorg Organomet Polym 18, 284–289 (2008). https://doi.org/10.1007/s10904-008-9202-3

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