Skip to main content
Log in

Antibacterial Thin Films on Glass Substrate by Sol–Gel Process

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Antibacterial transparent thin films, containing different amounts of silver ion, have been prepared on a glass substrate by the sol–gel process. Thin films were obtained from inorganic-organic hybrid sols derived from 3-(glicydiloxypropyl)trimethoxy silane, N-(2-aminoethyl)-3-aminopropyl-trimethoxysilane and aluminium-sec-butoxide/ethylaceto-acetate complex and doped with silver ions. The films were characterized by Scanning Electron Microscopy and Raman Spectroscopy. The physical properties of the films were studied by solar-box, taber abraser, hardness test pencil, scratch-adhesion test and spectroscopy. The antibacterial activity of the coatings were investigated against gram negative Escherichia coli and gram positive Staphylococcus aureus. The results showed that 1% doping of the transparent hybrid thin film with silver ions resulted in high antibacterial properties of the film.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1.
Scheme 2.
Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.
Fig. 10.

Similar content being viewed by others

References

  1. Q. L. Feng, J. Wu, G. Q. Chen, F. Z. Cui, T. N. Kim, J. O. Kim, J. Biomed. Mat. Res. 52, 662 (2000)

    Article  CAS  Google Scholar 

  2. H. J. Jeon, S. C. Yi, S. G. Oh, Biomaterials 24, 4921 (2003)

    Article  PubMed  CAS  Google Scholar 

  3. D. P. Dowling, A. J. Betts, C. Pope, M. L. McConnel, R. Eloy, M. N. Arnaud, Surf. Coat. Technol. 163–164, 637 (2003)

    Article  Google Scholar 

  4. Q. L. Feng, T. N. Kim, J. Wu, E. S. Park, J. O. Kim, D. Y. Lim, F. Z. Cui, Thin Solid Films 335, 214 (1998)

    Article  Google Scholar 

  5. M. Kawashita, S. Tsuneyama, F. Miyaji, T. Kokubo, H. Kozuka, K. Yamamoto, Biomaterials 21, 393 (2000)

    Article  PubMed  CAS  Google Scholar 

  6. I. Sondi, B. S. Sondi, Colloid Interf. Sci. 275, 177 (2004)

    Article  CAS  Google Scholar 

  7. A. E. Aiello, B. Marshall, S. B. Levy, P. D. Latta, S. X. Lin, E. Larson, Emerg. Infect. Dis. 11, 1565 (2005)

    PubMed  Google Scholar 

  8. V. Alt, T. Bechert, P. Steinrücke, M. Wagener, P. Seidel, E. Dingeldein, E. Domann, R. Schnettler, Biomaterials 25, 4383 (2004)

    Article  PubMed  CAS  Google Scholar 

  9. S. D. Nunzio, C. V. Brovarone, S. Spriano, D. Milanese, E. Verne, V. Bergo, G. Maiana, P. Spinelli, J. Eur. Ceram. Soc. 24, 2935 (2004)

    Article  CAS  Google Scholar 

  10. H. J. Lee, S. Y. Yeo, S. H. Jeong, J. Mat. Sci. 38, 2199 (2003)

    Article  CAS  Google Scholar 

  11. J. M. Schierholz, L. J. Lucas, A. Rump, G. Pulverer, J. Hosp. Infect. 40, 257 (1998)

    Article  PubMed  CAS  Google Scholar 

  12. T. N. Kim, Q. L. Feng, J. O. Kim, J. Wu, H. Wang, G. C. Chen, F. Z. Cui, J. Mat. Sci.: Mat. Med. 9, 129 (1998)

    Article  Google Scholar 

  13. H. Schmidt, J. Sol-Gel Sci. Technol. 1, 217 (1994)

    Article  CAS  Google Scholar 

  14. H. Dislich, J. Non-Cryst. Solids 80, 115 (1986)

    Article  CAS  Google Scholar 

  15. C. J. Brinker, G. W. Scherer, J. Non-Cryst. Solids 70, 301 (1985)

    Article  CAS  Google Scholar 

  16. C. Sanchez, J. Livage, New J. Chem. 14, 513 (1990)

    CAS  Google Scholar 

  17. D. Hoebbel, Atlas NMR-Spektren von Verbindungen für Sol-Gel-Synthesen und von Reaktionsprodukten, INM GmbH, Saarbrücken, 2002, p. 55

    Google Scholar 

  18. R. Budakoglu, E. Arpac, Key Eng. Mat. 264–268, 423 (2004)

    Article  Google Scholar 

  19. B. V. Zuhmud, J. Sonnefeld, J. Non-Cryst. Solid. 195, 16 (1996)

    Article  Google Scholar 

  20. G. Suyal, Thin Solid Films 426, 53 (2003)

    Article  CAS  Google Scholar 

  21. New Test Method for Optical Imaging Evaluation of Adhesion by Tape Test Specimens, ASTM D 3359 WK97

  22. A. L. Lehninger, D. L. Nelson, and M. M. Cox, Lehninger Principles of Biochemistry, 4th ed. (W.H. Freeman & Co., 2004) Chap. 11

  23. H. J. Lee, S. H. Jeong, Text. Res. J. 74, 442 (2004)

    Article  CAS  Google Scholar 

  24. M.A. Leugers, A. K. Shepherd, J. Weston, and Z. Sun, World Intellectual Property Organization, WO 99/27350 (1999)

  25. D. Lilge and C. Gabriel, World Intellectual Property Oorganization, WO 2004/017056 A1 (2004)

  26. Standard test method for determining the activity of incorporated antimicrobial agents in polymeric or hydrophobic materials, ASTM E 2180 – 01.

Download references

Acknowledgements

The authors gratefully acknowledge the financial support of the project DPT 2006 K 120 680. Gamze Gül AVCI and Volkan GÜNAY from TÜBİTAK-MAM (Turkey) are also acknowledged for the SEM and Raman measurements.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. Tatar.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tatar, P., Kiraz, N., Asiltürk, M. et al. Antibacterial Thin Films on Glass Substrate by Sol–Gel Process. J Inorg Organomet Polym 17, 525–533 (2007). https://doi.org/10.1007/s10904-007-9142-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-007-9142-3

Keywords

Navigation