Skip to main content
SpringerLink
Log in

Syntheses and Characterization of Diorganotin Derivatives of 2-Mercapto-5-methyl-1,3,4-thiadiazole: X-ray Crystal Structure of Polymeric (C3H3S2N2) [(n-C4H9)6Sn3O(OH)2](C3H3S2N2)

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

An Erratum to this article was published on 06 February 2007

Diorganotin derivatives of 2-mercapto-5-methyl-1,3,4 -thiadiazole, \((\hbox{C}_3\hbox{H}_3\hbox{S}_2\hbox{N}_2)[(\hbox{R})_6\hbox {Sn}_3\hbox{O}\hbox{(OH)}_2](\hbox{C}_3\hbox{H}_3\hbox{S}_2 \hbox{N}_2)\)(R = Me 1, n-Bu 2, Ph 3, PhCH2 4), have been synthesized and characterized by IR, 1H, 13C and 119Sn NMR spectroscopy. Among them, polymer 2 was also characterized by X-ray crystallography diffraction analysis. This revealed that 2 showed a unique tricyclic structure consisting of a fused five-membered Sn2ON2 ring and a four-membered Sn2O2 ring. These formed a planar N2Sn3O2 skeleton, with distorted trigonal bipyramidal coordination at the two tin centers and a distorted octahedral coordination at the other tin center. The supramolecular structure of polymer 2 was a 1D zig-zag polymeric chain stabilized by intermolecular O–H...S hydrogen bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1.
Scheme 2.
Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

References

  1. Eshel M., Bino A. (2001) Inorg. Chim. Acta. 320: 127

    Article  CAS  Google Scholar 

  2. Huang W., Zhu H. B., Gou S. H. (2006) Coord. Chem. Reviews 250: 414

    Article  CAS  Google Scholar 

  3. Kiss E., Petrohan K., Sanna D., Garribba E., Micera G., Kiss T. (2000) Polyhedron 19: 55

    Article  CAS  Google Scholar 

  4. Dakternieks D., Duthie A., Zobel B., Jurkschat K., Schürmann M., Tiekink E. R. T. (2002) Organometallics 21: 647

    Article  CAS  Google Scholar 

  5. S. Bhandari, M. F. Mahon, J. G. McGinley, K. C. Molloy, C. E. E. Roper J. Chem. Soc. Dalton Trans. 3425 (1998)

  6. Lu T. B., Ou G. C., Jiang L., Feng X. L., Ji L. N. (2005) Inorg. Chim. Acta. 358: 3241

    Article  CAS  Google Scholar 

  7. Li X. Z., He J. H., Liu B. L., Liao D. Z. (2004) Inorg. Chem. Commun. 7: 420

    Article  CAS  Google Scholar 

  8. Duboy S. K., Roy U. (2003) Appl. Organomet. Chem. 17: 3

    Article  Google Scholar 

  9. García -Zarracino R., Ramos-Quìňones J., Höpfl H. (2003) Inorg. Chem. 42: 3835

    Article  Google Scholar 

  10. Raper E. S. (1996) Coord. Chem. Rev. 153: 199

    Article  CAS  Google Scholar 

  11. C. L. Ma, Q. Jiang, R. F. Zhang, and D. Q. Wang, J. Chem. Soc. Dalton Trans. 2975 (2003)

  12. Ma C. L., Jiang Q., Zhang R. F. (2003) J. Organomet. Chem. 678: 148

    Article  CAS  Google Scholar 

  13. M. V. Castaňo, M. M. Plasencia, A. Macias, J. S. Casas, J. Sordo, and E. E. Castellano, J. Chem. Soc., Dalton Trans. 1409 (1989)

  14. C. L. Ma, J. K. Li, and R. F. Zhang, Heteroatom Chem (accepted)

  15. Sisido K., Takeda Y., Kinugawa Z. (1961) J. Am. Chem. Soc. 83: 538

    Article  Google Scholar 

  16. Ma C. L., Li F. (2003) Chin. J Chem. 21: 146

    CAS  Google Scholar 

  17. C. L. Ma, J. H. Zhang, F. Li, and R. F. Zhang, Eur. J Inorg. Chem. 2775 (2004).

  18. Chow Y. M. (1971) Inorg. Chem. 10: 673

    Article  CAS  Google Scholar 

  19. Hadjiliadis H., Theophanides T. (1977) Can. J. Spectrosc. 22: 51

    CAS  Google Scholar 

  20. Durig J. R., Layton R., Sink D. W., Mitchell B. R. (1965) Spectrochim. Acta 21: 1367

    Article  CAS  Google Scholar 

  21. de Sousa A. P. G., Silva R. M., Cesar A., Wardell J. L., Huffman J. C., Abras A. (2000) J. Organomet. Chem. 605: 82

    Article  Google Scholar 

  22. Schmiedgen R., Huber F., Preut H., Ruisi G., Barbieri R. (1994) Appl. Organomet. Chem. 8: 397

    Article  CAS  Google Scholar 

  23. Holeček J., Nádvorník M., Handlíř K., Lyčka A. (1986) J. Organomet. Chem. 315: 299

    Article  Google Scholar 

  24. H. Reuter, PhD thesis, University of Bonn, Germany, (1986)

  25. Puff H., Bung I., Friedrichs E., Jansen A. (1983) J. Organomet. Chem. 254: 23

    Article  CAS  Google Scholar 

  26. R. Okawara, Process of Chemistry Society, London, 383 (1961)

  27. Harrison P. G., Begley M. J., Molloy K. C. (1980) J. Organomet. Chem. 186: 213

    Article  CAS  Google Scholar 

  28. Hubeey J. E., Keiter E. A., Keiter R. L. (1993) Principles and Applications of lnorganic Chemistry, 4th ed. Harper Collins, New York, pp. 121–124

    Google Scholar 

  29. F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, and R. J. Taylor, J. Chem. Soc. Perkin Trans. II, S1 (1987)

Download references

Acknowledgments

We thank the National Natural Science Foundation of China (20271025) for financial support.

Author information

Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, Liaocheng, 252059, P.R. China

    Chunlin Ma, Jikun Li, Rufen Zhang & Daqi Wang

  2. Department of Chemistry, Taishan University, Taian, 271021, P.R. China

    Chunlin Ma

Authors
  1. Chunlin Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jikun Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Rufen Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Daqi Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Chunlin Ma.

Additional information

An erratum to this article can be found at http://dx.doi.org/10.1007/s10904-007-9110-y

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ma, C., Li, J., Zhang, R. et al. Syntheses and Characterization of Diorganotin Derivatives of 2-Mercapto-5-methyl-1,3,4-thiadiazole: X-ray Crystal Structure of Polymeric (C3H3S2N2) [(n-C4H9)6Sn3O(OH)2](C3H3S2N2). J Inorg Organomet Polym 16, 147–153 (2006). https://doi.org/10.1007/s10904-006-9042-y

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-006-9042-y

Keywords

Search

Navigation