Abstract
The condensation reaction of 1,n′-diaminoferrocene and 1,n′-ferrocene dicarboxylic acid gives rise of a series of novel oligo- and poly-ferrocene peptides. These materials are fully soluble in a variety of solvents and are fully characterized spectroscopically. There is no apparent electronic interaction between adjacent ferrocene groups in these systems.
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References
(a) T. J. Peckham, P. Gomez-Elipe, and I. Manners, in A. Togni and R. L. Haltermann, eds., Metallocenes. (Wiley-VCH, Weinheim, 1998), p. 723; (b) C. U. Pittman Jr., J. Inorg. Organometal. Polym. 15, 33 (2005); (c) H. R. Allcock, J. Inorg. Organometal. Polym. 15, 57 (2005); (d) C. E. Carraher Jr., J. Inorg. Organometal. Polym. 15, 121 (2005); (e) H. Nishihara and M. Murata, J. Inorg. Organometal. Polym. 15, 147 (2005)
Abd-El-Aziz A. S., Carraher C. E. Jr., Pittman C. U. Jr., Sheats J. E., Zeldin M. (2003) Macromolecules Containing Metal and Metal-Like Elements, Vol. 1. Wiley& Sons Inc., New Jersey
Neuse E. W., Bednarik L. (1979) Macromolecules 12:187
Buretea M. A., Tilley T. D. (1997) Organometallics 16:1507
C. E. Stanton, T. R. Lee, R. H. Grubbs, N. S. Lewis, J. K. C. Pudelski, M. R. Callstorm, M. S. Erickson, and M. L. McLaughlin, Macromolecules 28, 8713 (1995)
Gamble A. S., Patton J. T., Boncella J. M. (1993) Makromol. Chem. Rapid Commun. 13:109
Heo R. W., Park J. -S., Lee T. R. (2004) Macromolecules 38:2546
K. A. Mahmoud, Y. -T. Long, G. Schatte, and H. -B. Kraatz, Eur. J. Inorg. Chem. 173 (2005)
Abd-El-Aziz A. S., Manners I. (2005) J. Inorg. Organomet. Polym. 15:157
Manners I. (1996) Angew. Chem. Int. Ed. Engl. 35:1602
Nguyen P., Elipe-Gomez P., Manners I. (1999) Chem. Rev. 99:1515
Manners I. (1996) Angew. Chem. Int. Ed. Engl. 35:1603
Manners I. (1998) Can. J. Chem. 76:371
Heo R. W., Park J. -S., Goodson J. T., Claudio G. C., Takenaga M., Albright T. A., Lee T. R. (2004) Tetrahedron 60:7225
Alvarez J., Ni Y., Ren T., Kaifer A. (2001) J. Supramol. Chem. 1:7
Ding L., K. M., Bolt M., Zanello P., Wagner M. (2001) Organometallics 20:1041
Nishihara H. (2001) Bull. Chem. Soc. Jpn. 74:19
Wang X. J., Wang L., Wang J. J. (2002) J. Funct. Polym. 15:1709
M. Heitzmann, J. -C. Moutet, J. Pecaut, O. Reynes, G. Royal, and G. Serratrice, Eur. J. Inorg. Chem. 3767 (2003)
Butler I. R., Quayle S. C. (1998) J. Organomet. Chem. 63:552
Okamura T., Sakauye K., Ueyama N., Nakamura A. (1998) Inorg. Chem. 37:6731
K. Heinze and M. Schlenker, Eur. J. Inorg. Chem. 2974 (2004)
K. Heinze and M. Schlenker, Eur. J. Inorg. Chem. 66 (2005)
Chowdhury S., Mahmoud K. A., Schatte G., Kraatz H. -B. (2005) Org. Biomol. Chem. 3:3018
Rulkens R., Lough A. J., Manners I. (1994) J. Am. Chem. Soc. 116:797
Pannell K. H., Dementiev V. V., Li H., Cervantes-Lee F., Nguyen M. T., Diaz A. F. (1994) Organometallics 13:3644
Azkern H., Hiermeier J., Kohler F. H., Steck A. (1991) J. Organomet. Chem. 408:281
Zhu S. S., Carroll P. J., Swager T. M. (1996) J. Am. Chem. Soc. 118:8713
Alvarez J., Ren T., Kaifer A. E. (2001) Organometallics 20:3543
Tarraga A., Molina P., Curiel D., Desamparados Velasco M. (2001) Organometallics 20:2145
Sengupta S., Sadhukhan S. K. (2001) Organometallics 20:1889
Maricic S., Frejd T. (2002) J. Org. Chem 67:7600
Acknowledgments
Financial support from NSERC, CFI and SIF is gratefully acknowledged. H.-B.K. holds the Canada Research Chair in Biomaterials. We are grateful to the Saskatchewan Structure Science Center (SSSC) for providing access to all necessary instrumentation. Ken Thoms, Chemistry Department, University of Saskatchewan, is also acknowledged for carrying out the Maldi-Tof experiments.
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An erratum to this article can be found at http://dx.doi.org/10.1007/s10904-007-9118-3
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Mahmoud, K.A., Kraatz, HB. Synthesis and Electrochemical Investigation of Oligomeric Ferrocene Amides: Towards Ferrocene Polyamides. J Inorg Organomet Polym 16, 201–210 (2006). https://doi.org/10.1007/s10904-006-9040-0
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DOI: https://doi.org/10.1007/s10904-006-9040-0