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Synthesis, Characterization and Crystal Structure of a Novel One-Dimensional Supramolecular Dimethyltin (IV) Compound

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An Erratum to this article was published on 06 February 2007

Abstract

A novel one-dimensional (1D) supramolecular dimethyltin compound of (Me2SnO)2(Me2SnOCH3)(O2CCH2SC4H3N2-2,6)[Me2Sn(O2CCH2SC4H3N2-2,6)2]·CH3OH was prepared by the reaction of (CH3)2SnCl2 with (2-pyrimidylthio)acetic acid with CH3ONa as a base. The title compound contained four different tin atom environments. Among them, Sn(1) and Sn(2) were both five-coordinate with distorted trigonal bipyramidal geometries, Sn(3) was six-coordinate with a distorted octahedral geometry and Sn(4) was seven-coordinate with pentagonal bipyramidal geometry. Meanwhile, the compound was stabilized in a 1D infinite chain by intermolecular Sn–O bonds.

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ACKNOWLEDGMENTS

We thank the National Nature Science Foundation of China (20271025) and the National Nature Science Foundation of Shandong Province for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, Liaocheng, 252059, People’s Republic of China

    Rufen Zhang, Yinfeng Han & Chunlin Ma

  2. Taishan University, Taian, 271021, People’s Republic of China

    Chunlin Ma

Authors
  1. Rufen Zhang
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  2. Yinfeng Han
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  3. Chunlin Ma
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Correspondence to Chunlin Ma.

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An erratum to this article can be found at http://dx.doi.org/10.1007/s10904-007-9103-x

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Zhang, R., Han, Y. & Ma, C. Synthesis, Characterization and Crystal Structure of a Novel One-Dimensional Supramolecular Dimethyltin (IV) Compound. J Inorg Organomet Polym 16, 25–29 (2006). https://doi.org/10.1007/s10904-006-9032-0

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