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Synthesis, Characterization and Thermogravimetric Analysis of Two Dicyclohexyl-18-crown-6 Pd, Pt Isomaleonitriledithiolate Complexes

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An Erratum to this article was published on 06 February 2007

Two organic–inorganic hybrid dicyclohexyl-18-crown-6 complexes, [K(DC18C6-B)]2[Pd(i-mnt)2] (1) and [K(DC18C6-A)]2[Pt(i-mnt)2] (2) (DC18C6-A=cis-syn-cis-dicyclohexyl-18-crown-6, A isomer; DC18C6-B = cis-anti-cis-dicyclohexyl-18-crown-6, B isomer; i-mnt=1,1-dicyanoethene-2,2-dithiolate, isomaleonitriledithiolate), were synthesized by the reaction of dicyclohexyl-18-crown-6 with K2(i-mnt) and PdCl2 or K2PtCl4 respectively. These were characterized by elemental analysis, FT–IR, UV–Vis spectroscopy and single crystal X-ray diffraction. In complex 1, two [K(DC18C6-B)]+ complex cations and one [Pd(i-mnt)2]2− complex anion formed a neutral molecule through two K–N coordination bonds. The resulting molecule adopted a 1D chain arrangement via K N weak interactions. Complex 2 showed a 1D chain-like structure that was assembled by two [K(DC18C6-A)]+ complex cations and one [Pt(i-mnt)2]2− complex anion through N–K–N interactions.

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Acknowledgments

We acknowledge the financial support of the Natural Science Foundation of Shandong Province (Y2003B01) and Liaocheng University, P. R. China.

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Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, Liaocheng, 252059, P.R. China

    Yun-Ming Sun, Feng-Ying Dong, Jian-Min Dou, Da-Cheng Li, Xi-Ke Gao & Da-Qi Wang

  2. Department of Plant Protection, Laiyang Agricultural College, Qingdao, 266109, P.R. China

    Yun-Ming Sun & Feng-Ying Dong

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  1. Yun-Ming Sun
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  2. Feng-Ying Dong
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Correspondence to Jian-Min Dou.

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An erratum to this article can be found at http://dx.doi.org/10.1007/s10904-007-9100-0

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Sun, YM., Dong, FY., Dou, JM. et al. Synthesis, Characterization and Thermogravimetric Analysis of Two Dicyclohexyl-18-crown-6 Pd, Pt Isomaleonitriledithiolate Complexes. J Inorg Organomet Polym 16, 61–67 (2006). https://doi.org/10.1007/s10904-006-9027-x

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