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Extractive Spectrophotometric Detection of Sn(II) Using 6-bromo-3-hydroxy-2-(5-methylfuran-2-yl)-4H-chromen-4-one

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Abstract

For the determination of tin(II) traces, an extractive spectrophotometric approach is devised. The applied method serves a powerful tool for determination of tin(II), involves the formation of yellow colored complex after the binding of 6-bromo-3-hydroxy-2-(5-methylfuran-2-yl)-4H-chromen-4-one (BHMF) and tin(II) in 1:2 stiochiometry in a slightly acidic medium (HCl). The complex shows absorbance at 434 nm with respect of the blank reagent. The outcomes of spectral investigation for complexation showed a Beer’s range of 0–1.3 μg Sn mL−1, molar absorptivity, specific absorptivity and Sandell’s complex sensitivity are 9.291 × 104 L mol−1 cm−1, 0.490 mL g−1 cm−1 and 0.002040 μg cm−2 at 434 nm that was stable for two days. The interferences study results showed that this method is free from interferences, when tested with metal ions including Ag, Be, Bi, Ca, Cd, Ce, Co, Hg, Mo, Re, Pt, Se,Ti, U, V, W and other common cations, anions, and complexing agents. The applied method is quite simple, highly selective, and sensitive with good re-producibility. This method has been satisfactorily by utilizing the proposed procedure, and its applicability has been tested by analyzing synthetic samples and an alloy sample of gunmetal. The procedure assumes this because of the scarcity of better methods for determining tin(II). The results are in good agreement with the certified value.

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References

  1. Mohan B, Modi K, Patel C, Kumar S, Zhiyu T, You H, Ren P (2021) A new N-methylhydrazinecarbothioamide incorporated “naked-eye” and “turn-off” chemosensor for selective and low detection of Cu2+ ions and computation study. J Photochem Photobiol A Chem 408:113097. https://doi.org/10.1016/j.jphotochem.2020.113097

    Article  CAS  Google Scholar 

  2. Gupta SK, Zuniga JP, Pokhrel M, Mao Y (2020) High pressure induced local ordering and tunable luminescence of La2Hf2O7:Eu3+ nanoparticles. New J Chem 44:5463–5472. https://doi.org/10.1039/D0NJ00585A

    Article  CAS  Google Scholar 

  3. Saito Y, Nishikawa M, Tsubomura T (2018) Water-soluble copper(I) complexes bearing 2,2′-bicinchoninic acid dipotassium salt with red-light absorption and repeatable colour change upon freezing operation. New J Chem 43:277–283. https://doi.org/10.1039/C8NJ05147J

    Article  Google Scholar 

  4. Kaur B, Kaur N, Kumar S (2018) Colorimetric metal ion sensors – A comprehensive review of the years 2011–2016. Coord Chem Rev 358:13–69. https://doi.org/10.1016/j.ccr.2017.12.002

    Article  CAS  Google Scholar 

  5. Saravanan R, Khan MM, Gupta VK, Mosquera E, Gracia F, Narayanan V, Stephen A (2015) ZnO/Ag/CdO nanocomposite for visible light-induced photocatalytic degradation of industrial textile effluents. J Colloid Interface Sci 452:126–133. https://doi.org/10.1016/j.jcis.2015.04.035

    Article  CAS  PubMed  Google Scholar 

  6. Mohan B, Modi K, Patel C, Kumar S, Sharma HK (2020) Synthesis and computational mechanistic studies of copper selective molecular receptor. Vietnam J Chem 58:221–230. https://doi.org/10.1002/vjch.201900161

    Article  CAS  Google Scholar 

  7. Machado RC, Amaral CDB, Schiavo D, Nóbrega JA, Nogueira ARA (2017) Complex samples and spectral interferences in ICP-MS: Evaluation of tandem mass spectrometry for interference-free determination of cadmium, tin and platinum group elements. Microchem J 130:271–275. https://doi.org/10.1016/J.MICROC.2016.09.011

    Article  CAS  Google Scholar 

  8. Niknezhadi A, Nezamzadeh-Ejhieh A (2017) A novel and sensitive carbon paste electrode with clinoptilolite nano-particles containing hexadecyltrimethyl ammonium surfactant and dithizone for the voltammetric determination of Sn(II). J Colloid Interface Sci 501:321–329. https://doi.org/10.1016/J.JCIS.2017.04.068

    Article  CAS  PubMed  Google Scholar 

  9. Tan KH, Rahman HA, Taib H (2019) Coating layer and influence of transition metal for ferritic stainless steel interconnector solid oxide fuel cell: A review. Int J Hydrogen Energy 44:30591–30605. https://doi.org/10.1016/J.IJHYDENE.2019.06.155

    Article  CAS  Google Scholar 

  10. Wang Z, Cheng M, Bu J, Cheng L, Ru J, Hua Y, Wang D (2022) Understanding the electrochemical behavior of Sn(II) in choline chloride-ethylene glycol deep eutectic solvent for tin powders preparation. Adv Powder Technol 33:103670. https://doi.org/10.1016/J.APT.2022.103670

    Article  CAS  Google Scholar 

  11. Tan X, Jiang Y, Yiqing C, Anqi T, Li J, Sun Y (2022) Roles of different components of complex inclusion in pitting of 321 stainless steel: Induction effect of CaS and inhibition effect of TiN. Corros Sci 110692. https://doi.org/10.1016/J.CORSCI.2022.110692

  12. Bajnóczi ÉG, Czeglédi E, Kuzmann E, Homonnay Z, Bálint S, Dombi G, Forgo P, Berkesi O, Pálinkó I, Peintler G, Sipos P, Persson I (2014) Speciation and structure of tin(II) in hyper-alkaline aqueous solution. Dalt Trans 43:17971–17979. https://doi.org/10.1039/C4DT02706J

    Article  CAS  Google Scholar 

  13. Hu M, Wang G, Zhang Q, Gong J, Xing Z, Gao J, Wang J, Zeng P, Zheng S, Liu M, Zhou Y, Yang S (2022) Antioxidative solution processing yields exceptional Sn(II) stability for sub-1.4 eV bandgap inorganic perovskite solar cells. J Energy Chem 72:487–494. https://doi.org/10.1016/J.JECHEM.2022.05.030

    Article  CAS  Google Scholar 

  14. Mohan B, Modi K, Patel C, Bhatia P, Kumar A, Sharma HK (2018) Design and synthesis of two armed molecular receptor for recognition of Gd3+ metal ion and its computational study. Appl Organomet Chem 32:1–11. https://doi.org/10.1002/aoc.4502

    Article  CAS  Google Scholar 

  15. Gaur A, Joshi SK, Nair NN, Shrivastava BD, Patel RN, Jha SN, Bhattacharyya D (2020) XAFS study of tridentate Schiff base Ni(II) complexes having distorted octahedral geometry. Radiat Phys Chem 175:108066. https://doi.org/10.1016/J.RADPHYSCHEM.2018.11.020

    Article  CAS  Google Scholar 

  16. Pundi A, Chang CJ, Chen J, Hsieh SR, Lee MC (2021) A chiral carbazole based sensor for sequential “on-off-on” fluorescence detection of Fe3+ and tryptophan/histidine. Sens Actuators B Chem 328:129084. https://doi.org/10.1016/j.snb.2020.129084

    Article  CAS  Google Scholar 

  17. Likhonina AE, Lebedev IS, Mamardashvili GM, Mamardashvili NZ (2022) pH indicator and rotary fluorescent properties of the Sn(IV)-octaetylporphyrin-(BODIPY)2 triad. Inorganica Chim Acta 542:121150. https://doi.org/10.1016/J.ICA.2022.121150

    Article  CAS  Google Scholar 

  18. Singh G, Priyanka, Singh A, Satija P, Sushma, Pawan, Mohit, Singh J, Singh J (2021) Schiff base-functionalized silatrane-based receptor as a potential chemo-sensor for the detection of Al3+ ions. New J Chem 45:7850–7859. https://doi.org/10.1039/d1nj00943e

    Article  CAS  Google Scholar 

  19. Singh G, Priyanka, Sushma, Diksha, Mohit, Suman, Kaur JD, Saini A, Satija P (2021) Design, synthesis and photophysical aspects of 1,2,3-triazole appended Schiff base functionalized silanes and silatranes. New J Chem 45:17356–17365. https://doi.org/10.1039/D1NJ03364F

    Article  CAS  Google Scholar 

  20. Rahmalia W, Fabre JF, Usman T, Mouloungui Z (2014) Aprotic solvents effect on the UV–visible absorption spectra of bixin. Spectrochim Acta Part A Mol Biomol Spectrosc 131:455–460. https://doi.org/10.1016/J.SAA.2014.03.119

    Article  CAS  Google Scholar 

  21. Tolbin AY, Pushkarev VE, Tomilova LG (2018) A mathematical analysis of deviations from linearity of Beer’s law. Chem Phys Lett 706:520–524. https://doi.org/10.1016/J.CPLETT.2018.06.056

    Article  CAS  Google Scholar 

  22. Li L, Zhao H, Ni N, Wang Y, Gao J, Gao Q, Zhang Y, Zhang Y (2022) Study on the origin of linear deviation with the Beer-Lambert law in absorption spectroscopy by measuring sulfur dioxide. Spectrochim Acta Part A Mol Biomol Spectrosc 275:121192. https://doi.org/10.1016/J.SAA.2022.121192

    Article  CAS  Google Scholar 

  23. Kolcu F, Erdener D, Kaya İ (2020) A Schiff base based on triphenylamine and thiophene moieties as a fluorescent sensor for Cr (III) ions: Synthesis, characterization and fluorescent applications. Inorganica Chim Acta 509:119676. https://doi.org/10.1016/j.ica.2020.119676

    Article  CAS  Google Scholar 

  24. Chen H, Yang P, Li Y, Zhang L, Ding F, He X, Shen J (2020) Insight into triphenylamine and coumarin serving as copper (II) sensors with “OFF” strategy and for bio-imaging in living cells. Spectrochim Acta - Part A Mol Biomol Spectrosc 224:117384. https://doi.org/10.1016/j.saa.2019.117384

    Article  CAS  Google Scholar 

  25. Kundu S, Truong KN, Saha S, Rissanen K, Sahoo P (2022) A handy and accessible tool for identification of Sn(II) in toothpaste. Sci Rep 12:1–9. https://doi.org/10.1038/s41598-022-06299-0

    Article  CAS  Google Scholar 

  26. Gholivand MB, Babakhanian A, Rafiee E (2008) Determination of Sn(II) and Sn(IV) after mixed micelle-mediated cloud point extraction using α-polyoxometalate as a complexing agent by flame atomic absorption spectrometry. Talanta 76:503–508. https://doi.org/10.1016/J.TALANTA.2008.03.057

    Article  CAS  PubMed  Google Scholar 

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Acknowledgements

Gratitude to acknowledge the financial assistance provided by Human Resource Development Group (HRDG) Council of Scientific & Industrial Research (CSIR), New Delhi, India, to carry out this work under reference no. 09/105(0212)/2013-EMR-1. The authors are thankful to the Department of chemistry, Kurukshetra University, Kurukshetra (India), for providing spectral facilities, including NMR spectroscopy.

Funding

The financial assistance provided by Human Resource Development Group (HRDG) Council of Scientific & Industrial Research (CSIR), New Delhi, India, to carry out this work under reference no. 09/105(0212)/2013-EMR-1.

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Author notes

  1. Pankaj Bhatia and Virender are equally contributed to the manuscript.

Authors and Affiliations

  1. Department of Chemistry, Kurukshetra University Kurukshetra, Kurukshetra, 136119, India

    Pankaj Bhatia,  Virender & Harish Kumar Sharma

  2. Department of Chemistry, Panjab University, Chandigarh, 160014, India

    Gurjaspreet Singh

  3. Centro de Química Estrutural, Institute of Molecular Sciences, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal

    Brij Mohan

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Contributions

Original draft preparation, writing, methodology by Pankaj Bhatia and Virender. Formal analysis, review and editing by Gurjaspreet Singh. Formal analysis by Harish Kumar Sharma and Brij Mohan.

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Correspondence to Pankaj Bhatia or Gurjaspreet Singh.

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Bhatia, P., Virender, Sharma, H.K. et al. Extractive Spectrophotometric Detection of Sn(II) Using 6-bromo-3-hydroxy-2-(5-methylfuran-2-yl)-4H-chromen-4-one. J Fluoresc (2023). https://doi.org/10.1007/s10895-023-03413-x

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