Abstract
Gamma rays are a type of ionizing radiation that are extremely hazardous and dangerous for humans and the environment. The fluorescence method is a simple, useful, and fast method for the detection of gamma rays. In this research, CdTe/ZnS core/shell quantum dots were used as on fluorescence sensor for the detection of gamma rays. CdTe/ZnS core/shell QDs were prepared via a simple and rapid photochemical method. The shell thickness and concentration of CdTe/ZnS core/shell quantum dots were studied as two important factors in the optical behavior of CdTe/ZnS quantum dots. The obtained results showed that the PL intensity of CdTe/ZnS QDs after gamma irradiation was increased and also a slight redshift in the PL spectrum was observed. X-ray diffractions (XRD) and Raman analyses were used to study the effect of gamma irradiation on the structural properties of CdTe/ZnS QDs. The obtained results showed that gamma irradiation couldn’t damage the crystalline structure of CdTe/ZnS core/shell QDs.
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References
Conrad J, Cohen-Tanugi J, Strigari LE (2015) WIMP searches with gamma rays in the Fermi era: challenges, methods and results. J Exp Theor Phys 121:1104–1135
Kempner ES (2001) Effects of high-energy electrons and gamma rays directly on protein molecules. J Pharm Sci 90(10):1637–1646
van Eldik C (2015) Gamma rays from the Galactic Centre region: a review. Astropart Phys 71:45–70
Hobson PR, Leslie DE, Smith DR (2011) Effect of gamma radiation on potential ionising radiation detectors and dosimeters based on quantum dots. In: 2011 IEEE Nuclear Science Symposium Conference Record, pp 3015–3017
Farahmandzadeh F, Molaei M, Alehdaghi H, Karimipour M, Shamsi A (2022) Effect of concentration and shell thickness on the optical behavior of aqueous CdTe/ZnSe core/shell quantum dots (QDs) exposed to ionizing radiation. Luminescence 37(3):431–439
Bekasova OD, Revina AA, Rusanov AL, Kornienko ES, Kurganov BI (2013) Effect of gamma-ray irradiation on the size and properties of CdS quantum dots in reverse micelles. Radiat Phys Chem 92:87–92
Li Y, Dong X, Gao J, Hei D, Zhou X, Zhang H (2009) A highly sensitive γ-radiation dosimeter based on the CeO2 nanowires. Physica E 41(8):1550–1553
Farahmandzadeh F, Molaei M, Alehdaghi H, Karimipour M (2022) The significant increasing photoluminescence quantum yield of the CdTe/CdS/ZnS core/multi-shell quantum dots (QDs) by 60Co gamma irradiation. Appl Phys A 128(3):1–10
Pei B, Hao Su, Chen B, Huang W, Zhang X, Miao H, Wang Y, Wang T, Zhang G (2020) Quantifiable polymeric fluorescent ratiometric γ-ray chemosensor. ACS Appl Mater Interfaces 12(37):42210–42216
Han J-M, Miao Xu, Wang B, Na Wu, Yang X, Yang H, Salter BJ, Zang L (2014) Low dose detection of γ radiation via solvent assisted fluorescence quenching. J Am Chem Soc 136(13):5090–5096
Sarma R, Mohanta D (2015) Luminescence and bio-imaging response of thio-glycolic acid (TGA) and sodium dodecyl sulfate (SDS)-coated fluorescent cadmium selenide quantum dots. J Lumin 161:395–402
Farahmandzadeh F, Molaei M (2022) CdSe/CdS/ZnS core/multi-shell QDs: new microwave synthesis and applications for dye photodegradations. J Coord Chem 1–11
Bouali W, Erk N, Kholafazadehastamal G, Naser M, Tiris G (2023) Low-cost voltammetric sensor based on reduced graphene oxide anchored on platinum nanoparticles for robust determination of Favipiravir in real samples. Diam Relat Mater 131:109609
Vaishanav SK, Korram J, Nagwanshi R, Ghosh KK, Satnami ML (2017) Mn2+ doped-CdTe/ZnS modified fluorescence nanosensor for detection of glucose. Sens Actuators, B Chem 245:196–204
Alehdaghi H, Assar E, Azadegan B, Baedi J, Mowlavi AA (2020) Investigation of optical and structural properties of aqueous CdS quantum dots under gamma irradiation. Radiat Phys Chem 166:108476
Withers NJ, Sankar K, Akins BA, Memon TA, Gu T, Gu J, Smolyakov GA, Osinski M (2008) Effects of gamma irradiation on optical properties of CdSe/ZnS colloidal quantum dots. In: Conference on Lasers and Electro-Optics, p JThA66. Optical Society of America
Chang S, Xian Wu, Lan J, Li Z, Zhang X, Zhang H (2019) γ-Radiation enhanced luminescence of thiol-capped quantum dots in aqueous solution. Nanomaterials 9(4):506
Stodilka RZ, Carson JJ, Yu K, Zaman MB, Li C, Wilkinson D (2009) Optical degradation of CdSe/ZnS quantum dots upon gamma-ray irradiation. J Phys Chem C 113(6):2580–2585
Hien NT, Chi TTK, Vinh ND, Van HT, Thanh LD, Do PV, Tuyen VP, Ca NX (2020) Synthesis, characterization and the photoinduced electron-transfer energetics of CdTe/CdSe type-II core/shell quantum dots. J Lumin 217:116822
Ali M, Zayed D, Ramadan W, Kamel OA, Shehab M, Ebrahim S (2019) Synthesis, characterization and cytotoxicity of polyethylene glycol-encapsulated CdTe quantum dots. Int Nano Lett 9:61–71
Molaei M, Farahmandzadeh F, Mousavi TS, Karimipour M (2021) Photochemical synthesis, investigation of optical properties and photocatalytic activity of CdTe/CdSe core/shell quantum dots. Mater Technol 1–7
Derfus AM, Chan WC, Bhatia SN (2004) Probing the cytotoxicity of semiconductor quantum dots. Nano Lett 4(1):11–18
Zhao D, Fang Y, Wang H, He Z (2011) Synthesis and characterization of high-quality water-soluble CdTe: Zn 2+ quantum dots capped by N-acetyl-l-cysteine via hydrothermal method. J Mater Chem 21(35):13365–13370
Farahmandzadeh F, Molaei M, Karimipour M, Shamsi AR (2020) Highly luminescence CdTe/ZnSe core–shell QDs; synthesis by a simple low temperature approach. J Mater Sci: Mater Electron 31(15):12382–12388
Li Y, Wang W, Zhao D, Chen P, Hongwu Du, Wen Y, Zhang X (2015) Water-soluble fluorescent CdTe/ZnSe Core/Shell Quantum Dot: aqueous phase synthesis and cytotoxicity assays. J Nanosci Nanotechnol 15(6):4648–4652
Lu JJ, Ge SG, Wan FW, Yu JH (2011) Synthesis of CdTe and CdTe/CdS core-shell quantum dots and their optical properties. In: Advanced Materials Research, vol. 306, pp 1350–1353. Trans Tech Publications Ltd
Farahmandzadeh F, Molaei M, Karimipour M (2022) Ultrafast synthesis of CdTe/ZnSe semiconductor QDs by microwave method and investigation of structural, optical, and photocatalytic properties of CdTe/ZnSe QDs. J Mater Sci: Mater Electron 33(1):95–104
Eley C, Li T, Liao F, Fairclough SM, Smith JM, Smith G, Tsang SC (2014) Nanojunction-Mediated Photocatalytic Enhancement in Heterostructured CdS/ZnO, CdSe/ZnO, and CdTe/ZnO Nanocrystals. Angewandte Chemie 126(30):7972–7976
Tsay JM, Pflughoefft M, Bentolila LA, Weiss S (2004) Hybrid approach to the synthesis of highly luminescent CdTe/ZnS and CdHgTe/ZnS nanocrystals. J Am Chem Soc 126(7):1926–1927
Liu Y-F, Jun-Sheng Yu (2010) In situ synthesis of highly luminescent glutathione-capped CdTe/ZnS quantum dots with biocompatibility. J Colloid Interface Sci 351(1):1–9
Jing L, Ding Ke, Sergii Kalytchuk Yu, Wang RQ, Kershaw SV, Rogach AL, Gao M (2013) Aqueous manganese-doped core/shell CdTe/ZnS quantum dots with strong fluorescence and high relaxivity. The Journal of Physical Chemistry C 117(36):18752–18761
Liu H, Liu D, Fang G, Liu F, Liu C, Yang Y, Wang S (2013) A novel dual-function molecularly imprinted polymer on CdTe/ZnS quantum dots for highly selective and sensitive determination of ractopamine. Anal Chim Acta 762:76–82
Molaei M, Farahmandzadeh F, Hemmati R (2022) Correction to: Mercury (Hg2+) Detection in Aqueous Media, Photocatalyst, and Antibacterial Applications of CdTe/ZnS Quantum Dots. J Fluoresc 32(6):2139–2139
Molaei M, Karimimaskon F, Lotfiani A, Samadpour M, Liu H (2013) Synthesis of ZnS: Ni nanocrystals (NCs) using a rapid microwave activated method and investigation of the structural and optical properties. J Lumin 143:649–652
Ali M, El Nady J, Ebrahim S, Soliman M (2018) Structural and optical properties of upconversion CuInS/ZnS quantum dots. Opt Mater 86:545–549
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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by Farzad Farahmandzadeh, Mehdi Molaei, and Hassan Alehdaghi. The first draft of the manuscript was written by Farzad Farahmandzadeh. All authors read and approved the final manuscript.
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Farahmandzadeh, F., Molaei, M. & Alehdaghi, H. Application of CdTe/ZnS Core/Shell Quantum Dots as on Fluorescence Sensor for Detection of Gamma Rays. J Fluoresc 33, 2361–2367 (2023). https://doi.org/10.1007/s10895-023-03242-y
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DOI: https://doi.org/10.1007/s10895-023-03242-y