Skip to main content

Advertisement

SpringerLink
Log in

Development of a Sensitive and Selective Method for the Determination of some Selected Aldehydes Based on Fluorescence Quenching

  • Research
  • Published:
Journal of Fluorescence Aims and scope Submit manuscript

Abstract

Phenanthrene fluorescence quenching in anionic micellar system of sodium dodecyl sulphate (SDS) was explored for the development of a sensitive and selective method for a group of selected aldehydes (2,6-dichlorobenzaldehyde, 4-(dimethylamino)benzaldehyde, 4-aminobenzaldehyde, 4-nitrobenzaldehyde, 2-chlorobenzaldehyde, benzaldehyde and 2-methoxybenzaldehyde). Experiments were performed in 0.02 mol L− 1 SDS. All the studied aldehydes quenched the fluorescence intensity of the probe (phenanthrene). Stern-Volmer equation was useful in explaining the phenanthrene quenching by the studied aldehydes. Stern-Volmer constants (\({K}_{\text{S}\text{V}}\)) were obtained as a result of using the Stern-Volmer equation that gives the information in respect of sensitivity of the method for the studied aldehydes. Greater the \({K}_{\text{S}\text{V}}\) higher will be the sensitivity and vice versa. \({K}_{\text{S}\text{V}}\), detection limit (DL) and quantification limit (QL) were observed in the order 2,6-dichlorobenzaldehyde > 4-dimethylaminobenzaldehyde > 4-aminobenzaldehyde > 4-nitrobenzaldehyde > 2-chlorobenzaldehyde > benzaldehyde > 2-methoxybenzaldehyde. Phenanthrene fluorescence quenching by the studied aldehydes is useful for their determination in environmental samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

Data Availability

Data has been included in the manuscript, though if the spectra’s of all the experiments performed was needed will be sent on request.

References

  1. Vargas LV, Sand J, Brandão TAS, Fiedler HD, Quina FH, Nome F (2005) Determination of environmentally important metal ions by fluorescence quenching in anionic micellar solution. Analyst 130:242–246. https://doi.org/10.1039/B409600B

    Article  PubMed  CAS  Google Scholar 

  2. Silva AF, Fiedler HD, Nome F (2011) Ionic quenching of Naphthalene fluorescence in Sodium Dodecyl Sulfate Micelles. J Phys Chem A 115 2509 – 2514. https://doi.org/10.1021/jp109759f

  3. Sapelli E, Brandão TAS, Fiedler HD, Nome F (2007) Fluorescence of zn(II) 8-hydroxyquinoline complex in the presence of aqueous micellar media: the special cetyltrimethylammonium bromide effect. J Colloid Interf Sci 314:214–222. https://doi.org/10.1016/j.jcis.2007.05.049

    Article  CAS  Google Scholar 

  4. Idrees M, Bibi R, Khan MN (2018) Phenanthrene fluorescence quenching in Aqueous Sodium Dodecyl Sulphate (SDS) and determination of important metal ions. J Fluoresc 28:1251–1254. https://doi.org/10.1007/s10895-018-2288-2

    Article  PubMed  CAS  Google Scholar 

  5. Idrees M, Ayaz M, Bibi R, Khan MN (2019) Fluorescence quenching of the Probes L-Tryptophan and Indole by Anions in aqueous system. Anal Sci 36:183–185. https://doi.org/10.2116/analsci.19P264

    Article  PubMed  Google Scholar 

  6. Idrees M, Salam A (2021) Pyrene Interaction with selected Amines in Aqueous Sodium Dodecyl Sulphate (SDS). J Fluoresc 31:595–598. https://doi.org/10.1007/s10895-021-02688-2

    Article  PubMed  CAS  Google Scholar 

  7. Fiedler HD, Westrup JL, Souza AJ, Pavei AD, Chagas CU, Nome F (2004) Cd(II) determination in the presence of aqueous micellar solutions. Talanta 64:190–19516. https://doi.org/10.1016/j.talanta.2004.02.008

    Article  PubMed  CAS  Google Scholar 

  8. Khalil RB, Al-Khayat RZ (2008) Micellar catalysis in reactions of some β-lactam antibiotics with p –dimethylaminobenzaldehyde. 46:34–46. https://doi.org/10.1080/00319100601084993

  9. Khalil RA, Saeed AMA (2007) The role of micellar catalysis from kinetic and thermodynamic investigations of the reaction between bromhexine drug with para-dimethylaminobenzaldehyde. Colloids and Surfaces A: Physiochemical and Engineering Aspects 298:206–215. https://doi.org/10.1016/j.colsurfa.2006.10.064

    Article  CAS  Google Scholar 

  10. Bozkurt E, Gul HI (2019) Fluorescence quenching of novel pyrazoline derivative with aniline in different solvents. J Photochem Photobiol A: Chem 383:111996–1111002. https://doi.org/10.1016/j.jphotochem.2019.111996

    Article  CAS  Google Scholar 

  11. Adnan M, Fiedler HD, Ali J, Idrees M (2022) Pyrene interaction with selected heavy metal ions in aqueous sodium dodecyl sulphate (SDS). 346:117135. https://doi.org/10.1016/j.molliq.2021.117135

  12. Panda M, Chandel TI, Kamil M, Khan RH (2020) Fluorescence quenching of chloroquine by Cu2+ in micelles. 306:112763. https://doi.org/10.1016/j.molliq.2020.112763

  13. Baños CE, Silva M (2010) Liquid chromatography-tandem mass spectrometry for the determination of low-molecular mass aldehydes in human urine. J Chromatogr B 878:653–658. https://doi.org/10.1016/j.jchromb.2010.01.024

    Article  CAS  Google Scholar 

  14. Zwiener C, Glauner T, Frimmel FH (2002) Method optimization for the determination of carbonyl compounds in disinfected water by DNPH derivatization and LC-ESI-MS-MS. Anal Bioanal Chem 372:615–621. https://doi.org/10.1007/s00216-002-1233-y

    Article  PubMed  CAS  Google Scholar 

  15. Xue R, Dong L, Zhang S, Deng C, Liu T, Wang J, Shen X (2008) Investigation of volatile biomarkers in liver cancer blood using solid-phase microextraction and gas chromatography/mass spectrometry. Rapid Commun Mass Sp 22:1181–1186. https://doi.org/10.1002/rcm.3466

    Article  CAS  Google Scholar 

  16. Ye Q, Zheng D, Liu L, Hong L (2011) Rapid analysis of aldehydes by simultaneous microextraction and derivatization followed by GC-MS. J Sep Sci 34:1607–1612. https://doi.org/10.1002/jssc.201100145

    Article  PubMed  CAS  Google Scholar 

  17. Serrano M, Gallego M, Silva M (2017) Quantitative analysis of aldehydes in canned vegetables using static headspace-gas chromatography-mass spectrometry. J Chromatogr A 1524:21–28. https://doi.org/10.1016/j.chroma.2017.09.067

    Article  PubMed  CAS  Google Scholar 

  18. Serrano M, Gallego M, Silva M (2017) Origin of low-molecular mass aldehydes as disinfection by-products in beverages. Food Addit Contam A 34:1461–1471. https://doi.org/10.1080/19440049.2017.1346393

    Article  CAS  Google Scholar 

  19. Zardari LA, Khuhawar MY, Laghari A (2009) Capillary GC analysis of glyoxal and methylglyoxal in the serum and urine of diabetic patients after use of 2, 3-diamino-2, 3-dimethylbutane as derivatizing reagent. J Chromatogr 70:891–897. https://doi.org/10.1365/s10337-009-1202-0

    Article  CAS  Google Scholar 

  20. Fiamegos YC, Stalikas CD (2008) Gas chromatographic determination of carbonyl compounds in biological and oil samples by headspace single-drop microextraction with in-drop derivatization. Anal Chim Acta 609:175–183. https://doi.org/10.1016/j.aca.2007.12.042

    Article  PubMed  CAS  Google Scholar 

  21. Ruan ED, Aalhus J, Juárez M (2014) A rapid, sensitive and solvent-less method for determination of malonaldehyde in meat by stir bar sorptive extraction coupled thermal desorption and gas chromatography/mass spectrometry with in situ derivatization. Rapid Commun Mass Sp 28:2723–2728. https://doi.org/10.1002/rcm.7058

    Article  CAS  Google Scholar 

Download references

Acknowledgements

Authors thank HEC, for financial help and research facilities in the department.

Funding

No funding.

Author information

Authors and Affiliations

  1. Department of Chemistry, Bacha Khan University, Charsadda, Pakistan

    Muhammad Idrees, Shah Hussain & Abdul Salam

Authors
  1. Muhammad Idrees
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shah Hussain
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Abdul Salam
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

Shah Hussain prepared the solutions, performed the experiments and treated the data whereas Abddul Salam being a senior student in the lab, helped him in performing the experiments. The corresponding author supervised the work, prepared the manuscript.

Corresponding author

Correspondence to Muhammad Idrees.

Ethics declarations

Competing Interests

No competing interest.

Consent for publication

Corresponding author on behalf of all the authors authorize the publishers to publish the data after acceptance.

Consent to Participate

Not Applicable.

Ethics Declaration Statement

Not applicable.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic Supplementary Material

Below is the link to the electronic supplementary material.

Supplementary Material 1

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Idrees, M., Hussain, S. & Salam, A. Development of a Sensitive and Selective Method for the Determination of some Selected Aldehydes Based on Fluorescence Quenching. J Fluoresc 33, 2253–2256 (2023). https://doi.org/10.1007/s10895-023-03219-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10895-023-03219-x

Keywords

Search

Navigation