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The Preparation and Nonlinear Properties Study of a Mixture of Polyurethane and Neutral Red Dye Solution

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Abstract

A mixture of polyurethane (PU) and neutral red (NR) dye solution is prepared. The nonlinear optical properties of the mixture of PU with NR dye solution are studied using a 473 nm laser beam of continuous fashion. The nonlinear refraction index of prepared material is determined via diffraction patterns and Z-scan. The diffraction patterns are calculated based on the Fresnel-Kirchhoff integral. Optical limiting of the prepared material is tested. All-optical switching occur in the sample using two low power visible laser beams.

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References

  1. Potember RS, Hoffman RC, Stetyick KA, Murphy RA (1988) Molecular materials for nonlinear optics. John Hopkin APL Techno Dig 9:189–198

    CAS  Google Scholar 

  2. Halasyamani SP, Zhang W (2017) Viewpoint inorganic material, for UV and Leep-UV nonlinear optical applications. Inorg Chem 56:12077–12085

    Article  CAS  PubMed  Google Scholar 

  3. Khoo IC (1994) Liquid crystal nonlinear optics. Act Phys Polon A 86:267–134

    Article  CAS  Google Scholar 

  4. Linke Li, Yang H, Song Y, Hou H, Fan Y (2006) Two cobalt(II) one-dimensional ribbon of rings polymers: Synthesis, structures and non-linear optical properties. Inorg Chim Acta 359:2135–2140

    Article  Google Scholar 

  5. Jiang L, Lu F, Gao Y, Song Y, Liu H, Gan H, Jiu T, Li Y, Li Y, Wang S, Zhu D (2006) Nonlinear optical properties of an ultrathin film containing porphyrin and poly (phenylenevinylene) units. Thin Solid Films 496:311–316

    Article  CAS  Google Scholar 

  6. Shi FW, Meng XJ, Wang GS, Sun JL, Lin T, Ma JH, Li YW, Chu JH (2006) The third-order optical nonlinearity of Bi 3.25La 0.75Ti3O12 ferroelectric thin film on quartz. Thin Solid Films 496:333–335

    Article  CAS  Google Scholar 

  7. Alsous MB, Zidan MD, Ajji Z, Allahham A (2014) Z-scan measurements of optical nonlinearity in acid blue 29 dye. Optik 125:5160–5163

    Article  CAS  Google Scholar 

  8. Zidan MD, Allaf AW, Alsous MB, Allahham A (2014) Investigation of optical nonlinearity and diffraction ring patterns of carbon nanotubes. Opt Las Technol 58:128–134

    Article  CAS  Google Scholar 

  9. Zidan MD, Al-Ktaifani MM, El-Daher MS, Allahham A, Ghanem A (2020) Diffraction ring patterns and nonlinear measurements of the Tris (2′, 2-bipyridyl) iron (II) tetrafluoroborate. Opt Las Technol 131:106449

    Article  CAS  Google Scholar 

  10. Hassan QMA, Palanisamy PK, Manickasundaram S, Kannan P (2006) Sudan IV dye based poly(alkyloxymethacrylate)films for optical data storage. Opt Commun 267:236–243

    Article  Google Scholar 

  11. Manickasundaram S, Kannan P, Hassan QMA, Palanisamy PK (2008) Azo dye based poly(alkyloxymethacrylate)s and their spacer effect on optical data storage. J Mater Sci Mater Electron 19:1045–1053

    Article  CAS  Google Scholar 

  12. Manickasundaram S, Kannan P, Kumaran R, Velu R, Ramamurthy P, Hassan QMA, Palanisamy PK, Senthil S, Narayanan SS (2011) Holographic grating studies in pendant xanthene dyes containing poly(alkyloxymethacrylate)s. J Mater Sci Mater Electron 22:25–34

    Article  CAS  Google Scholar 

  13. Kagami M (2004) Visible optical fiber communication. R&D Rev Toyota 40:1–6

    Google Scholar 

  14. Hassan QMA, Manshad RKH (2019) Surface morphology and optical limiting properties of azure B doped PMMA film. Opt Mater 92:22–29

    Article  CAS  Google Scholar 

  15. Hassan QMA, Manshad RKH (2015) Optical limiting properties of sudan red B in solution and solid film. Opt Quant Electron 47:297–311

    Article  CAS  Google Scholar 

  16. Al-Mudhaffer MF, Al-Ahmad AY, Hassan QMA, Emshary CA (2019) Optical characterization and all-optical switching of benzenesulfonamide azo dye. Optik 127:1160–1166

    Article  Google Scholar 

  17. Durbin SD, Arakelian SM, Shen YR (1981) Laser-induced diffraction rings from a nematic liquid-crystal film. Opt Lett 8:411–413

    Article  Google Scholar 

  18. Franko M, Tran CD (2010) Thermal lens spectroscopy, Encyclop. Analy. Chem. R. A. Meyers (Ed) John Wiley and Sons Ltd. 1–32

  19. Derkowska-Zielinska B, Barwiolek M, Cassagne C, Boudebs G (2020) Nonlinear optical study of Schiff bases using Z-scan technique. Opt Las Technol 124:105968 (7pp)

    Article  Google Scholar 

  20. Callen WR, Hutth BG, Pantell RH (1967) Optical patterens of thermally self -defocused light. Appl Phys Lett 11:103–105

    Article  Google Scholar 

  21. Sheik-Bahae M, Said AA, Van Stryland EW (1989) High sensitivity single beam n2 measurements. Opt Lett 14:955–957

    Article  CAS  PubMed  Google Scholar 

  22. Sheik-Bahae M, Said AA, Wei T, Hagan DJ, Van Stryland EW (1990) Sensitive measurement of optical nonlinearities using a single beam. IEEE J Quant Electron 26:760–769

    Article  CAS  Google Scholar 

  23. Shabeeb GM, Emshary CA, Hassan QMA, Sultan HA (2020) Investigating the nonlinear optical properties of poly eosin-Y phthalate solution under irradiation with low power visible CW laser light. Phys B 578:411847 (13pp)

    Article  Google Scholar 

  24. Sultan HA, Hassan QMA, Bakr H, Al-Asadi AS, Hashim DH, Emshary CA (2018) Thermal-induced nonlinearities in rose, linseed and chamomile oils using CW visible laser beam. Can J Phys 96:157–164

    Article  CAS  Google Scholar 

  25. Hassan QMA, Emshary CA, Sultan HA (2021) Investigating the optical nonlinear properties and limiting optical of eosin methylene blue solution using a cw laser beam. Phys Scr 96:095503 (16 pp)

    Article  Google Scholar 

  26. Emshary CA, Hassan QMA, Bakr H, Sultan HA (2021) Determination of the optical constants, nonlinear optical parameters and threshold limiting of methyl red-epoxy resin film. Phys B 622:413354 (8 pp)

    Article  Google Scholar 

  27. Al-Timimy KhA, Hassan QMA, Sultan HA, Emshary CA (2020) Solvents effect on the optical nonlinear properties of the sudan iv. Optik 224:165398 (15 pp)

    Article  Google Scholar 

  28. Abdulkader AF, Hassan QMA, Al-Asadi AS, Bakr H, Sultan HA, Emshary CA (2018) Linear, nonlinear and optical limiting properties of carbon black in epoxy resin. Optik 160:100–108

    Article  CAS  Google Scholar 

  29. Jebur JH, Hassan QMA, Al-Mudhaffer MF, Al-Asadi AS, Elias RS, Saeed BA, Emshary CA (2020) The gamma radiation effect on the surface morphology and optical properties of alphamethyl curcumin: PMMA film. Phys Scr 95:045804 (10pp)

    Article  Google Scholar 

  30. Khalaf SK, Hassan QMA, Emshary CA, Sultan HA (2022) Concentration effect on optical properties and optical limiting of PVA doped with nigrosin films. J Photochem Photob A Chem 427:113809 (11 pp)

    Article  Google Scholar 

  31. Kadhum AJ, Hussein NA, Hassan QMA, Sultan HA, Al-Asadi AS, Emshary CA (2018) Investigating the nonlinear behavior of cobalt (II) phthalocyanine using visible CW laser beam. Optik 157:540–550

    Article  CAS  Google Scholar 

  32. Elias RS, Hassan QMA, Emshary CA, Sultan HA, Saeed BA (2019) Formation and temporal evolution of diffraction ring patterns in a newly prepared dihydropyridone. Spectrochim Acta Part A Mol Biomol Spectrosc 223:117297 (16 pp)

    Article  Google Scholar 

  33. Saeed BA, Hassan QMA, Emshary CA, Sultan HA, Elias RS (2020) The nonlinear optical properties of two dihydropyridones derived from curcumin. Spectrochim Acta Part A Mol Biomol Spectrosc 240:118622 (14 pp)

    Article  Google Scholar 

  34. Almashal FA, Mohammed MQ, Hassan QMA, Emshary CA, Sultan HA, Dhumad AM (2020) Spectroscopic and thermal nonlinearity study of a Schiff base compound. Opt Mater 100:109703 (12 pp)

    Article  Google Scholar 

  35. Jassem AM, Hassan QMA, Emshary CA, Sultan HA, Almashal FA, Radhi WA (2021) Synthesis and optical nonlinear properties performance of azonaphthol dye. Phys Scr 96:025503 (20 pp)

    Article  Google Scholar 

  36. Sultan HA, Dhumad AM, Hassan QMA, Fahad T, Emshary CA, Raheem NA (2021) Synthesis, characterization and the nonlinear optical properties of newly synthesized 4-((1,3-dioxo-1-phenylbutan-2-yl)diazenyl) benzenesulfonamide. Spectrochim Acta Part A Mol Biomol Spectrosc 251:119487 (15 pp)

    Article  Google Scholar 

  37. Mutlaq DZ, Hassan QMA, Sultan HA, Emshary CA (2021) The optical nonlinear properties of a new synthesized azo-nitrone compound. Opt Mater 113:110815 (13 pp)

    Article  Google Scholar 

  38. Dhumad AM, Hassan QMA, Emshary CA, Fahad T, Raheem NA, Sultan HA (2021) Nonlinear optical properties investigation of a newly synthesised Azo-(β)- diketone dye. J Photochem Photobio A Chem 418:113429 (17 pp)

    Google Scholar 

  39. Dhumad AM, Hassan QMA, Fahad T, Emshary CA, Raheem NA, Sultan HA (2021) Synthesis, structural characterization and optical nonlinear properties of two azo- β-diketones. J Mol Struct 1235:130196 (9 pp)

    Article  Google Scholar 

  40. Al-Hamdani UJ, Hassan QMA, Emshary CA, Sultan HA, Dhumad AM, Al-Jaber AA (2021) All optical switching and the optical nonlinear properties of 4-(benzothiazolyldiazenyl)-3-chlorophenyl 4-(nonylthio)benzoate (EB-3Cl). Optik 248:168196 (17 pp)

    Article  Google Scholar 

  41. Hassan QMA, Raheem NA, Emshary CA, Dhumad AM, Sultan HA, Fahad T (2022) Preparation, DFT and optical nonlinear studies of a novel azo-(β)- diketone dye. Opt Las Technol 148:107705 (14 pp)

    Article  Google Scholar 

  42. Abdullmajed HA, Sultan HA, Al-Asadi RH, Hassan QMA, Ali AA, Emshary CA (2022) Synthesis, DFT calculations and optical nonlinear properties of two derived Schiff base compounds from ethyl-4-amino benzoate. Phys Scr 97:025809 (18 pp)

    Article  Google Scholar 

  43. Jia Y, Shan Y, Wu L, Dai X, Fan D, Xiang Y (2018) Broad band nonlinear optical resonance and all-optical switching of liquid phase exfoliated tungsten diselenide. Phot Res 6:1040–1046

    Article  CAS  Google Scholar 

  44. Waang Q, Wu X, Wu L, Xiang Y (2019) Broadband nonlinear optical response in Bi2Se3-Bi2Te3 heterastructure and it’s application in all-optical switching. AIP Adv 9:025022 (7 pp)

    Google Scholar 

  45. El-Fadl AA, Mohamad GA, El-Moiz ABA, Rashad M (2005) Optical constants of Zn1-xLixO films prepared by chemical bath deposition technique. Phys B 366:44–54

    Article  Google Scholar 

  46. Santamato E, Shen YR (1984) Field-curvature effect on the diffraction ring patterns of a laser beam dressed by spatial self-phase modulation in a nematic film. Opt Lett 9:564–566

    Article  CAS  PubMed  Google Scholar 

  47. Deng L, He K, Zhon T, Li C (2005) Formation and evolution of far-field diffraction patterns of divergent and conver Gaussian beams passing through self-focusing and self-defocusing media. J Opt Aipure Appl Opt 7:409–415

    Article  Google Scholar 

  48. Shan Y, Tang J, Wa L, Ln S, Dain X (2014) Spatial self-phase nodulation and all-optical switching of graphene oxciz dimensional martials. J Cent South Univ 26:2295–2306

    Google Scholar 

  49. Jia Y, Liao Y, Wu L, Shan Y, Dai X, Cai H, Xiang Y, Fan D (2019) Nonlinear optical response, all optical switching, and all optical information conversion in NbSe2 nanosheets based on spatial self-phase modulation. Nanoscale 11:4515–4522

    Article  CAS  PubMed  Google Scholar 

  50. Ogusu K, Kohtani Y, Shao H (1996) Laser-induced diffraction rings from an absorbing solution. Opt Rev 3:232–234

    Article  CAS  Google Scholar 

  51. Karimzadeh R (2012) Spatial self-phase modulation of a laser beam propagation through liquids with self-induced natural convection flow. J Opt 14:095701 (9 pp)

    Article  Google Scholar 

  52. Karimzadeh R (2013) Studies of spatial self-phase modulation of a laser beam passing through liquids. Opt Commun 286:329–333

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, College of Science, University of Basrah, Basrah, 61001, Iraq

    Kh. A. Al-Timimy, Ali Qassim Abdullah & Emad Abdul Reaz Arebi

  2. Department of Physics, College of Education for Pure Sciences, University of Basrah, Basrah, 61001, Iraq

    H. A. Sultan, Qusay M. A. Hassan & C. A. Emshary

Authors
  1. Kh. A. Al-Timimy
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  2. H. A. Sultan
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  3. Qusay M. A. Hassan
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  4. C. A. Emshary
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  5. Ali Qassim Abdullah
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Contributions

Kh. A. Al-Timimy and H. A. Sultan wrote the manuscript, Qusay M. A. Hassan participated in the characterization and analysis of the results, C. A. Emshary wrote the main manuscript text – review & editing and Ali Qassim Abdullah and Emad Abdul Reaz Arebi prepared Figs. 1, 2 and 3. All authors reviewed the manuscript.

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Correspondence to Qusay M. A. Hassan.

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Al-Timimy, K.A., Sultan, H.A., Hassan, Q.M.A. et al. The Preparation and Nonlinear Properties Study of a Mixture of Polyurethane and Neutral Red Dye Solution. J Fluoresc 33, 1761–1776 (2023). https://doi.org/10.1007/s10895-023-03189-0

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