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CTV Based Sensor for the Detection of Ni2+ Ions With Real Sample Analysis Based on Mechanism of Fluorescence Along with Computational Insights

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Abstract

Identification and detection of harmful contaminants such as nickel and other materials from soil and water is critical necessity at the present moment. So with this motive to detect and identify harmful pollutants, a novel cyclotriveratrylene based derivative was prepared for the detection and binding of harmful pollutants which had the properties of fluorescence. The newly derivative of Cyclotriveratrylene was found to be highly sensitive and selective towards Ni2+ ions. The complexation behaviour of this newly synthesised molecule was studied in presence of transition elements. Also computational methods such as docking, molecular modelling and DFT were used to study the molecular orbitals and energies of CTG-NBEP. The detection of Ni2+ from water samples were also carried out successfully.

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References

  1. Lee MH, Kim JS, Sessler JL (2015) Small molecule-based ratiometric fluorescence probes for cations, anions, and biomolecules. Chem Soc Rev 44(13):4185–4191. https://doi.org/10.1039/C4CS00280F

  2. Babich H, Stotzky G (1983) Toxicity of nickel to microbes: environmental aspects. Adv Appl Microbiol 29:195–265. https://doi.org/10.1016/S0065-2164(08)70358-7

  3. Salins LL et al (2002) A fluorescence-based sensing system for the environmental monitoring of nickel using the nickel binding protein from Escherichia coli. Anal Bioanal Chem 372(1):174–180. https://doi.org/10.1007/s00216-001-1169-7

  4. US Department of Health and Human Services (1996) Toxicological profile for nickel. Public Health Service, Atlanta, GA, US Department of Health and Human Services

    Google Scholar 

  5. Environmental Protection Agency (1983) Methods for the analysis of water and wastes. Environmental Protection Agency, Washington DC

    Google Scholar 

  6. Mrzljak RI et al (1994) On-line and off-line voltammetric methods for the determination of nickel in zinc plant electrolyte. Analyst 119(5):1057–1061. https://doi.org/10.1039/AN9941901057

  7. Panchal M et al (2016) Turn-off fluorescence probe for the selective determination of pendimethalin using a mechanistic docking model of novel oxacalix [4] arene. RSC Adv 6(58):53573–53577. https://doi.org/10.1039/C6RA05707A

  8. Quang DT, Kim JS (2010) Fluoro-and chromogenic chemodosimeters for heavy metal ion detection in solution and biospecimens. Chem Rev 110(10):6280–6301. https://doi.org/10.1021/cr100154p

  9. Lee YH et al (2010) Pyrene excimer-based calix [4] arene FRET chemosensor for mercury (II). J Org Chem 75(21):7159–7165. https://doi.org/10.1021/jo101113f

  10. Kumar R et al (2019) Revisiting fluorescent calixarenes: from molecular sensors to smart materials. Chem Rev 119(16):9657–9721. https://doi.org/10.1021/acs.chemrev.8b00605

  11. Sutariya PG et al (2013) Fluorescence switch on–off–on receptor constructed of quinoline allied calix [4] arene for selective recognition of Cu 2+ from blood serum and F− from industrial waste water. Analyst 138(9):2531–2535. https://doi.org/10.1039/C3AN00209H

  12. Birnbaum GI et al (1985) Crystal structure and infrared spectra of an inclusion compound of cyclotriveratrylene and water. Can J Chem 63(11):3258–3263. https://doi.org/10.1139/v85-539

  13. Moriuchi-Kawakami T et al (2019) AC 3-substituted cyclotriveratrylene derivative with 8-quinolinyl groups as a fluorescence-enhanced probe for the sensing of Cu 2+ ions. Analyst 144(4):1140–1146. https://doi.org/10.1039/C8AN01615A

  14. Muhammad S, Liu C, Zhao L, Wu S, Su Z (2009) A theoretical investigation of intermolecular interaction of a phthalimide based on–off sensor with different halide ions: tuning its efficiency and electro-optical properties. Theor Chem Accounts 122:77–86. https://doi.org/10.1007/s00214-008-0486-8

    Article  CAS  Google Scholar 

  15. Pérez-Ruiz R, Díaz Y, Goldfuss B, Hertel D, Meerholz K, Griesbeck AG (2009) Fluoride recognition by a chiral urea receptor linked to a phthalimide chromophore. Org Biomol Chem 7:3499–3504. https://doi.org/10.1039/B908433A

    Article  PubMed  Google Scholar 

  16. Bühlmann P, Pretsch E, Bakker E (1998) Carrier-based ion-selective electrodes and bulk optodes. 2. Ionophores for potentiometric and optical sensors. Chem Rev 98:1593–1688. https://doi.org/10.1021/cr970113+

  17. Liu X, Zhang N, Zhou J, Chang T, Fang C, Shangguan D (2013) A turn-on fluorescent sensor for zinc and cadmium ions based on perylene tetracarboxylic diimide. Analyst 138:901–906. https://doi.org/10.1039/C2AN36203A

    Article  CAS  PubMed  Google Scholar 

  18. Blaney Jeff (2012) A very short history of structure-based design: how did we get here and where do we need to go?. J Comput Aided Mol Des 26(1):13–14. https://doi.org/10.1007/s10822-011-9518-x

    Article  CAS  PubMed  Google Scholar 

  19. Mandal S, Mandal SK (2009) Rational drug design. Eur J Pharmacol 625(1–3):90–100. https://doi.org/10.1016/j.ejphar.2009.06.065

  20. Chakrabarti A et al (2005) Convenient synthesis of selectively substituted tribenzo [a, d, g] cyclononatrienes. Tetrahedron 61(52):12323–12329. https://doi.org/10.1016/j.tet.2005.09.101

  21. Diaz P, Yrene H (2009) New Phthalimide-based Sensors for Chiral and Achiral Anions and Peroxides. Universität zu Köln, Diss

  22. Hanwell MD, Curtis DE, Lonie DC et al (2012) Avogadro: an advanced semantic chemical editor, visualization, and analysis platform. J Cheminform 4:17. https://doi.org/10.1186/1758-2946-4-17

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  23. Neese F (2012) The ORCA program system,Wiley Interdiscip. Rev Comput Mol Sci 2:73–78. https://doi.org/10.1002/wcms.81

  24. Szabo A, Ostlund NS (1989) Modern Quantum Chemistry: Introduction to Advanced Electronic Structure Theory. Dover Publications. http://books.google.de/books?id=6mV9gYzEkgIC

  25. Mayer I (1983) Charge, bond order and valence in the AB initio SCF theory. Chem Phys Lett 97(3):270–274. https://doi.org/10.1016/0009-2614(83)80005-0

    Article  CAS  Google Scholar 

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Acknowledgement

The authors thank COENFDD, Rajkot, O2H and Gujarat University for providing instrumental Facilities and library journals

Funding

The research was supported by Gujarat University-Ahmedabad India.

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Authors and Affiliations

  1. Department of Chemistry, School of Sciences, Gujarat University, Ahmedabad, 380009, Gujarat, India

    Patrick F. Fernandes & Divya R. Mishra

Authors
  1. Patrick F. Fernandes
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  2. Divya R. Mishra
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Contributions

Patrick F. Fernandes: (Supervision, investigation designed and directed the study, planned and carried out the experiments, wrote the manuscript). Dr. Divya R. Mishra: (Supervision, designed and directed the study, contributed to the interpretation of the results and characterized of the molecules). The author(s) read and approved the final manuscript.

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Correspondence to Patrick F. Fernandes.

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Fernandes, P.F., Mishra, D.R. CTV Based Sensor for the Detection of Ni2+ Ions With Real Sample Analysis Based on Mechanism of Fluorescence Along with Computational Insights. J Fluoresc 32, 583–592 (2022). https://doi.org/10.1007/s10895-021-02858-2

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  • DOI: https://doi.org/10.1007/s10895-021-02858-2

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