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Surface-Modified Colloid CdTe/CdS Quantum Dots by a Biocompatible Thiazolidine Derivative as Promising Platform for Immobilization of Glucose Oxidase: Application to Fluorescence Sensing of Glucose

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Abstract

This work focuses on the synthesis of novel modified core–shell CdTe/CdS quantum dots (QDs) and develops as a fluorescence sensor for glucose determination. The (E)-2,2'-(4,4'-dioxo-2,2'-dithioxo-2H,2'H-[5,5'-bithiazolylidene]-3,3'(4H,4'H)-diyl)bis(3- mercaptopropanoic acid) (DTM) as a new derivative of thiazolidine was synthesized and characterized and used to surface-modification of CdTe/CdS QDs. DTM-capped CdTe/CdS QDs used to immobilization of glucose oxidase (GOD). The intensity fluorescence emission of the CdSe/CdS-DTM/GOD is highly sensitive to the concentration of H2O2 as a byproduct of the catalytic oxidation of glucose. The experimental results showed that the quenched fluorescence was proportional to the glucose concentration within the range of 10 nM—0.32 μM under optimized experimental conditions. The limit of detection of this system was found to be 4.3 nM. Compared with most of the existing methods, this newly developed system possesses many advantages, including simplicity, low cost, and good sensitivity.

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Acknowledgements

The financial support of the Iranian Nanotechnology Initiative and Research Office of the University of Kurdistan are gratefully acknowledged.

Funding

The authors declare that, this research received no specific grant from any funding agency.

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Authors and Affiliations

  1. Department of Chemistry, University of Kurdistan, P.O. Box 416, Sanandaj, Iran

    Rahman Hallaj & Zahra Hosseinchi

  2. Nanotechnology Research Center, University of Kurdistan, P.O. Box 416, Sanandaj, Iran

    Rahman Hallaj

Authors
  1. Rahman Hallaj
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  2. Zahra Hosseinchi
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All authors contributed to the study conception design and data acquisition.

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Correspondence to Rahman Hallaj.

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Hallaj, R., Hosseinchi, Z. Surface-Modified Colloid CdTe/CdS Quantum Dots by a Biocompatible Thiazolidine Derivative as Promising Platform for Immobilization of Glucose Oxidase: Application to Fluorescence Sensing of Glucose. J Fluoresc 31, 1805–1813 (2021). https://doi.org/10.1007/s10895-021-02805-1

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  • DOI: https://doi.org/10.1007/s10895-021-02805-1

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