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Role of Substituent Position in Coumarin Derivatives during their Interaction with TiO2 Nano Particles

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Abstract

The effect of position of benzo group in coumarin derivatives, 5,6 benzo-4-azidomethyl coumarin (5BAMC) and 7,8 benzo-4-azidomethyl coumarin (7BAMC) during their interaction with TiO2 nanoparticles in ethyl acetate, tetrahydrofuran, butan-1-ol and acetonitrile solvents has been studied using different spectroscopic methods and electrochemical analysis. Benesi-Hildebrand plots indicate that nature of interaction between 7BAMC and TiO2 is 1:2 in solvent with low dielectric constant whereas for 5BAMC and TiO2, it is 1:1 in all the solvents. From the fluorescence quenching study and binding equilibria analysis, it is observed that interaction between 5BAMC and TiO2 depends on the dielectric constant of the solvent. Time resolved quenching study reveals that quenching is dynamic for 5BAMC in solvent with high dielectric constant. Whereas for 7BAMC, it is dynamic in solvent with low dielectric constant. Hence the nature of interaction of these two coumarin derivatives with TiO2 NPs is different. From electrochemical analysis, it is observed that, free energy change for electron transfer is more negative for 5BAMC-TiO2 compared to 7BAMC-TiO2 therefore quenching is more efficient for 5BAMC-TiO2 compared to 7BAMC-TiO2 system, which is also confirmed from fluorescence quenching studies. Non-radiative energy transfer rate is more than radiative energy transfer rate for both the systems according to FRET study.

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All data recorded and analysed in this article are already included. Further for any clarification, data recorded or analysed during the current study are available from the corresponding author on reasonable request.

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Authors and Affiliations

  1. Department of Physics, Karnatak Science College, Dharwad, Karnataka, 580001, India

    Nirupama M. Jagadeeshwar

  2. Department of Chemistry, Karnatak University, Dharwad, Karnataka, 580003, India

    Netravati I. Khanapurmath & Manohar V. Kulkarni

  3. Department of Physics, Karnatak University, Dharwad, Karnataka, 580003, India

    Lakkanna S. Chougala & Jagadish S. Kadadevarmath

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  1. Nirupama M. Jagadeeshwar
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  2. Netravati I. Khanapurmath
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  3. Lakkanna S. Chougala
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  4. Manohar V. Kulkarni
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  5. Jagadish S. Kadadevarmath
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Contributions

All authors contributed to this work. Conceptualization: [Dr. Nirupama Jagadeeshwar M.], Synthesis of coumarin derivative [Dr. Netravati I. Khanapurmath], Formal analysis of the results and investigation [Dr. Nirupama Jagadeeshwar M. and Dr. Lakkanna S. Chougala], Writing-original draft preparation [Dr. Nirupama Jagadeeshwar M.]; review, suggestions and supervision [Prof. Manohar V. Kulkarni, Prof. Jagadish S. Kadadevarmath]. All authors read and approved the final manuscript.

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Correspondence to Nirupama M. Jagadeeshwar.

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Jagadeeshwar, N.M., Khanapurmath, N.I., Chougala, L.S. et al. Role of Substituent Position in Coumarin Derivatives during their Interaction with TiO2 Nano Particles. J Fluoresc 31, 775–785 (2021). https://doi.org/10.1007/s10895-021-02706-3

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