Abstract
Novel isonicotinic acid hydrazide functionalized silver nanoparticles (INH-AgNPs) were synthesized by wet chemical method and used for the detection of Hg2+ ions in aqueous medium. The INH-AgNPs exhibit good absorbance and emission peaks by sensing Hg2+ ions with visible color changes. The detection of Hg2+ ions was confirmed by FT-IR, EDAX spectra and by the changing morphology of INH-AgNPs, and after addition of Hg2+ was confirmed by SEM and TEM imaging studies. Based on the emission intensity the probe INH-AgNPs exhibit a lowest detection limit (LOD) of Hg2+ to 0.18 nM. The association constant (Ka) of INH-AgNPs + Hg2+ ions is calculated using the Bensei-Hildebrand equation. Also, the probe is successfully utilized for the detection of Hg2+ ions in real water samples obtained from different fields, which showed good results.
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Grandjean P, Weihe P, White RF, Debes F (1998) Cognitive performance of children prenatally exposed to “safe” levels of methylmercury. Environ Res 77:165–172
Zhao B, Zhou YC, Fan MJ, Li ZY, Wang LY, Deng QG (2013) Synthesis, fluorescence properties and selective Cr(III) recognition of tetraaryl imidazole derivatives bearing thiazole group. Chin Chem Lett 24:257–259
Wang Y, Zhang L, Zhang G, Wu Y, Wu S, Yu J, Wang L (2014) A new colorimetric and fluorescent bifunctional probe for Cu2+ and F− ions based on perylene bisimide derivatives. Teterahedron Lett 55:3218–3222
Ahmed SW, Shama HA, Siddiqui A, Shah MR, Ahmed A, Ali SA (2018) Synthesis and chemosensing of nitrofurazone using olive oil based silver nanoparticles (O-AgNPs). Sensors and Actuators B Chem 256:429–439
Dainel MC, Astruc D (2004) Gold nanoparticles: assembley, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology. Chem Rev 104:293–346
Ateeq M, Shah MR, Ain N, Bano S, Lubna IA, Faizi S, Bertino MF, Naz SS (2015) Green synthesis and molecular recognition ability of patuletin coated gold nanoparticles. Biosens Bioelectron 63:499–505
Ain N, Anis I, Ahmad F, Shah MR, Parveen S, Faizi S, Ahmeed S (2018) Colorimetric detection of amoxicillin based on Querecteagetin coated silver nanoparticles. Sensors and Actuators B Chem 265:617–624
Basiri S, Mehdinia A, Jabbari A (2018) A sensitive triple colorimetric sensor based on plasmonic response quenching of green synthesized silver nanoparticles for determination of Fe2+, hydrogen peroxide, and glucose. Sensors and Actuators B Chem 545:138–146
Guzmán MG, Dille J, Godet S (2009) Synthesis of silver nanoparticles by chemical reduction method and their antibacterial activity. Int J Chem Biomol Eng 2:104–111
Navaladian S, Viswanathan B, Viswanath R, Varadarajan T (2007) Thermal decomposition as route for silver nanoparticles. Nanoscale Res Lett 2:44–48
Sreeram K, Nidhin M, Nair B (2008) Microwave assisted template synthesis of silver nanoparticles. Bull Mater Sci 31:937–942
Tharmaraj V, Pitchumani K (2013) A highly selective ratiometric fluorescent chemosensor for cu(II) based on dansyl-functionalized thiol stabilized silver nanoparticles. J Mater Chem B 1:1962–1967
Cheng ZH, Li G, Zhang N, Liu H (2014) A novel functionalized silver nanoparticles solid chemosensor for detection of Hg(II) in aqueous media. Dalton Trans 43:4762–4769
Tharmaraj V, Pitchumani K (2011) Alginate stabilized silver nanocube-Rh6G composite as a highly selectivemercury sensor in aqueous solution. Nanoscale 3:1166–1170
Kaur N, Kaur S, Kaur A, Saluja P, Sharma H, Saini A, Dhariwal N, Singh A, Singh N (2014) Nanoparticle-based, organic receptor coupled fluorescent chemosensors for the determination of phosphate. Journal of Lumin 145-175-179
Sondi I, Sondi BS (2004) Silver nanoparticles as antimicrobial agent: a case study on E. coli as a model for gram-negative bacteria. J Coll Inter Sci 275:177–182
McFarland AD, Van Duyne RP (2003) Single silver nanoparticles as real-time optical sensors with Zeptomole sensitivity. Nano Lett 3:1057–1062
Sung Y, Wu S (2014) Highly selective and sensitive colorimetric detection of Ag(I) using N-1-(2-mercaptoethyl)adenine functionalized gold nanoparticles. Sensors and Actuators B Chem 197:172–176
Thompson DG, Enright A, Faulds K, Smith WE, Graham D (2008) Ultrasensitive DNA detection using oligonucleotide-silver nanoparticle conjugates. Anal Chem 80:2805–2810
Vasimalai N, Sheeba G, John SA (2012) Ultrasensitive fluorescence-quenched chemosensor for Hg(II) in aqueous solution based on mercaptothiadiazole capped silver nanoparticles. J Haz Mater 213-214:193–199
Dong Y, Ding L, Jin X, Zhu N (2017) Silver nanoparticles capped with chalcon carboxylic acid as a probe for colorimetric determination of cadmium (II). Microchim Acta 184:3357–3362
El-Shekheby HA, Mangood AH, Hamza SM, Al-Kady AS, Ebeid EM (2014) A highly efficient and selective turn-on fluorescent sensor for Hg2+, Ag+ and Ag nanoparticles based on a coumarin dithioate derivative. Luminescence 29:158–167
Makwana BA, Vyas DJ, Bhatt KD, Jain VK, Agrawal YK (2015) Highly stable antibacterial silver nanoparticles as selective fluorescent sensor for Fe3+ ions. Spec Acta Part A Mol Bio Spec 134:73–80
Niaz A, Bibi A, Zaman MI, Khan M, Rahim A (2018) Highly selective and ecofriendly colorimetric method for the detection of iodide using green tea synthesized silver nanoparticles. J Mol Liq 249:1047–1051
Dai B, Cao Q, Wang L, Wang Z, Yang Z (2014) A new naphthalene containing triazolophane for fluorescence sensing of mercury (II) ion. Inorg Chim Acta 423:63–167
Qin J, Yang Z, Wang G, Li C (2015) FRET-base rhodamine-coumarin conjugate as a Fe3+ selective ratiometric fluorescent sensor in aqueous media. Teterahedron Lett 56:5024–5029
Sakthivel P, Sekar K, Sivaraman G, Singaravadivel S (2017) Rhodamine Diaminomaleonitrile conjugate as a novel colorimetric fluorescent sensor for recognition of Cd2+ ion. J Fluoresc 27:1109–1115
Bhalla V, Tejpal R, Kumar M (2010) Rhodamine appended terphenyl: a reversible “off-on” fluorescent chemosensor for mercury ions. Sens Actuators B Chem 151:180–185
Wang L, Yan JX, Qin W, Liu W, Wang R (2012) A new rhodamine-based single molecule multianalyte (Cu2+, Hg2+) sensor and its application in the biological system. Dyes Pigments 92:1083–1090
Yang H, Zhou Z, Huang K, Yu M, Li F, Yi T, Huang C (2007) Multisignaling optical electrochemical sensor for Hg2+ based on a Rhodamine derivative with a ferrocene unit. Org Lett 9:4729–4732
Chen X, Pradhan T, Wang F, Kim JS, Yoon J (2012) Fluorescent Chemosensors based on Spiroring-opening of Xanthenes and related derivatives. J Chem Rev 112:1910–1956
Mercury Update (2001) Impact on fish advisories; EPA fact sheet EPA-8230F-01-001; Environmental Protection Agency. Office of water, Washington, DC
De Silva AP, Gunaratne HQN, Gunnlaugsson T, Huxley AJM, McCoy CP, Rademacher JT, Rice TE (1997) Signaling recognition events with fluorescent sensors and switches. Chem Rev 97:1515–1566
Lakowicz JR (2006) Principles of fluorescence spectroscopy, 3rd edn. Springer
Wang C, Zhang D, Huang X, Ding P, Wang Z, Zhao Y, Ye Y (2014) Ratiometricfluorescent chemosensor for Hg2+ based on FRET and its application in living cells. Sens and Actutators B Chem 198:33–40
Balamurugan A, Lee H (2015) Single molecular probe for multiple analyte sensing: efficient and selective detection of mercury and fluoride ion. Sens and actutators B Chem 216:80–85
Vengaian KM, Britto CD, Sekar K, Sivaraman G, Singaravadivel S (2016) Phenothiazine-diaminomalenonitrile base colorimetric and fluorescence “turn-off-on” sensing of Hg2+ and S2−. Sens and actutators B Chem 235:232–240
Kaushik R, Singh A, Ghosh A, Jose DA (2016) Selective colorimetric sensor for the detection of Hg2+ and H2S in aqueous medium and waste water samples. Chemistry Select 1:1533–1540
Muthu Vengaian K, Denzil Britto C, Sivaraman G, Sekar K, Singaravadivel S (2016) Fluorescence “on–off–on” chemosensor for selective detection of Hg2+ and S2−: application to bioimaging in living cells. RSC Adv 6:7668–7673
Sakthivel P, Sekar K, Sivaraman G, Singaravadivel S (2018) Rhodamine-benzothiazole conjugate as an efficient multimodal sensor for Hg2+ ions and its application to imaging in living cells. New J Chem 42:11665–11672
Seung J, Han MS, Mirkin CA (2007) Colorimetric detection of mercuric ion (Hg2+) in aqueous media using DNA-functionalized gold nanoparticles. Angew Chem Int Ed 46:4093–4096
Bothra S, Solanki JN, Sahoo SK (2013) Functionalized silver nanoparticles as Chemosensor for pH, Hg2+ and Fe3+ in aqueous medium. Sensors and Actuators B Chem 188:937–943
Sebastian M, Aravind A, Mathew B (2018) Green silver nanoparticles based dual sensor for toxic hg (II) ions. Nanotechnology 29:29
Tian K, Siegel G, Tiwari A (2017) A simple and selective colorimetric mercury (II) sensing system based on chitosan stabilized gold nanoparticles and 2,6-pyridine dicarboxylic acid. Mater Sci Eng C 71:195–199
Nie K, Dong B, Shi H, Liu Z, Liang B (2017) Diketopyrrolopyrrole Amphiphile-based micelle-like fluorescent nanoparticles for selective and sensitive detection of mercury(II) ions in water. Anal Chem 89:2928–2936
Zeynali KA, Amini R (2017) A novel voltammetric sensor for Hg(II) based on mercaptocarboxylic acid intercalated layered double hydroxide nanoparticles modified electrode. Sens and actutators B Chem 246:961–968
Brouwer AM (2011) Standards for photoluminescence yield measurements in solution. Pure Appl Chem 83:2213–2228
Nolan EM, Lippard SJ (2003) A “turn-on” fluorescent sensor for the selective detection of mercuric ion in aqueous media. J Am Chem Soc 125:14270–14271
Acknowledgments
The authors are grateful thanks to UGC, New Delhi (UGC-MRP No. 43-186/2014 (SR)) for the financial assistance through the Major Research Project (MRP).
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Sakthivel, P., Sekar, K. A Sensitive Isoniazid Capped Silver Nanoparticles - Selective Colorimetric Fluorescent Sensor for Hg2+ Ions in Aqueous Medium. J Fluoresc 30, 91–101 (2020). https://doi.org/10.1007/s10895-019-02473-2
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DOI: https://doi.org/10.1007/s10895-019-02473-2