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Perylene Derivative Dyes Luminescence in Polysiloxane Matrix in Presence of Gold Nanoparticles

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Abstract

Four perylene derivatives, including commercially available dyes Lumogen Red and Lumogen Orange, as well as 1,6,7,12-tetrachlоrоperylene-3,4,9,10-tetradicarboxydianhydride (Dye I) and 3,4:9,10-bis(1,2-benzimidazole)- 1,6,7,12-tetra(4-tert-octylphenoxy) perylene (syn/ anti-isomers) (Dye III, which was prepared from dye I through intermediate 3,4:9,10-bis(1,2-benzimidazole)-1,6,7,12-tetrachloro perylene (Dye II)) were used for preparation of polysiloxane samples (PSi) containing different concentrations of gold nanoparticles (GN). Dyes I and III demonstrate significant fluorescence intensity increase upon addition of GN independent on excitation energy. For Lumogen Red composition in PSi some increase of fluorescence intensity was observed upon addition of small concentrations of GN, while further increase of GN concentration quenches fluorescence. The increase of Lumogen Red emission intensity, which depends on energy of excitation, is probably due to the increase of radiation decay rate since excitation rate decreases. Effect of GN on Lumogen Orange provided quenching of fluorescence even at small concentrations of GN. Calculations at DFT level of approximation for dye III suggest location of GN in plane of perylene core for increase of fluorescence intensity.

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Acknowledgments

This work was supported by the Ministry of Education and Science of the Republic of Kazakhstan. Authors would like to thank the National Scientific Laboratory of Shared Utilization of Informational and Space Technologies at KazNTU (Kazakh National Technical University) for providing computational resources and Institute of Nuclear Physics, Astana branch for making SEM images.

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Authors and Affiliations

  1. Laboratory of Physical and Quantum Chemistry, L.N. Gumilyov Eurasian National University, Kazhymukan 13, Astana, Kazakhstan, 010008

    Artur Mantel, Nazerke Shautenbaeva, Irina Irgibaeva, Albina Lang & Iskander Mukatayev

  2. Luminescent materials research center Ltd., Pushkin 37/1, Astana, Kazakhstan, 010008

    Artur Mantel, Irina Irgibaeva & Nikolay Barashkov

  3. Department of Technical Physics, L.N. Gumilyov Eurasian National University, Kazhymukan 13, Astana, Kazakhstan, 010008

    Anuar Aldongarov

  4. Micro-Tracers, Inc., 1370 Van Dyke Ave, San Francisco, CA, 94124, USA

    Nikolay Barashkov

Authors
  1. Artur Mantel
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  2. Nazerke Shautenbaeva
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  3. Irina Irgibaeva
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  4. Anuar Aldongarov
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  5. Albina Lang
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  6. Nikolay Barashkov
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  7. Iskander Mukatayev
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Correspondence to Anuar Aldongarov.

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Mantel, A., Shautenbaeva, N., Irgibaeva, I. et al. Perylene Derivative Dyes Luminescence in Polysiloxane Matrix in Presence of Gold Nanoparticles. J Fluoresc 26, 2213–2223 (2016). https://doi.org/10.1007/s10895-016-1917-x

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  • DOI: https://doi.org/10.1007/s10895-016-1917-x

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