Skip to main content
Log in

A Simple Fluorescence Probe Based on Aggregation-Induced Emission (AIE) Property for the Detection of Mg2+ Ions

  • SHORT COMMUNICATION
  • Published:
Journal of Fluorescence Aims and scope Submit manuscript

Abstract

A simple aggregation-induced emission-based fluorescence probe (1) for Mg2+ was synthesized by condensation of benzene-1, 2-diamine with 5-bromo-2-hydroxybenzaldehyde, This compound shows favourable character of the AIE-active molecules. More importantly, after addition of Mg2+ to probe (1) in acetonitrile, the solution changed from colorless to yellow colour solution under ultraviolet (UV) radiation obtained from hand-held UV lamp, this finding suggested that probe (1) can be used to detect Mg2+ by colorimetric detection. Detection limit can reach 2.31 × 10−5 M−1. The practical value of the selective and sensitive fluorescence indicators was confirmed by its application to detection of magnesium ion in acetonitrile.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Scheme 2

References

  1. Luo JD, Xie ZL, Lam JWY, Cheng L, Chen HY, Qiu CF, Kwok HS, Zhan XW, Liu YQ, Zhu DB, Tang BZ (2001) Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole. Chem Commun 18: 1740–1741

  2. Song PS, Chen XT, Xiang Y, Huang L, Zhou ZJ, Wei RR, Tong AJ (2011) A ratiometric fluorescent pH probe based on aggregation-induced emission enhancement and its application in live-cell imaging. J Mater Chem 21:13470–13475

    Article  CAS  Google Scholar 

  3. Peng L, Zhou ZJ, Wei RR, Li K, Song PS, Tong AJ (2014) A fluorescent probe for thiols based on aggregation-induced emission and its application in live-cell imaging. Dyes Pigments 108:24–31

    Article  CAS  Google Scholar 

  4. Xi DX, Ran ZJ, Jin Z, Zhang XB, An DL (2013) A simple fluorescent probe for Zn(II) based on the aggregation-induced emission. Dyes Pigments 96:495–499

    Article  Google Scholar 

  5. Gong WT, Zhang QL, Shang L, Gao B, Ning GL (2013) A new principle for selective sensing cyanide anions based on 2-hydroxy-naphthaldeazine compound. Sensors Actuators B Chem 177:322–326

    Article  CAS  Google Scholar 

  6. Li H, Guo Y, Li GX, Xiao HP, Lei YX, Huang XB, Chen JX, Wu HY, Ding JC, Cheng YX (2015) Aggregation-induced fluorescence emission properties of dicyanomethylene-1,4-dihydropyridine derivatives. J Phys Chem C 119:6737–6748

    Article  CAS  Google Scholar 

  7. Zhai DP, Yang J, Guo ZY, Wang QS, Ouyang J (2014) A fluorescent probe for the detection of Mg(II) and Cu(II) and its application for imaging in living cells. RSC Adv 4:46800–46805

    Article  CAS  Google Scholar 

  8. Men GW, Chen CR, Zhang ST, Liang CS, Wang Y, Deng MY, Shang HX, Yang B, Jiang SM (2015) A real-time fluorescent sensor specific to Mg2+: crystallographic evidence, DFT calculation and its use for quantitative determination of magnesium in drinking water. Dalton Trans 44:2755–2762

    Article  PubMed  CAS  Google Scholar 

  9. Zhao Y, Zheng BZ, Du J, Xiao D, Yang L (2011) A fluorescent “turn-on” probe for the dual-channel detection of Hg(II) and Mg(II) and its application of imaging in living cells. Talanta 85:2194–2201

    Article  PubMed  CAS  Google Scholar 

  10. Niu CX, Zhao L, Fang T, Deng XB, Ma H, Zhang JX, Na N, Han JS, Ouyang J (2014) Color- and morphology-controlled self-assembly of new electron- donor-substituted aggregation-induced emission compounds. Langmuir 30:2351–2359

    Article  PubMed  CAS  Google Scholar 

  11. Adenier A, Aaron JJ (2002) A spectroscopic study of the fluorescence quenching interactions between biomedically important salts and the fluorescent probe merocyanine 540. Spectrochim Acta A 58:543–551

    Article  CAS  Google Scholar 

  12. Hong YN, Lama JWY, Tang BZ (2009) Aggregation-induced emission: phenomenon, mechanism and applications. Chem Commun 29:4332–4353

    Article  Google Scholar 

  13. Wu JS, Liu WM, Ge JC, Zhang HY, Wang PF (2011) New sensing mechanisms for design of fluorescent chemosensors emerging in recent years. Chem Soc Rev 40:34833495

    Google Scholar 

  14. Wang AZ, Yang YX, Yu FF, Xue LW, Hu BW, Fan WP, Dong YJ (2015) A highly selective and sensitive fluorescent probe for quantitative detection of Hg2+ based on aggregation-induced emission features. Talanta 132:864–870

    Article  PubMed  CAS  Google Scholar 

  15. Ye JH, Liu J, Wang ZH, Bai Y, Zhang WC, He WJ (2014) A new Fe3+ fluorescent chemosensor based on aggregation-induced emission. Tetrahedron Lett 55:3688–3692

    Article  CAS  Google Scholar 

  16. Tang LJ, Wu D, Wen X, Dai X, Zhong KL (2014) A novel carbazole-based ratiometric fluorescent sensor for Zn2+ recognition through excimer formation and application of the resultant complex for colorimetric recognition of oxalate through IDAs. Tetrahedron 70:9118–9124

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The project was supported by the national natural science funds projects (No. 21176029, 21476029) and “LNET (No.LR2015001)”.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Yan-Jiang Bian or Li-Jun Tang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bian, YJ., Wang, LQ., Cao, FX. et al. A Simple Fluorescence Probe Based on Aggregation-Induced Emission (AIE) Property for the Detection of Mg2+ Ions. J Fluoresc 26, 53–57 (2016). https://doi.org/10.1007/s10895-015-1717-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10895-015-1717-8

Keywords

Navigation