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A Colorimetric and Fluorescent Sensor Based on Novel Iminocoumarin Precursor for Pd2+ Dectection in Aqueous Solution

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Abstract

A novel iminocoumarin precursor L was designed and well characterized. Sensor L showed high selectivity toward Pd2+ in aqueous solution (CH3CN:H2O, v/v, 1:1) with a detection limit is 2.1 × 10−7M. Iminocoumarin was formed when added Pd2+ to the solution of L by removing the propargylic group.

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References

  1. Iwasawa T, Tokunaga M, Obora Y, Tsuji Y (2004) Homogeneous palladium catalyst suppressing Pd black formation in air oxidation of alcohols. J Am Chem Soc 126:6554–6555

    Article  CAS  PubMed  Google Scholar 

  2. Kielhorn J, Melber C, Keller D, Mangelsdorf I (2002) Palladium – a review of exposure and effects to human health. Int J Hyg Environ Health 205:417–432

    Article  CAS  PubMed  Google Scholar 

  3. Buchwald SL, Mauger C, Mignani G, Scholzc U (2006) Industrial-scale palladium-catalyzed coupling of aryl halides and amines –a personal account. Adv Synth Catal 348:23–39

    Article  CAS  Google Scholar 

  4. F. Yu, X. Han, L. Chen, Fluorescent probes for hydrogen sulfide detection and bioimaging. Chem Commun, (2014).

  5. Wang R, Yu C, Yu F, Chen L, Yu C (2010) Molecular fluorescent probes for monitoring pH changes in living cells. TrAC Trends Anal Chem 29:1004–1013

    Article  CAS  Google Scholar 

  6. L. Duan, Y. Xu, X. Qian, Highly sensitive and selective Pd2+ sensor of naphthalimide derivative based on complexation with alkynes and thio-heterocycle. Chem. Commun. (Cambridge, U. K.). (2008) 6339–6341.

  7. H. Li, J. Fan, J. Du, K. Guo, S. Sun, X. Liu, X. Peng, A fluorescent and colorimetric probe specific for palladium detection. Chem. Commun. (Cambridge, U. K.). 46 (2010) 1079–1081.

  8. Li H, Fan J, Peng X (2013) Colourimetric and fluorescent probes for the optical detection of palladium ions. Chem Soc Rev 42:7943–7962

    Article  CAS  PubMed  Google Scholar 

  9. He J, Zha M, Cui J, Zeller M, Hunter AD, Yiu S-M, Lee S-T, Xu Z (2013) Convenient detection of Pd(II) by a metal-organic framework with sulfur and olefin functions. J Am Chem Soc 135:7807–7810

    Article  CAS  PubMed  Google Scholar 

  10. Jiang J, Jiang H, Liu W, Tang X, Zhou X, Liu W, Liu R (2011) A colorimetric and ratiometric fluorescent probe for palladium. Org Lett 13:4922–4925

    Article  CAS  PubMed  Google Scholar 

  11. Kaur P, Kaur N, Kaur M, Dhuna V, Singh J, Singh K (2014) ‘Turn-on’ coordination based detection of Pd2+ and bioimaging applications. RSC Adv 4:16104–16108

    Article  CAS  Google Scholar 

  12. Li H, Cao J, Zhu H, Fan J, Peng X (2013) Optical Pd2+ sensing by rhodamine hydrazone ligands: different stoichiometries in aqueous/nonaqueous environments. Tetrahedron Lett 54:4357–4361

    Article  CAS  Google Scholar 

  13. LQ. Li, ZH Liu, A colormetric and fluorescent turn on chemodosimeter for Pd2+ detection. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 138(2015) 954–957.

  14. S. Cai, Y. Lu, S. He, F. Wei, L. Zhao, X. Zeng, A highly sensitive and selective turn-on fluorescent chemosensor for palladium based on a phosphine-rhodamine conjugate. Chem. Commun. (Cambridge, U. K.). 49 (2013) 822–824.

  15. Song F, Garner AL, Koide K (2007) A highly sensitive fluorescent sensor for palladium based on the allylic oxidative insertion mechanism. J Am Chem Soc 129:12354–12355

    Article  CAS  PubMed  Google Scholar 

  16. Wei G, Wang L, Jiao J, Hou J, Cheng Y, Zhu C (2012) Cu2+ triggered fluorescence sensor based on fluorescein derivative for Pd2+ detection. Tetrahedron Lett 53:3459–3462

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by Scientific Research Program Funded by Shaanxi Provincial Education Department (Program No.14JK1181) and Scientific Foundation of Shaanxi Xue Qian Normal University (Program No. 2015ZDKJ016).

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Authors and Affiliations

  1. Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an, 710062, People’s Republic of China

    Lianqing Li & Zhihong Liu

  2. Department of Chemistry and Chemical Engineering, ShaanXiXueQian Normal University, Xi’an, 710010, People’s Republic of China

    Lianqing Li, Junfeng Wang & Zhengfeng Xiao

  3. Binzhou Medical University Hospital, Binzhou, 256600, People’s Republic of China

    LeJun Gao

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  1. Lianqing Li
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  2. LeJun Gao
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  3. Junfeng Wang
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  4. Zhengfeng Xiao
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  5. Zhihong Liu
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Correspondence to Zhihong Liu.

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Li, L., Gao, L., Wang, J. et al. A Colorimetric and Fluorescent Sensor Based on Novel Iminocoumarin Precursor for Pd2+ Dectection in Aqueous Solution. J Fluoresc 25, 1165–1168 (2015). https://doi.org/10.1007/s10895-015-1646-6

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  • DOI: https://doi.org/10.1007/s10895-015-1646-6

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