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“Estimation of Ground and Excited State Dipole Moments of aryl Boronic acid Derivative by Solvatochromic Shift Method”

Journal of Fluorescence volume 24, pages 1651–1659 (2014)Cite this article

Abstract

In the present work, the absorption and fluorescence spectra of newly synthesized aryl boronic acid derivative namely 2-Methylphenyl boronic acid (2MPBA) have been recorded in various solvents of different polarities. The ground state dipole moment of 2MPBA was obtained from quantum chemical calculations. Solvatochromic correlations were used to estimate the ground state (μ g ) and excited state (μ e ) dipole moments. The excited state dipole moments are observed to be greater than the ground state dipole moment and ground and excited state dipole moments are not parallel but subtend by an angle of 880. Further, the changes in dipole moment (Δμ) were calculated both from solvatochromic shift method and microscopic solvent polarity parameter (E N T ), and the value are compared. The spectral variations were analyzed by Kamlet-Taft parameters.

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Acknowledgments

Authors (GVM) and (NRP) thank the H.O.D., the Principal B V B College of Engineering & Technology, Hubli, India for financial support under Capacity Building Fund and K.L.E Society Management Belgaum for their encouragement. And another author (RMM) is also grateful to the H.O.D., Dr. Suguna, the Principal and the Management of M.S.R.I.T. for their continuous encouragement.

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Affiliations

  1. Department of Physics, B V B College of Engineering and Technology, Hubli, 580031, Karnataka, India

    G. V. Muddapur & N. R. Patil

  2. Department of Physics, Government R G S P U College, Kittur, 591115, Karnataka, India

    S. S. Patil

  3. Department of Physics, M S Ramaiah Institute of Technology, Bangalore, 560054, Karnataka, India

    R. M. Melavanki

  4. Department of Chemistry, R V College of Engineering, Bangalore, 560059, Karnataka, India

    R. A. Kusanur

Authors
  1. G. V. Muddapur
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  2. N. R. Patil
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  3. S. S. Patil
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  4. R. M. Melavanki
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  5. R. A. Kusanur
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Corresponding authors

Correspondence to N. R. Patil or R. M. Melavanki.

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Muddapur, G.V., Patil, N.R., Patil, S.S. et al. “Estimation of Ground and Excited State Dipole Moments of aryl Boronic acid Derivative by Solvatochromic Shift Method”. J Fluoresc 24, 1651–1659 (2014). https://doi.org/10.1007/s10895-014-1452-6

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  • DOI: https://doi.org/10.1007/s10895-014-1452-6

Keywords

  • Solvent polarity
  • DFT
  • Boronic acid
  • Kamlet-Taft
  • Angle between dipole moments