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Fast Separation Ultra-Performance Liquid Chromatography for Determination of Pre-Column Derivative Abamectin and Ivermectin Residues in Vegetable

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Abstract

A new residue method for quantification of abamectin and ivermectin in vegetable is described in the article. The derivative process is devised that acylating chemical is firstly performed by N-methylimidazole (MI) and trifluoroacetic anhydride (TFAA), then which reacted with hydroxyl function of abamerctin to make fluorescence. The influence of triethylamin (TEA) is examined. Separation is resolute by a short column of 1.7 μm size and operated at high pressure values (10.000 psi). The optimal chromatographic condition and the highest sensitivity are achieved by acetonitrile: water (95: 5), 0.4 mL/min, 0.2 μL injector. The detection limits of abamectin and ivermectin are 1 μg/kg respectively.

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Acknowledgement

We were grateful for support funded the science and technology department of Yunnan province (project No: 2008 CD181, 2009AB 002).

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Authors and Affiliations

  1. Supervision & Testing Center for Farm Product Quality, Ministry of Agriculture, (Kunming), Institute of Quality Standard and Testing Technology, Yunnan Academy of Agriculture Science, 650223, Kunming, People’s Republic of China

    Hongcheng Liu, Qiwan Li, Jinliang Shao & Yanhong Zou

  2. College of Biosystem Engineering and Food Science, Zhejiang University, 310029, Hangzhou, People’s Republic of China

    Hongcheng Liu, Ying Zhang & Lianliang Liu

  3. Institute of Quality Standard and Testing Technology, Kunming Xufu Road, Kunming, Yunnan Province, China

    Qiwan Li

Authors
  1. Hongcheng Liu
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  2. Ying Zhang
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  3. Lianliang Liu
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  4. Qiwan Li
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  5. Jinliang Shao
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  6. Yanhong Zou
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Correspondence to Qiwan Li.

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Liu, H., Zhang, Y., Liu, L. et al. Fast Separation Ultra-Performance Liquid Chromatography for Determination of Pre-Column Derivative Abamectin and Ivermectin Residues in Vegetable. J Fluoresc 21, 825–829 (2011). https://doi.org/10.1007/s10895-010-0734-x

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  • DOI: https://doi.org/10.1007/s10895-010-0734-x

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