Abstract
The Yb3+-doped barium gallogermanate glass has been prepared via the conventional melt method. The absorption spectra, the near infrared emission spectra, the upconversion emission spectra and the differential scanning calorimetry have been measured. Bright blue upconversion emission centered at 476 nm has been observed under the 976 nm laser diode excitation at room temperature. The blue upconversion emission mechanism has been discussed on the blue emission intensity and the measured lifetime. The slope of the log-log plot of the blue emission intensity versus the pump power is equal to 1.98, and the blue luminescence decay time is half of the near infrared fluorescence decay time, confirming that the blue emission comes from Yb3+-Yb3+ pairs cooperative upconversion mechanism. The result of differential scanning calorimetry suggests that this type of glass is suitable as a potential candidate for fiber drawing.
Similar content being viewed by others
References
Wen L, Li SG, Huang GS, Hu LL, Jiang ZH (2004) Optical transitions and upconversion properties of Er3+-doped chloride tellurite glasses. Chin Phys 13:258
Chen XB, Nie YX, Wen O (2001) Yb3+ Ion Upconversion Luminescence from YbEr:ZBLAN Glass Excited by 966 nm Laser Light. Chin Phys Lett 18:280
Yang ZM, Feng ZM, Jiang ZH (2005) Upconversion emission in multi-doped glasses for full colour display. J Phys D: Appl Phys 38:1629
Chen XB, Zheng Z, Song ZF (2001) Direct upconversion sensitization luminescence of Ho(0.1)Yb(5): oxyfluoride vitroceramics. Chin Phys 10:1163
Yang ZM, Xu SQ, Hu LL, Jiang ZH (2004) Frequency upconversion properties of Yb3+-Er3+ co-doped oxyfluoride germanate glass. J Mater Sci 39:2223
Liu GK, Jacquier B (2005) Spectroscopic properties of rare earths in optical materials Tsinghua University Press, Beijing, pp. 266
Maciel GS, Biswas A, Kapoor R, Prasad PN (2000) Blue cooperative upconversion in Yb3+-doped multicomponent silica glass for three-dimensional display. Appl Phys Lett 76:1978
Su J, Song F, Tan H, Han L, et al (2006) Phonon-assisted mechanisms and concentration dependence of Tm3+ blue upconversion luminescence in codoped NaY(WO4)2 crystals. J Phys D: Appl Phys 39:2094
Nakazawa E, Shionoya S (1970) Cooperative luminescence in YbPO4. Phys Rev Lett 25:1710
Montoya E, Bausa LE, Schaudel B, Golder P (2001) Yb3+ distribution in LiNbO3:(MgO) studied by cooperative luminescence. J Chem Phys 114:3200
Golder P, Pellé F, Auzel F (1997) Theoretical evaluation of cooperative luminescence rate in Yb3+: CsCdBr3 and comparison with experiment. J Lumin 72–74:901
Golder P, Pellé F, Meichenin D, Auzel F (1997) Cooperative luminescence in ytterbium-doped CsCdBr3. J. Lumin 71:137
Hehlen MP, Güdel HU, Shu QZ, Rand SH (1996) Cooperative optical bistability in the dimer system Cs3Y2Br9:10% Yb3+. J Chem Phys 104:1232
Chen XB, Song ZF, Sawanobori N (2001) Blue cooperative up-conversion luminescence of Yb3+ ions in oxyfluoride glass excited by 960 nm Laser. Chin Phys 10:564
dos Santos PV, Vermelho MVD, Gouveia EA, et al (2002) Blue cooperative luminescence in Yb3+-doped tellurite glasses excited at 1.064 μm. J Chem Phys 116:6772
Wang J, Lincoln JR, Brocklesby WS, Deol RS, Mackechnie CJ, Pearson A, Tropper AC, Hanna DC, Payne DN (1993) Fabrication and optical properties of lead-germanate glasses and a new class of optical fibers doped with Tm3+. J Appl Phys 73:8066
Schaudel B, Golder P, Prassas M, Auzel F (2000) Upconversion luminescence as a probe of clustering in Yb3+ doped glasses. J Alloys Compd 300–301:443
Sun HT, Yang JJ, Zhang LY, Zhang JJ, Hu LL, Jiang ZH (2005) Composition dependent frequency upconversion luminescence in Er3+-doped oxychloride germanate glasses. Solid State Commun 133:753
Zhang QY, Li T, Jiang ZH, Ji XH, Buddhudu S (2005) Appl Phys Lett 87:171911–1
Acknowledgements
The authors would like to thank Zhouming Feng and Dongdan Chen for the spectra and differential scanning calorimetry measurements. This work was supported by the National Natural Science Foundation of China (Grant Nos. 60307004 and 50402007), the Guangdong Science and Technology Program (Grant Nos. 2005A10602001 and 2004A10602002), the Guangzhou Science and Technology Program (Grant Nos. 2004Z2-D0131), and the Program for New Century Excellent talents (NCET-04-0821).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Xiao, K., Yang, Z. Blue Cooperative Luminescence In Yb3+-Doped Barium Gallogermanate Glass Excited At 976 nm. J Fluoresc 16, 755–759 (2006). https://doi.org/10.1007/s10895-006-0134-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10895-006-0134-4