An approach is proposed making it possible to construct the shock adiabats of molecular crystals of nitro compounds based on the data on their isothermal compression. For this purpose, an equation of state for a crystal of pentaerythritol tetranitrate (PETN) was constructed. The employed comparative analysis of the experimental data on the shock-wave compression of a simple PETN crystal with calculations carried out using the proposed approach to converting the isothermal compression pressures to the shock adiabat and the constructed equation of state of the PETN showed that the experimental and calculated pressure values are within the experimental error.
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References
G. I. Kanel’, S. V. Razorenov, A. V. Utkin, and V. E. Fortov, Shock-Wave Phenomena in Condensed Media [in Russian], Yanus-K, Moscow (1996).
Yu. M. Kovalev, Determination of the temperature dependence of the isobaric volumetric expansion coefficient for certain molecular crystals of nitro compounds, J. Eng. Phys. Thermophys., 91, No. 6, 1573–1582 (2018).
Yu. M. Kovalev, Equations of state to describe isothermal compression of certain molecular nitro compound crystals, J. Eng. Phys. Thermophys., 93, No. 1, 223–233 (2020).
B. Olinger and H. Cady, Shock compressibility of PETN, TATB, CO2, and H2O at pressures up to 10 GPa, calculated from experimental data on hydrostatic compression, in: Deton. Explos. [Russian translation], Mir, Moscow (1981), pp. 203–219.
S. P. Marsh, LASL Shock Hugoniot Data, University of California Press, Los Angeles (1980).
L. D. Landau and E. M. Lifshits, Statistical Physics, Pt. 1 [in Russian], Fizmatlit, Moscow (2002).
Yu. M. Kovalev, Determination of the form of the Grüneisen coefficient for molecular crystals, Dokl. Akad. Nauk, 403, No. 4, 475–478 (2005).
Yu. M. Kovalev, Grüneisen function for solid explosives, Vopr. Atomn. Nauki Tekh., Ser. Mat. Modelir. Fiz. Prots., No. 2, 55–59 (2005).
I. P. Bazarov, Thermodynamics [in Russian], Vysshaya Shkola, Moscow (1991).
B. Olinger, P. M. Halleck, and H. H. Cady, The isothermal linear and volume compression of pentaerythritol tetranitrate (PETN) to 10 GPa (100 kbar) and the calculated shock compression, J. Chem. Phys., 62, No. 11, 4480–4483 (1975).
V. G. Shchetinin, Calculation of the parameters of state of condensed substances at high pressures and temperatures, Fiz. Goreniya Vzryva, No. 4, 39–46 (1991).
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Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 96, No. 4, pp. 1053–1061, July–August, 2023
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Kovalev, Y.M., Pomykalov, E.V. Equations of State for Calculating the Pressures of Shock-Wave Compression of Pentaerythritol Tetranitrate (PETN). J Eng Phys Thermophy 96, 1052–1059 (2023). https://doi.org/10.1007/s10891-023-02769-y
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DOI: https://doi.org/10.1007/s10891-023-02769-y