An analysis is made of kinetically and aggregatively unstable non-Newtonian oil disperse systems and of the reasons for the occurrence of this instability that are associated with the coalescence of droplets and their settlement. In this connection, the authors have proposed models of thinning and rupture of the interphase non-Newtonian film between two joined droplets, and also the model of change in the thickness of the interphase film. The Ostwald–de Waele model satisfactorily describing pseudoplastic properties of oil was taken as the basis for the investigation. A model of settlement of particles in a non-Newtonian oil was proposed. The proposed models were compared with the existing experimental data, which has shown their efficiency. Consideration has been given to the conditions of self-organization of aggregatively and kinetically unstable disperse systems. It has been noted that such systems, in the case of infinite time, have no hereditary memory.
Similar content being viewed by others
References
G. I. Kelbaliyev, D. B. Tagiyev, and S. R. Rasulov, Transport Phenomena in Dispersed Media, Taylor & Francis Group, Boca Raton-London-New York (2019).
G. I. Kelbaliyev, D. B. Tagiyev, and M. R. Manafov, Rheology of structured oil emulsion, in: Nanoand Micro-Encapsulation — Techniques and Applications, IntechOpen, London (2021), pp. 1-38; doi: https://doi.org/10.5772/intechopen.92770.
S. L. Soo, Fluid Dynamics of Multiphase Systems, Blaisdell Puiblishing, London (1970).
G. I. Kelbaliev, M. R. Manafov, and F. R. Shikhieva, Rheology of a viscous-plastic liquid in a porous medium, Open J. Fluid Dyn., 13, 16–31 (2023); https://doi.org/10.4236/ojfd.2023.131002.
V. N. Matveenko and S. V. Kirsanov, The rheology of structured disperse systems, Vestn. Moskovsk. Univ., 47, No. 6, 393-397 (2006).
S. V. Kirsanov and V. N. Matveenko, Non-Newtonian Behavior of Structured Systems [in Russian], Tekhnosfera, Moscow (2016).
G. I. Kelbaliev, D. B. Tagiev, S. R. Rasulov, et al., Structurization and effective viscosity of a non-Newtonian oil, J. Eng. Phys. Thermophys., 96, No. 1, 55–63 (2023); https://doi.org/10.1007/s10891-023-02661-9.
M. K. Rogachev and N. K. Kondrashenko, The Rheology of Oil and Petroleum Products [in Russian], Izd. Ufimsk. Gos. Neftyan. Tekhnol. Univ., Ufa (2000).
A. Hirschberg, N. L. DeJong, B. A. Schipper, and J. G. Meijer, Infl uence of temperature and pressure on asphaltene fl occulation, Soc. Pet. Eng., 24, No. 3, 283-293 (1984).
Mhunir Bayonle Alamu, Investigation of Periodic Structures in Gas–Liquid Flow. The University of Nottingham School of Chemical & Environmental Engineering, Thesis submitted to the University of Nottingham for the degree of Doctor of Philosophy, UK (2010).
S. Delaux, Physical and Numerical Modeling of Particle Settlement in a Turbulent Flow: Implication for the Settlement of Algal Propagules, Thesis submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy in Ecology, Department of Biological Sciences, University of Canterbury (2009).
R. H. Chhabra, Bubbles, Drops and Particles in Non-Newtonian Fluids, Taylor and Francis Group, CRC Press, Boca Raton, US (2007).
G. Astariata, G. Marucci, and I. Nicolas, Rheology, Vol. 2, Fluids, Springer, New York (1980).
Adina Ghirisan and Simion Dragan, Sedimentation of Concentrated Suspensions in Non-Newtonian Fluids, Universitatea Babes-Bolyai (2011); http://chem.ubbcluj.ro/~studiachemia/index.html.
G. Nicolis and I. Prigogine, Self-Organization in Non-Equilibrium Systems, John Wiley and Son, New York-London-Sidney (1978).
C. W. Gardiner, Handbook of Stochastic Methods for Physics, Chemistry and the Natural Sciences, Springer, Berlin– Heidelberg (1985).
M. R. Manafov, Software application for solving some typical problems of chemical technology, Azerbaijan Chem. J., No. 2, 89-94 (2016).
M. R. Manafov, E. M. Mammadov, and G. S. Aliyev, Application of Software package "OptimMe" for the study of the process of partial oxidation of propane, Am. J. Chem. Appl., 2, No. 4, 47–51 (2015).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 96, No. 3, pp. 663–670, May–June, 2023.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Kelbaliyev, G.I., Tagiyev, D.B., Manafov, M.R. et al. Kinetically and Aggregatively Unstable Oil Disperse Systems. J Eng Phys Thermophy 96, 660–668 (2023). https://doi.org/10.1007/s10891-023-02727-8
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10891-023-02727-8