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Results of Chemical Activation of Biochar Obtained by the Method of Accelerated Hydrothermal Carbonization of Sewage Sludge

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Journal of Engineering Physics and Thermophysics Aims and scope

An investigation has been made into accelerated hydrothermal fluidized carbonization of sewage sludge in a superheated steam medium. It is shown that an increase in the process temperature has no effect on its duration but has a significant effect on the composition of noncondensable gases. Biochar activation has been investigated in potassium hydroxide at a temperature of 750°C and the biochar–KOH ratios of 1:1.5, 1:2, and 1:3. It is shown that the KOH concentration has no effect, in practice, on the sorption characteristics of the obtained product which is more suitable for the use as a soil improver.

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References

  1. S. Khan, N. Wang, B. J. Reid, A. Freddo, and C. Cai, Reduced bioaccumulation of PAHs by Lactuca satuva L. grown in contaminated soil amended with sewage sludge and sewage sludge derived biochar, Environ. Pollut., 175, 64–68 (2013).

    Article  Google Scholar 

  2. X. Yuan, H. Huang, G. Zeng, H. Li, J. Wang, C. Zhou, H. Zhu, X. Pei, Z. Liu, and Z. Liu, Total concentrations and chemical speciation of heavy metals in liquefaction residues of sewage sludge, Bioresour. Technol., 102, No. 5, 4104–4110 (2011).

    Article  Google Scholar 

  3. C. He, A. Giannis, and J. Wang, Conversion of sewage sludge to clean solid fuel using hydrothermal carbonization: Hydrochar fuel characteristics and combustion behavior, Appl. Energy, 111, 257–266 (2013).

    Article  Google Scholar 

  4. C. Peng, Y. Zhai, Y. Zhu., B. Xu, T. Wang, C. Li, and G. Zeng, Production of char from sewage sludge employing hydrothermal carbonization: Char properties, combustion behavior and thermal characteristics, Fuel, 176, 110–118 (2016).

    Article  Google Scholar 

  5. Y. Zhai, H. Chen, B. Xu, B. Xiang, Z. Chen, C. Li, and G. Zeng, Influence of sewage sludge-based activated carbon and temperature on the liquefaction of sewage sludge: Yield and composition of bio-oil, immobilization and risk assessment of heavy metals, Bioresour. Technol., 159, 72–79 (2014).

    Article  Google Scholar 

  6. L. Leng, X. Yuan, J. Shao, H. Huang, H. Wang, H. Li, X. Chen, and G. Zeng, Study on demetalization of sewage sludge by sequential extraction before liquefaction for the production of cleaner bio-oil and bio-char, Bioresour. Technol., 200, 320–327 (2016).

    Article  Google Scholar 

  7. P. Zhao, Y. Shen, S. Ge, Z. Chen, and K. Yoshikawa, Clean solid biofuel production from high moisture content waste biomass employing hydrothermal treatment, Appl. Energy, 131, 345–367 (2014).

    Article  Google Scholar 

  8. R. Dewil, J. Baeyens, and L. Appels, Enhancing the use of waste activated sludge as bio-fuel through selectively reducing its heavy metal content, J. Hazard. Mater., 144, No. 3, 703–707 (2007).

    Article  Google Scholar 

  9. T. Chen, Z. Zhou, S. Xu, H. Wang, and W. Lu, Adsorption behavior comparison of trivalent and hexavalent chromium on biochar derived from municipal sludge, Bioresour. Technol., 190, 388–394 (2015).

    Article  Google Scholar 

  10. A. Méndez, J. Paz-Ferreiro, F. Araujo, and G. Gascó, Biochar from pyrolysis of deinking paper sludge and its use in the treatment of a nickel polluted soil, J. Anal. Appl. Pyrolysis, 107, 46–52 (2014).

    Article  Google Scholar 

  11. A. Zielinska and P. Oleszczuk, Evaluation of sewage sludge and slow pyrolyzed sewage sludge-derived biochar for adsorption of phenanthrene and pyrene, Bioresour. Technol., 192, 618–626 (2015).

    Article  Google Scholar 

  12. W. Shi, C. Liu, D. Ding, Z. Lei, Y. Yang, C. Feng, and Z. Zhang, Immobilization of heavy metals in sewage sludge by using subcritical water technology, Bioresour. Technol., 137, 18–24 (2013).

    Article  Google Scholar 

  13. L. Leng, X. Yuan, H. Huang, H. Jiang, X. Chen, and G. Zeng, The migration and transformation behavior of heavy metals during the liquefaction process of sewage sludge, Bioresour. Technol., 167, 144–150 (2014).

    Article  Google Scholar 

  14. H. Pan, Effects of liquefaction time and temperature on heavy metal removal and distribution in liquefied CCA-treated wood sludge, Chemosphere, 80, No. 4, 438–444 (2010).

    Article  Google Scholar 

  15. R. L. Isemin, A. V. Mikhalev, N. S. Muratova, V. S. Kogh-Tatarenko, Yu. S. Teplitskii, E. K. Buchilko, A. Zh. Greben’kov, and E. A. Pitsukha, Improving the efficiency of biowaste torrefaction, Therm. Eng., 66, No. 7, 521–526 (2019).

    Article  Google Scholar 

  16. P. J. Arauzo, P. A. Maziarka, M. P. Olszewski, R. L. Isemin, N. S. Muratova, F. Ronsse, and A. Kruse, Valorization of the poultry litter through wet torrefaction and different activation treatments, Sci. Total Environ., 732, Article 139288 (2020).

  17. B. Ghanim, D. Pandey, W. Kwapinski, and J. Leahy, Hydrothermal carbonization of poultry litter: Effects of treatment temperature and residence time on yields and chemical properties of hydrochars, Bioresour. Technol., 216, 373–380 (2016).

    Article  Google Scholar 

  18. V. I. Kovenskii, V. A. Borodulya, Yu. S. Teplitskii, G. I. Pal’chenok, and D. S. Slizhuk, Modeling of superheated-steam drying of biofuel in a fl uidized bed, J. Eng. Phys. Thermophys., 83, No. 4, 764–769 (2010).

    Article  Google Scholar 

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Correspondence to N. S. Muratova.

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Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 94, No. 6, pp. 1591–1596, November–December, 2021.

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Muratova, N.S., Is’emin, R.L., Melezhik, A.V. et al. Results of Chemical Activation of Biochar Obtained by the Method of Accelerated Hydrothermal Carbonization of Sewage Sludge. J Eng Phys Thermophy 94, 1557–1562 (2021). https://doi.org/10.1007/s10891-021-02436-0

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  • DOI: https://doi.org/10.1007/s10891-021-02436-0

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