The physical mechanism of detonation combustion of nanostructured silicon with a solid-phase oxidant at a velocity of the combustion front of 1000–3000 m/s has been proposed. Thermodynamic characteristics of combustion of model solid-phase mixtures “silicon–ammonium perchlorate” with different equivalent ratios of their components have been calculated at different pressures. It has been established that a characteristic feature of detonation combustion of nanostructured silicon with a solid-phase oxidant is the stationary velocity of motion of the detonation front with a significant defect (10–15%) with respect to the Chapman–Jouguet detonation velocity. The detonation (supersonic) and subsonic regimes of combustion of nanostructured silicon with a solid-phase oxidant have been determined.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
D. Kovalev, V. Y. Timoshenko, N. Kunzner, E. Gross, and F. Koch, Strong explosive interaction of hydrogenated porous silicon with oxygen at cryogenic temperatures, Phys. Rev. Lett., 87, No. 6, 068301 (2001).
F. V. Mikulec, J. D. Kirtland, and M. J. Sailor, Explosive nanocrystalline porous silicon and its use in atomic emission spectroscopy, Adv. Mater., 14, No. 1, 38–41 (2002).
D. Clement, J. Diener, E. Gross, N. Kunzner, V. Y. Timoshenko, and D. Kovalev, Highly explosive nanosilicon-based composite materials, Phys. Status Solidi A, 202, No. 8, 1357–1361 (2005).
S. K. Lazarouk, A. V. Dolbik, P. V. Jaguiro, V. A. Labunov, and V. E. Borisenko, Fast exothermic processes in porous silicon, Semiconductors, 39, 881–883 (2005).
M. Du Plessis, Properties of porous silicon nano-explosive devices, Sens. Actuators A, 135, 666–674 (2007).
W. Churaman, L. Currano, and C. Becker, Initiation and reaction tuning of nanoporous energetic silicon, J. Phys. Chem. Solids, 71, 69–74 (2010).
N. W. Piekiel, Chr. J. Morris, W. A. Churaman, M. E. Cunningham, D. M. Lunking, and L. J. Currano, Combustion and material characterization of highly tunable on-chip energetic porous silicon, Propel. Explos. Pyrotech., 40, 16–26 (2010).
C. R. Becker, S. Apperson, C. J. Morris, S. Gangopadhyay, L. J. Currano, W. A. Churaman, and C. R. Stoldt, Galvanic porous silicon composites for high-velocity nanoenergetics, Nano Lett., 11, 803–807 (2011).
A. Plummer, V. Kuznetsov, T. Joyner, J. Shapter, and N. H. Voelcker, The burning rate of energetic fi lms of nanostructured porous silicon, Small, 7, 3392–3398 (2011).
V. S. Parimi, A. Bermúdez Lozda, S. A. Tadigadapa, and R. A. Yetter, Reactive wave propagation in energetic porous silicon composites, Combust. Flame, 161, 2991–2999 (2014).
V. S. Parimi, S. A. Tadigadapa, and R. A. Yetter, Reactive wave propagation mechanisms in energetic porous silicon composites, Combust. Sci. Technol., 187, Nos. 1–2, 249–268 (2015).
V. N. Mironov, O. G. Penyazkov, P. N. Krivosheev, E. A. Baranyshin, E. S. Golomako, and A. V. Sokolov, Distinctive features of combustion of porous silicon in oxygen at elevated pressures and in the atmosphere in the system "porous silicon–sodium perchlorate," in: Heat and Mass Transfer–2018, A. V. Luikov Heat and Mass Transfer Institute of the National Academy of Sciences of Belarus, Minsk (2019), pp. 152–162.
V. N. Mironov, O. G. Penyazkov, K. N. Kasparov, E. A. Baranyshin, I. A. Ivanov, E. A. Vyazova, K. I. Delendik, and L. Yu. Roshchin, On the dynamics and temperature of combustion of a thin porous silicon layer in an oxygen medium, in: Heat and Mass Transfer–2016, A. V. Luikov Heat and Mass Transfer Institute of the National Academy of Sciences of Belarus, Minsk (2017), pp. 101–114.
V. N. Mironov, O. G. Penyazkov, P. N. Krivosheev, E. A. Baranyshin, E. S. Golomako, and A. V. Sokolov, Regimes and rates of combustion of porous silicon in oxygen at pressures of 2 to 35 bar, in: Heat and Mass Transfer–2018, A. V. Luikov Heat and Mass Transfer Institute of the National Academy of Sciences of Belarus, Minsk (2019), pp. 141–151.
S. I. Futko, I. A. Koznacheev, O. S. Rabinovich, O. G. Penyazkov, P. N. Krivosheev, On the mechanism of combustion of thin nanostructurized silicon plates in oxygen at an elevated pressure, J. Eng. Phys. Thermophys., 92, No. 1, 1–11 (2019).
Ya. B. Zel’dovich and A. S. Kompaneets, Detonation Theory [in Russian], Gos. Izd. Tekh.-Teor. Lit., Moscow (1955).
I. Schumacher, Perchlorates: Their Properties, Manufacture, and Uses [in Russian], Goskhimizdat, Moscow (1963).
B. A. Mason, L. J. Groven, S. F. Son, and R. A. Yetter, Combustion performance of several nanosilicon-based nanoenergetics, J. Propuls. Power, 29, No. 6, 1435–1444 (2013).
M. Tanaka and M. W. Beckstead, Three phase combustion model of ammonium perchlorate, Proc. AIAA/ASME/SAE/ ASEE 32nd Joint Propuls. Conf., AIAA Paper 96–2888.20 (1996).
R. J. Kee, F. M. Rupley, and J. A. Miller, Chemkin II: A Fortran Chemical Kinetics Package for the Analysis of Gas Phase Chemical Kinetics, Report SAND89-8009, Sandia National Lab. (1989).
M. E. Coltrin, R. J. Kee, F. M. Rupley, and E. Meeks, Surface Chemkin III: a Fortran Package for Analyzing Heterogeneous Chemical Kinetics at a Solid-Surface–Gas-Phase Interface, Report SAND96-8217, Sandia National Lab. (1996).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 93, No. 6, pp. 1492–1501, November–December, 2020.
Rights and permissions
About this article
Cite this article
Krivosheyev, P.N., Mironov, V.N., Penyazkov, O.G. et al. On the Mechanism of Detonation Combustion of Nanostructured Silicon with a Solid-Phase Oxidant. J Eng Phys Thermophy 93, 1439–1448 (2020). https://doi.org/10.1007/s10891-020-02249-7
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10891-020-02249-7