The influence of three different nanomaterials (nonfunctionalized and functionalized with amino and oxygencontaining groups) forming a part of elastomeric compounds based on a natural SMR-10 rubber and a butadienenitrile BNKS-18 rubber on the interfacial interactions of these rubbers with an active and a semiactive carbons blacks added to them was investigated. For the purpose of estimating the action of the indicated nanomaterials incorporated into the composition of a rubber on its properties and the interaction of the rubber with a carbon black introduced into the compound, investigations have been performed on determination of the bound rubber in such a compound, the qualitative characteristics of the distribution of an extender in it (the modulus of elasticity and the shear modulus of the compound in the cases of its small and large deformations, respectively, and the difference between these moduli representing the complex dynamic modulus of the compound), and its Mooney viscosity.
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References
T. A. Vilgis, G. Heinrich, and M. Klüppel, Reinforcement of Polymer Nanocomposites: Theory, Experiments and Applications, Cambridge, Cambridge University Press (2010).
A. Limper, Mixing of Rubber Compounds, Hanser Publishers, Munich (2012).
Anqiang Zhang, Lianshi Wang, Yaling Lin, and Xiongfei Mi, Carbon black fi lled powdered natural rubber: Preparation, particle size distribution, mechanical properties, and structures, J. Appl. Polymer Sci., 101, 1763–1774 (2006).
P. M. Visakh, T. Sabu, K. Ch. Arup, and P. M. Aji, Advances in Elastomers II: Composites and Nanocomposites, RSC Publishing, Cambridge (2014).
T. Sabu, J. M. Hanna, J. Jithin, H. Ch. Chin, and A. P. Laly, Natural Rubber Materials: Volume 2: Composites and Nanocomposites, The Royal Society of Chemistry, Cambridge (2014).
Jean Le Bras and Eugene Papirer, The fi ller–elastomer chemical link and the reinforcement of rubber, J. Appl. Polym. Sci., 22, 525–531 (1978).
Y.-W. Mai and Z. Z. Yu (Eds.), Polymer Nanocomposites, Woodhead Publishing Ltd, Cambridge (2006).
I. Yu. Averko-Antonovich and R. T. Bikmullin, Methods of Investigating the Structure and Properties of Polymers [in Russian], Kazan Gos. Tekh. Univ., Kazan (2002).
Standard test method for rubber properties — measurement of cure and after-cure dynamic properties using a rotorless shear rheometer: in ASTM D6601–02 (2008).
B. S. Grishin, Theory and Practice of the Reinforcement of Polymers, State and Development Directions [in Russian], Izd. Kazan Nats, Issled. Tekh. Univ., Kazan (2016).
Determination of the viscosity, the stress relaxation, and the precure characteristics of a rubber with the use of a Mooney viscosimeter, in: Rubbers and Rubber Compounds, Standard R 54552-2011 [in Russian], Standartinform, Moscow (2013).
J. Mark, Science and Technology of Rubber, Academic Press (2005).
R. C. Bansal, J. B. Donnet, and F. Stoeckli (Eds.), Active Carbon, Marcel Dekker Inc., New York (1988).
M.-J. Wang, S. Wolff, and J.-B. Donnet, Filler–elastomer interactions. Part I. Silica surface energies and interactions with model compounds, Rubber Chem. Technol., 64, No. 4, 559–576 (1991).
Bandyopadhyay Sumanda, P. P. De, D. K. Tripathy, and S. K. Dе, Effect of chemical interaction between surface oxidized carbon black and carboxylated nitrile rubber on dynamic properties, J. Appl. Polymer Sci., 58, 719–727 (1995).
Yu. F. Shutilin, Physical Chemistry of Polymers [in Russian], Voronezh Obl. Tipogr., Voronezh (2012).
A. Roychoudhury and P. P. De, Elastomer–carbon black interaction: Infl uence of elastomer chemical structure and carbon black surface chemistry on bound rubber formation, J. Appl. Polym. Sci., 55, 9–15 (1995).
A. Roychoudhury, S. K. De, P. P. De, J. A. Ayala, and G. A. Joyce, Chemical interaction between carbon black and elastomers — crosslinking of chlorosulfonated polyethylene by carbon black, Rubber Chem. Technol., 67, No. 4, 662–671 (1994).
J. Léopoldès, C. Barrès, J. L. Leblanc, and P. Georget, Infl uence of fi ller–rubber interactions on the viscoelastic properties of carbon-black-fi lled rubber compounds, J. Appl. Polym. Sci., 91, 577–588 (2004).
N. V. Belozerov, Technology of Rubber [in Russian], Khimiya, Moscow (1979).
G. M. Bartenev and Yu. S. Zuev, Strength and Destruction of Highly Elastic Materials [in Russian], Khimiya, Moscow (1964).
I. A. Tugorskii, Introduction to Colloid Chemistry, Part 1. Surface Phenomena and Adsorption of a Gas on a Solid Surface [in Russian], MITKhT im. M. V. Lomonosova, Moscow (2007).
J. B. Donnet, Carbon Black, Marcel Dekker, New York (1993).
P. G. Maier and D. Göritz, Molecular interpretation on the Payne effect, Kautsch Gummi Kunstst., No. 49, 18–21 (1996).
A. N. Gent and Y. C. Hwang, Elastic behavior of a rubber layer bonded between two rigid spheres, Rubber Chem. Technol., 61, No. 4, 630–638 (1988).
M. J. Wang, Effect of polymer–fi ller and fi ller–fi ller interactions on dynamic properties of fi lled vulcanizates, Rubber Chem. Technol., 71, No. 3, 520–589 (1998).
Zh. S. Shashok, N. R. Prokopchuk, K. V. Vishnevskii, A. V. Krauklis, K. O. Borisevich, and I. O. Borisevich, Rheological properties of rubber compounds with fi nely divided carbon additives, J. Eng. Phys. Thermophys., 91, No. 1, 146–151 (2018).
Sung-Seen Choi, Effect of bound rubber on characteristics of highly fi lled styrene–butadiene rubber compounds with different types of carbon black, J. Appl. Polym. Sci., 93, 1001–1006 (2004).
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Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 93, No. 1, pp. 88–95, January–February, 2020. Original article submitted June 29, 2018.
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Shashok, Z.S., Prokopchuk, N.R., Uss, E.P. et al. Elastomeric Compounds with Fine-Grained Carbonic Additives. J Eng Phys Thermophy 93, 83–90 (2020). https://doi.org/10.1007/s10891-020-02093-9
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DOI: https://doi.org/10.1007/s10891-020-02093-9