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Use of a Vortex-Type Contact Condenser in Absorption of Methanol and Formaldehyde from a Contact Gas

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Journal of Engineering Physics and Thermophysics Aims and scope

Consideration has been given to the process of absorption of methanol and formaldehyde from a contact gas in the production of technical formalin. Using computer simulation, the authors set up a model of a standard flow diagram of methanol and formaldehyde absorption of a contact gas. For the process of absorption, use was made of NRTL and Lee–Kesler mathematical models which allow for the heat and mass transfer. Empirical coefficients for these models have been determined. The amount of methanol and formaldehyde has been established in absorption gases utilized by burning with a standard flow diagram and on adding a supplementary stage of condensation. A comparison has been made of experimental and calculated data of the process. A heat- and mass transfer apparatus of the vortex type has been proposed, which will make it possible to remove an environmental burden and to improve energy-resource saving. The conditions of operation of the absorber with an increase of 22% in the output have been considered.

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References

  1. L. N. Moskalev and S. I. Ponikarov, Application of a contact vortex condenser to absorb methanol from a contact gas, Theor. Foundations Chem. Eng., 50, No. 2, 194–200 (2016).

    Article  Google Scholar 

  2. All-Union State Standard 625-89. Technical Formalin, Specifications.

  3. N. A. Platé and N. A. Slivinskii, Fundamentals of the Chemistry and Technology of Monomers, a Textbook [in Russian], Nauka: MAIK "Nauka/Interperiodika," Moscow (2002).

  4. V. I. Panchenko, Y. F. Magaril, A. A. Nazarov, Y. S. Shpaner, and R. G. Gimranov, Aerodynamic gas gates for flare units, Chem. Petr. Eng., 45, Nos. 5-6, 278–280 (2009).

  5. Ya. F. Magaril, A. A. Nazarov, Ya. S. Shpaner, and R. G. Gimranov, Special torch heads, Chem. Petr. Eng., 45, Nos. 1–2, 13–14 (2009).

  6. Hygienic Standards 2.2.5.686-98. Maximum Permissible Concentrations of Harmful Substances in the Air of the Working Area, Hygienic Standards.

  7. H. Renon and J. M. Prausnitz, Local compositions in thermodynamic excess functions for liquid mixtures, AIChE J., 14, No. 1, 135–144 (1968).

    Article  Google Scholar 

  8. R. C. Reid, J. M. Prausnitz, and B. E. Poling, The Properties of Gases and Liquids, 4th edn., McGraw-Hill, New York (1988).

    Google Scholar 

  9. B. I. Lee and M. G. Kesler, A generalized thermodynamic correlation based on three-parameter corresponding states, AIChE J., 21, No. 3, 510-527 (1975).

    Article  Google Scholar 

  10. R. Reid, J. Prausnitz, and Th. Sherwood, The Properties of Gases and Liquids [Russian translation], Khimiya, Leningrad (1982).

  11. L. N. Moskalev, S. I. Ponikarov, and I. I. Ponikarov, Description of the experimental setup for investigations of the process of condensation in a vortex contact apparatus, Vestn. Kazansk. Tekhnol. Univ., No. 4, 235–240 (2011).

  12. L. N. Moskalev, S. I. Ponikarov, I. I. Ponikarov, and V. V. Alekseev, Vortex-Type Heat- and Mass-Transfer Device, RF Patent No. 2502929, F28B 3/00, published 17.12.2013, Byull. No. 36.

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Correspondence to L. N. Moskalev.

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Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 89, No. 5, pp. 1188–1194, September–October, 2016.

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Moskalev, L.N., Ponikarov, S.I. Use of a Vortex-Type Contact Condenser in Absorption of Methanol and Formaldehyde from a Contact Gas. J Eng Phys Thermophy 89, 1179–1185 (2016). https://doi.org/10.1007/s10891-016-1481-x

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  • DOI: https://doi.org/10.1007/s10891-016-1481-x

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