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Synthesis of Polyfunctionalized Furan Analogs Catalyzed by Chlorosulfonic Acid Immobilized Nano-Cobaltferrite

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Abstract

A direct and effective method for the preparation of polyfunctionalized furan analogs was developed by employing the reaction of 1,4-diaryl-but-2-ene-1,4-diones and alkyl acetoacetates using sulfonic acid immobilized cobalt ferrite (nano-CoFe2O4@SiO2@APTES@4,7-dichloroquinoline-SO3H) as a novel magnetic nanocatalyst in isopropanol under reflux conditions. Sulfonic acid immobilized cobalt ferrite was characterized by FT-IR, XRD, FE-SEM, TEM, EDX, TGA, and VSM. Furthermore, the nanocatalyst could be easily recovered via magnetic isolation and recycled at least for 5 times without remarkable losing its catalytic property. In this protocol alkyl 2-methyl-4-(2-aryl-2-oxoethyl)-5-arylfuran-3-carboxylate analogs were prepared in good yields over suitable reaction times under green conditions. The main advantage of this procedure is the simple separation of the nanocatalyst from products by using magnetic attraction.

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Acknowledgements

Financial support by Rasht Branch, Islamic Azad University is gratefully acknowledged.

Funding

This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-proft sector.

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Authors and Affiliations

  1. Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran

    Ahmad Gholami, Masoud Mokhtary, Seyedeh Setareh Attarseyedi & Benyamin Masoumi

  2. Department of Education of the Second District of Rasht, Rasht, Guilan, Iran

    Ahmad Gholami

  3. Department of Chemistry, Faculty of Sciences, University of Guilan, Rasht, Iran

    Manouchehr Mamaghani

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  1. Ahmad Gholami
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  2. Masoud Mokhtary
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  3. Seyedeh Setareh Attarseyedi
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  4. Benyamin Masoumi
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Contributions

AG: methodology, formal analysis; MM: conceptualized and executed the research as well as drafted the first manuscript, edited and proofread the manuscript; SSA: formal analysis; BM: formal analysis; MM: provides the resources and supervised the research.

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Correspondence to Masoud Mokhtary.

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Gholami, A., Mokhtary, M., Attarseyedi, S.S. et al. Synthesis of Polyfunctionalized Furan Analogs Catalyzed by Chlorosulfonic Acid Immobilized Nano-Cobaltferrite. J Clust Sci 35, 69–78 (2024). https://doi.org/10.1007/s10876-023-02462-3

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