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Synthesis, Characterization and Efficient Detection of Antibiotics of Two CdII-Based Coordination Polymers

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Abstract

In this work, two CdII-based coordination polymers, namely [Cd4(HL)2(H2O)5]n (1), and {[Cd2(HL)(2,2′-bpy)2(H2O)]·6H2O}n (2) (2,2′-bpy = 2,2′-bipyridine) have been designed and synthesized using 2,3-bis(3,5-dicarboxylphenxoy)benzoic acid (H5L). Coordination polymer 1 displays a layer structure, which was connected through C–H‧‧‧π interactions into 3D supramolecular network, while coordination polymer 2 shows a three-dimensional framework structure. In addition, the excellent fluorescence performance make them potential luminescent sensors for antibiotics. The results show that coordination polymer 1 exhibits high sensitivity for detecting of sulfadiazine (SDZ), while coordination polymer 2 can selectively detect nitrofurantoin (NFT).

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Acknowledgements

The authors gratefully acknowledge financial support by the National Natural Science Foundation of China (No. U1904199), the Program for Science and Technology Innovation Talents at the University of Henan Province (22HASTIT007), and Nanyang Normal University.

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Authors and Affiliations

  1. College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, 473061, People’s Republic of China

    Yi-Yang Zhao, Ye Zhou, Ran Li & Bo Li

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Correspondence to Bo Li.

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Zhao, YY., Zhou, Y., Li, R. et al. Synthesis, Characterization and Efficient Detection of Antibiotics of Two CdII-Based Coordination Polymers. J Clust Sci 34, 2791–2797 (2023). https://doi.org/10.1007/s10876-023-02424-9

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  • DOI: https://doi.org/10.1007/s10876-023-02424-9

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