Abstract
The Z-scheme TiO2/Bi2O3-g-C3N4 ternary heterojunction photocatalyst was successfully constructed by sol–gel method and solvothermal method. The structure, morphology, chemical composition, optical properties of photocatalyst were characterized by XRD, TEM(HRTEM), SAED, XPS, EDX, UV–vis, FTIR, PL, EIS. And the photocatalytic performance of the photocatalyst was studied by using RhB as a simulated organic pollutant. The results show that the prepared ternary heterojunction photocatalyst has high photocatalytic activity under both ultraviolet light and visible light, and the degradation rate reaches 100% in 100 min. This paper also proposes a possible Z-scheme mechanism of a ternary heterojunction photocatalyst to explain the increased photocatalytic activity.
Similar content being viewed by others
References
S. Mazhar, A. Ditta, L. Bulgariu, L. Bulgariu, I. Ahmad, M. Ahmed, and A. A. Nadiri (2019). Chemosphere 227, 256–268.
X.-Y. Gao, Q. Guo, G.-B. Tang, W.-J. Zhu, X.-X. Yang, and Y.-M. Luo (2020). J. Coll. Interface Sci. 570, 242–250.
P. K. Boruah and M. R. Das (2020). J. Hazard. Mater. 385.
M. A. Salam, M. R. AbuKhadra, and A. S. Mohamed (2020). Environ. Pollut. 259.
T. Ahamad, M. Naushad, S. I. Al-Saeedi, S. Almotairi, and S. M. Alshehri (2020). Mater. Lett. 263.
P.-H. Chang, Y.-H. Huang, C. L. Hsueh, M.-C. Lu, and G.-H. Huang (2004). Water Sci. Technol. 49 (4), 213–218.
Q. Yang, D. Chen, L.-B. Chu, and J.-L. Wang (2020). J. Hazard. Mater. 389.
P. S. De Velasco-Maldonado, V. Hernandez-Montoya, M. A. Montes-Moran, N. A. R. Vazquez, and M. A. Perez-Cruz (2018). Appl. Surf. Sci. 434, 1193–1199.
H.-Z. Li, L.-Y. Shen, K.-F. Zhang, B.-J. Sun, L.-P. Ren, P.-Z. Qiao, K. Pan, L. Wang, and W. Zhou (2018). Appl. Catal. B-Environ. 220, 111–117.
Z.-F. Bian, J. Zhu, and H.-X. Li (2016). J. Photochem. Photobiol. 28, 72–86.
H.-J. Wang, D.-P. Wu, W.-P. Wu, D.-Q. Wang, Z.-Y. Gao, F. Xu, K. Cao, and K. Jiang (2019). J. Coll. Interface Sci. 539, 194–202.
A. H. Mamaghani, F. Haghighat, and C. S. Lee (2019). Chemosphere 219, 804–825.
V. G. Parale, T. Kim, V. D. Phadtare, H. M. Yadav, and H. H. Park (2019). J. Mol. Liq. 277, 424–433.
B. J. Cha, S. Saqlain, H. O. Seo, and Y. D. Kim (2019). Appl. Surf. Sci. 479, 31–38.
U. N. Saqib, R. Adnan, and I. Shah (2016). Environ. Sci. Pollut. Res. 26 (13), 15941–15951.
X.-P. Wang, Y.-Y. Tang, M. Y. Leiw, and T. T. Lim (2011). Appl. Catal. A-Gen. 409, 257–266.
D.-L. Li, L.-L. Li, W. Guo, Z.-X. Chang, and M.-H. He (2015). Mater. Sci. Semicond. Proc. 31, 530–535.
S. A. Alim, T. Siva Rao, I. Manga Raju, M. R. Kumar, and K. V. D. Lakshmi (2019). J. Saudi Chem. Soc. 23 (1), 92–103.
M.-L. Zhang, T.-C. An, X.-L. Liu, X.-H. Hu, G.-Y. Sheng, and J.-M. Fu (2010). Mater. Lett. 64 (17), 1883–1886.
X.-Y. Guo, C.-F. Chen, W.-Y. Song, X. Wang, W.-H. Di, and W.-P. Qin (2014). J. Mol. Catal. A-Chem. 387, 1–6.
Y. Hu, D.-Z. Li, Y. Zheng, W. Chen, Y.-H. He, Y. Shao, X.-Z. Fu, and G.-C. Xiao (2011). Appl. Catal. B-Environ. 101 (1), 30–36.
S. A. Singh and G. Madras (2013). Sep. Purif. Technol. 105, 79–89.
Y. Satoshi, O. Katsuto, T. Yoshihiro, S. Tsutomu, S. Takeshi, and S. Tsugio (2012). J. Mater. Chem. 48, 24959–25506.
Y.-D. Liua, X.-A. Feng, F.-M. Wang, S.-X. Luo, and X.-H. Yin (2010). J. Alloys Compds. 498 (2), 179–184.
S. Shamaila, A. K. L. Sajjad, F. Chen, and J.-L. Zhang (2010). Appl. Catal. B-Environ. 94 (3), 272–280.
Z.-F. Bian, J. Zhu, S.-H. Wan, Y. Gao, X.-F. Qian, and H.-X. Li (2008). J. Phys. Chem. C 112 (16), 6258–6262.
R.-A. He, H.-J. Liu, H.-M. Liu, D.-X. Xu, and L.-Y. Zhang (2020). J. Mater. Sci. Technol. 52, 145–151.
M. Shi, L.-J. Luo, J.-H. Dai, L.-H. Xia, J.-H. Long, W.-R. Yang, H.-B. Wang, and L. Shu (2020). Environ. Sci. Pollut. Res. 20, 24692–24701.
N. Wang, X. Li, Y.-L. Yang, Z.-W. Zhou, Y. Shang, X.-X. Zhuang, T.-T. Zhang, and J. Water (2020). Process Eng. 35.
J. Wang, Z. Yang, W.-Q. Yao, X.-X. Gao, and D.-P. Tao (2018). Appl. Catal. B-Environ. 238, 629–637.
D. M. Ruan, S. Kim, M. Fujitsuka, and T. Majima (2018). Appl. Catal. B-Environ. 238, 638–646.
M. Malligavathy, S. Iyyapushpam, S. T. Nishanthi, and D. P. Padiyan (2017). J. Nanopart. Res. 19 (4), 144.
H. Zou, M.-X. Song, F.-C. Yi, X.-Q. Wang, L. Bian, W.-M. Li, J.-L. Zhang, N. Pan, and P. Zeng (2018). J. Mater. Sci.-Mater. Electron. 29 (3), 2201–2208.
W.-Y. Gou, P. Wu, D.-M. Jiang, and X.-M. Ma (2015). J. Alloys Compds. 646, 437–445.
S. Noor, S. Sajjad, S. A. K. Leghari, C. Flox, T. Kallio, E. I. Kauppinen, and S. Ahmad (2021). New J. Chem. 45 (5), 2431–2442.
M. Imran, A. Bin Yousaf, M. Farooq, and P. Kasak (2018). Int. J. Hydrogen Energy 43 (9), 4256–4264.
Y.-H. Liang, X. Wang, W.-J. An, Y. Li, J.-H. Hu, and W.-Q. Cui (2019). Appl. Surf. Sci. 466, 666–672.
Y.-Q. Cui, X.-Y. Zhang, R.-N. Guo, H.-X. Zhang, B. Li, M.-Z. Xie, Q.-F. Cheng, and X.-W. Cheng (2018). Sep. Purif. Technol. 203, 301–309.
M. Wang, P.-Y. Guo, T.-Y. Chai, Y.-H. Xie, J. Han, M.-Y. You, Y.-Z. Wang, and T. Zhu (2017). J. Alloys Compds. 691, 8–14.
T.-Y. Wang, W. Quan, D.-L. Jiang, L.-L. Chen, D. Li, S.-C. Meng, and M. Chen (2016). Chem. Eng. J. 300, 280–290.
X. Li, J.-G. Yu, J.-X. Low, Y.-P. Fang, J. Xiao, and X.-B. Chen (2016). J. Mater. Chem. A 3 (6), 2485–2534.
S.-H. Liang, D.-F. Zhang, X.-P. Pu, X.-T. Yao, R.-T. Han, J. Yin, and X.-Z. Ren (2019). Sep. Purif. Technol. 210, 786–797.
Acknowledgements
National Natural Science Foundation of China (20871108, 51272239); Natural Science Foundation of Shanxi Province China (201801D121066, 201901D111138).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Jing, Hx., Gao, Yl., Li, Lx. et al. Synthesis of a Novel Double Z-Scheme TiO2/Bi2O3-g-C3N4 Photocatalyst with Enhanced Photocatalytic Performance to Rhodamine B Under Sunlight. J Clust Sci 34, 1347–1354 (2023). https://doi.org/10.1007/s10876-022-02308-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10876-022-02308-4