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Structures and Magnetic Properties of Binuclear Co(II) and Dy(III) Complexes with Cis-1,3-Dibenzyl-2-Imidazolidone-4,5-Dicarboxylic Acid of Variable Conformations

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Abstract

Two new complexes [Co2(bia)2(2,2′-bpy)2] (1) and [Dy4(bia)6(2,2′-bpy)2(H2O)2]·8H2O (2) (H2bia = cis-1,3-dibenzyl-2-imidazolidone-4,5-dicarboxylic acid, 2,2′-bpy = 2,2′-bipyridine) have been synthesized by method of hydrothermal reactions and their crystal structures determined. In 1, two symmetrical Co atoms are connected through bia ligands forming a discrete rhomboid binuclear Co2 cluster. Complex 2 has a one-dimensional chain structure based on binuclear paddle-wheel Dy2 and rhomboid Dy2 units. The structure versatility indicates that the nature of the metal ion and variable conformations of bia ligand play a crucial role in modulating the cluster complexes. IR, elemental analysis and XRPD confirmed the phase purity of the bulk materials. Magnetic properties of 1 and 2 in the 300–2 K have been discussed.

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Acknowledgements

This work was supported by the Guangzhou Science and Technology Program (202102080326).

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Authors and Affiliations

  1. School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou, 510006, China

    Cen-Huai Ma, Chuan-Yi Pan & Sheng Hu

  2. Guangzhou Vocational College of Technology and Business, Guangzhou, 511442, China

    Ling-Ling Zheng

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  1. Cen-Huai Ma
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Ma, CH., Pan, CY., Zheng, LL. et al. Structures and Magnetic Properties of Binuclear Co(II) and Dy(III) Complexes with Cis-1,3-Dibenzyl-2-Imidazolidone-4,5-Dicarboxylic Acid of Variable Conformations. J Clust Sci 34, 727–733 (2023). https://doi.org/10.1007/s10876-022-02254-1

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  • DOI: https://doi.org/10.1007/s10876-022-02254-1

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