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Formation and Structures of the μ4-Oxygen-Bridged High-Nuclearity Lead(II) Clusters from a Lead Propane-2-thiolate Complex

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Abstract

Interaction of [Pb(SiPr)2]n with 1.5 equiv. of AgNO3 in DMF under aerobic conditions at room temperature gave a cationic lead-centered thiolate cluster [Pb13(SiPr)6O8](NO3)4 (1). While treatment of [Pb(SiPr)2]n in refluxing DMF in air afforded a two-dimensional layered structure of [Pb14(SiPr)16O6]n (2), comprising of [Pb14(SiPr)18O6]2− units bridged the iPrS− moieties. Molecular structures of the two oxidation products of μ4-oxygen-bridged high-nuclearity lead(II) clusters have been determined by single-crystal X-ray analysis. The UV/Vis properties of the two clusters in both solid state and solution state were also investigated in this paper.

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References

  1. 1. D. Fenske, C. Persau, S. Dehnen, and C. E. Anson (2004). Angew. Chem. Int. Ed. 43, 305–309.

    Article  CAS  Google Scholar 

  2. 2. Z. J. Wang, H. D. Ye, Y. G. Li, Y. Z. Li, and H. Yan (2013). J. Am. Chem. Soc. 135, 11289–11298.

    Article  CAS  Google Scholar 

  3. 3. M. S. Queen, B. D. Towey, K. A. Murray, B. S. Veldkamp, H. J. Byker, and R. K. Szilagyi (2013). Coord. Chem. Rev. 257, 564–578.

    Article  CAS  Google Scholar 

  4. 4. S.-J. Bao, C.-Y. Liu, M. Zhang, X.-R. Chen, H. Yu, H.-X. Li, P. Braunstein, and J.-P. Lang (2019). Coord. Chem. Rev. 397, 28–53.

    Article  CAS  Google Scholar 

  5. 5. F. Wang, F.-L. Li, M.-M. Xu, H. Yu, J.-G. Zhang, H.-T. Xia, and J.-P. Lang (2015). J. Mater. Chem. A 3, 5908–5916.

    Article  CAS  Google Scholar 

  6. 6. F. Wang, C.-Y. Ni, Q. Liu, F.-L. Li, J. Shi, H.-X. Li, and J.-P. Lang (2013). Chem. Commun. 49, 9248–9250.

    Article  CAS  Google Scholar 

  7. 7. A. L. P. Cornacchio, and N. D. Jones (2006). J. Mater. Chem. 16, 1171–1177.

    Article  CAS  Google Scholar 

  8. 8. G. G. Briand, A. D. Smith, G. Schatte, A. J. Rossini, and R. W. Schurko (2007). Inorg. Chem. 46, 8625–8637.

    Article  CAS  Google Scholar 

  9. 9. P. B. Hitchcock, M. F. Lappert, B. J. Samways, and E. L. Weinberg (1983). J. Chem. Soc., Chem. Comm. 1492–1494

    Article  Google Scholar 

  10. 10. P. B. Hitchcock, H. A. Jasim, R. E. Kelly, and M. F. Lappert (1985). J. Chem. Soc., Chem. Comm. 1778–1780

    Article  Google Scholar 

  11. 11. F. T. Edelmann, J.-K. F. Buijink, S. A. Brooker, R. Herbst-Irmer, U. Kilimann, and F. M. Bohnen (2000). Inorg. Chem. 39, 6134–6135.

    Article  CAS  Google Scholar 

  12. 12. A. Eichhöfer (2005). Eur. J. Inorg. Chem. 9, 1683–1688.

    Article  CAS  Google Scholar 

  13. 13. R. A. Shaw, M. Woods (1971). J. Chem. Soc. A 1569–1571.

    Article  Google Scholar 

  14. SMART and SAINT+ for Windows NT Version 6.02a, Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin, USA (1998).

  15. 15. G. M. Sheldrick, SADABS, University of Göttingen, Germany (1996).

    Google Scholar 

  16. G. M. Sheldrick, SHELXTL Software Reference Manual. Version 5.1, (Bruker AXS Inc, Madison, Wisconsin, USA, 1997).

  17. 17. G. M. Sheldrick (2008), Acta Crystallogr. A 64 112–122.

    Article  CAS  Google Scholar 

  18. 18. J. L. Liu, F. Hu, M. M. Sheng, A.-Q. Jia, and Q.-F. Zhang (2020), J. Cluster Sci. DOI: 10.1007/s10876-020-01872-x.

    Article  Google Scholar 

  19. 19. J. S. Magyar, T. C. Weng, C. M. Stern, D. F. Dye, and H. A. Godwin (2005). J. Am. Chem. Soc. 127, 9495–9505.

    Article  CAS  Google Scholar 

  20. 20. P. A. W. Dean, J. J. Vittal, and N. C. Payne (1984). Inorg. Chem. 23, 4232–4236.

    Article  CAS  Google Scholar 

  21. 21. P. Klüfers and J. Schuhmacher (1994). Angew. Chem. Int. ed. Engl. 33, 1863–1865.

    Article  Google Scholar 

  22. 22. P. Klüfers and J. Schuhmacher (1995). Z. Anorg. Allg. Chem. 621, 19–22.

    Article  Google Scholar 

  23. 23. M. Katz, H. Kaluarachchi, R. Batchelor, A. Bokov, Z. G. and Ye, D. Leznoff (2007). Angew. Chem. 46, 8720–8720.

    Google Scholar 

  24. 24. A. Eichhöfer, O. Hampe, and M. Blom (2003). Eur. J. Inorg. Chem. 1307–1314

    Article  Google Scholar 

  25. 25. S. E. Appleton, G. G.Briand, A. Decken, and A. S. Smith (2004). Dalton Trans. 21, 3515–3520.

    Article  CAS  Google Scholar 

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Acknowledgements

This project was supported by Natural Science Foundation of Anhui Province (2008085MB58) and Young Wanjiang Scholar program of Anhui Province.

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  1. Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, Anhui, 243002, People’s Republic of China

    Shun-Shun Qin, Jing-Long Liu, Feng Hu, Ai-Quan Jia, Chao Xu & Qian-Feng Zhang

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  1. Shun-Shun Qin
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  2. Jing-Long Liu
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Correspondence to Qian-Feng Zhang.

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Qin, SS., Liu, JL., Hu, F. et al. Formation and Structures of the μ4-Oxygen-Bridged High-Nuclearity Lead(II) Clusters from a Lead Propane-2-thiolate Complex. J Clust Sci 32, 1593–1599 (2021). https://doi.org/10.1007/s10876-020-01917-1

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