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Structural Surface Features of Paramagnetic Multifunctional Nanohybrids Based on Silver Oleic Acid

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Abstract

Sols of core–shell silver nanoparticles (AgNPs) are synthesized by electrochemical method. The method provides the ability to adjust the particle size by changing both the concentration of oleic acid and the residence time τ0 in the organic phase. We synthesized AgNPs with oleic acid (OA) concentration of 0.25% (AgNPs & 0.25% OA) and 0.75% (AgNPs & 0.75% OA). These nanoparticles have been studied using modern physical–chemical methods. Differential thermal analysis curves indicate the chemical nature of bond ligand in the secondary shell; this conclusion is confirmed by quantum chemical simulation and semi-empirical calculation. In the electron paramagnetic resonance spectra of silver-containing sols AgNPs & 0.25% OA and AgNPs & 0.75% OA complex wide asymmetric signals of 500–800 G and g-factor of 2.09–2.13 are recorded, in addition, in the spectra of AgNPs with bilayer the pronounced ferromagnetic contribution is observed. The change of the oleic acid layers of the particles affects the dimension of the nanocrystallites that are being formed and the manifestation of their magnetism.

Trial registration number and date of registration JCS-P-20-03-0188.R1, 22-Sep-2020 (02-Mar-2020)

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Acknowledgements

The project has been fulfilled with financial support of National Science Foundation of Georgia (Grant No 217020). The authors are grateful to the Baikal Analytical Center of Collective Use, SB RAS. Research studies is performed by S.S. Khutsishvili in the framework of State contracts No AAAA-A1611611210009-5 of the program of fundamental research.

Funding

The project has been fulfilled with financial support of National Science Foundation of Georgia (Grant No 217020).

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Authors and Affiliations

  1. Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences, 1 Favorsky St., Irkutsk, 664033, Russia

    Spartak S. Khutsishvili

  2. Research Institute of Green and Sustainable Chemistry, Georgian Technical University, 17 Guramishvili Ave, 0175, Tbilisi, Georgia

    Polina Toidze, Marine Donadze, Maia Gabrichidze, Nino Makhaldiani & Tamaz Agladze

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  1. Spartak S. Khutsishvili
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Supplementary file 1 (TIF 1403 kb) Fig. S1 TGA and DTA curves of (a) AgNPs & 0.25% OA and (b) AgNPs & 0.75% OA sols

Supplementary file 2 (TIF 449 kb) Fig. S2 XRD spectra for (a) AgNPs & 0.25% OA and (b) AgNPs & 0.75% OA sols

Supplementary file 3 (TIF 360 kb) Fig. S3 FT-IR spectra for (a) AgNPs & 0.25% OA and (b) AgNPs & 0.75% OA sols

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Supplementary file 4 (TIF 1527 kb) Fig. S4 OFW plots at various mass loss for (a) AgNPs & 0.25% OA and (b) AgNPs & 0.75% OA sols

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Supplementary file 5 (TIF 162 kb) Fig. S5 Thermodesorption activation energies calculated by OFW method as a function of the conversion degree

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Supplementary file 6 (TIF 1669 kb) Fig. S6 Calculated values of (a) effective charges and (b) potential of free OA molecule

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Supplementary file 7 (TIF 768 kb) Fig. S7 Calculated values of chemisorbed OA molecules for (a) AgNPs & 0.25% OA and (b) AgNPs & 0.75% OA sols

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Khutsishvili, S.S., Toidze, P., Donadze, M. et al. Structural Surface Features of Paramagnetic Multifunctional Nanohybrids Based on Silver Oleic Acid. J Clust Sci 32, 1351–1359 (2021). https://doi.org/10.1007/s10876-020-01904-6

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