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A Double-Layered {Cu9} Nanocage with Diacylhydrazine: Synthesis, Structure and Magnetic Properties

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Abstract

The reaction of a multidentate diacylhydrazine ligand N,N′-bis(2-hydroxy-3-naphthoyl)oxalylhydrazide (H6hnohz) with copper acetate in the presence of pyridine (Py), resulted in a novel Cu nanocluster, [Cu II9 (hnohz)3(Py)8]·7DMSO (1). This nanocluster consists of a {CuII4} and a {CuII5} cluster units, which were linked together by the coordination bonds between them owing to the Jahn–Teller effects of the CuII centers and flexible coordination modes of the hnohz6− ligands. The Py was found to act as not only the deprotonating reagent in the synthesis, but the peripheral ligand in molecular structure. Whether in {CuII4} or in {CuII5} unit, the CuII ions are approximatively coplanar. And the meaning planes of two units are just parallel. Thus 1 displays a double-layered cage-like skeleton that was rarely reported in previous literature. Variable temperature magnetic susceptibility measurement revealed dominate antiferromagnetic couplings between the CuII ions in the system of 1.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 21961008 and 21771043) and the Guangxi Natural Science Foundation (No. 2018GXNSFAA138123).

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  1. Sheng-Xue Huang and Fan Xu have contributed equally to this work.

Authors and Affiliations

  1. Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China

    Sheng-Xue Huang, Fan Xu, Kai Wang, Yan Li, Shu-Hua Zhang, Xiu-Qing Zhang, Shu-Ying Luo & Fu-Pei Liang

  2. State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, China

    Shu-Jian Qi

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  1. Sheng-Xue Huang
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Huang, SX., Xu, F., Qi, SJ. et al. A Double-Layered {Cu9} Nanocage with Diacylhydrazine: Synthesis, Structure and Magnetic Properties. J Clust Sci 32, 765–772 (2021). https://doi.org/10.1007/s10876-020-01838-z

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