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Structure and Magnetic Properties of Tetranuclear Dysprosium Cluster Based on 2,6-bis(2-((E)-(8-Hydroxyquinolin-2-yl)methylene)hydrazine-1-carbonyl)pyridine 1-oxide

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Abstract

The complex [Dy4(L1)2(CH3COO)4(DMF)3] (1) was obtained by using 2,6-bis(2-((E)-(8-hydroxyquinolin-2-yl)methylene)hydrazine-1-carbonyl)pyridine 1-oxide (H4L1) and Dy(CH3COO)3·4H2O under 100 in N,N-dimethylformamide (DMF) solvent. Structure analyzing showed that Dy(III) ions had two types of configuration with D2d and C4v. AC magnetic susceptibilities exhibited that complex 1 was an obvious single-molecule magnet (SMM) with obvious ac susceptibilities at zero Oe static magnetic field over the frequency range of 9–999 Hz. These findings demonstrated potential applications of polydentate ligands for the synthesis of SMMs.

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Acknowledgements

This work is supported by the Special Fund for Outstanding Youth Cultivation of Henan Academy of Sciences (No. 190403004).

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Authors and Affiliations

  1. School of Architecture, Sias University, Zhengzhou, 451100, People’s Republic of China

    Yu-Meng Zhang

  2. Institute of Chemistry Co. Ltd Henan Academy of Sciences, Zhengzhou, 450002, People’s Republic of China

    Fu-Wei Zheng, Hai-Tao Chen, De-Jin Li, Fu-Jiao Han & Liu Yang

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  1. Yu-Meng Zhang
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  2. Fu-Wei Zheng
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Zhang, YM., Zheng, FW., Chen, HT. et al. Structure and Magnetic Properties of Tetranuclear Dysprosium Cluster Based on 2,6-bis(2-((E)-(8-Hydroxyquinolin-2-yl)methylene)hydrazine-1-carbonyl)pyridine 1-oxide. J Clust Sci 32, 737–742 (2021). https://doi.org/10.1007/s10876-020-01837-0

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  • DOI: https://doi.org/10.1007/s10876-020-01837-0

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