Skip to main content
SpringerLink
Log in

A Chained Iodocuprate(I) and its Photoluminescence Behavior

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

The simple solvothermal self-assemble of CuI, 1,4-bis(2-methyl-1H-imidazol-1-yl)butane (L1) and HI in a C2H5OH solvent at pH = 2 created a new H2(L1)2+-templated 1-D chained iodocuprate(I) [H2(L1)][Cu3I5] 1. The crystal data reveal that the Cu-I chain mode in 1 is rare. Two folded Cu2I2 cores first aggregate into a trinuclear cluster by sharing an edge. Then the extra I− ions doublely bridge these trinuclear clusters into the title 1-D chain of 1. Synchronously, a non-folded Cu2I2 cluster is formed. In 1, all of the Cu···Cu distances are smaller than 2.8 Å. The investigation on photoluminescence property indicates that with the decrease of the temperature, the photoluminescence emission for 1 exhibits a minor change from the green-yellow light (298 K) to yellow light (77 K). This means that 1 might possess the fluorescent thermochromic property.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. G. N. Liu, R. Y. Zhao, H. Xu, Z. H. Wang, Q. S. Liu, M. Z. Shahid, J. L. Miao, G. Chen, and C. Li (2018). Dalton Trans. 47, 2306–2317.

    Article  CAS  Google Scholar 

  2. T. Sengupta, T. T. Dang, J. S. Chung, and S. G. Kang (2019). N. J. Chem. 43, 16176–16187.

    Article  CAS  Google Scholar 

  3. L. K. Gong, J. R. Li, Z. F. Wu, B. Hu, Z. P. Wang, N. N. Shen, Q. Q. Hu, Z. H. Deng, Z. Z. Zhang, J. J. Fu, K. Z. Du, and X. Y. Huang (2019). J. Mater. Chem. C. 7, 9803–9807.

    Article  CAS  Google Scholar 

  4. A. H. Sun, Q. Wei, A. P. Fu, S. D. Han, J. H. Li, and G. M. Wang (2018). Dalton Trans. 47, 6965–6972.

    Article  CAS  Google Scholar 

  5. L. Zhang, C. Tang, W. Zheng, W. Jiang, and D. Jia (2019). Eur. J. Inorg. Chem. 19, 237–244.

    Article  Google Scholar 

  6. Y. Zhang, C. Zhao, S. You, J. Zou, N. Yan, S. Zhang, and W. Li (2019). J. Clust. Sci.. https://doi.org/10.1007/s10876-019-01727-0.

    Article  Google Scholar 

  7. L. Zhang, W. Zheng, S. Li, J. Han, W. Jiang, and D. Jia (2019). Inorg. Chim. Acta 484, 104–110.

    Article  CAS  Google Scholar 

  8. N. Nuñoz-Castro, M. Fuentealba, E. G. Pérez, and J. J. Hurtado (2019). Inorg. Chim. Acta. https://doi.org/10.1016/j.ica.2019.119136.

    Article  Google Scholar 

  9. S. Chen, J. Gao, J. Chang, Y. Li, C. Huangfu, H. Meng, Y. Wang, G. Xia, and L. Feng (2019). ACS. Appl. Mater. Interfaces. 11, 17513–17520.

    Article  CAS  Google Scholar 

  10. T. L. Yu, Y. M. Guo, G. X. Wu, X. F. Yang, M. Xue, Y. L. Fu, and M. S. Wang (2019). Coord. Chem. Rev. 397, 91–111.

    Article  CAS  Google Scholar 

  11. Z. Wu, C. Ji, Z. Sun, S. Wang, S. Zhao, W. Zhang, L. Li, and J. Luo (2018). J. Mater. Chem. C. 6, 1171–1175.

    Article  CAS  Google Scholar 

  12. P. Hou, C. Guo, M. Wang, J. Shen, and Y. Fu (2019). Inorg. Chem. 58, 3364–3373.

    Article  Google Scholar 

  13. M. Mathlouthi, A. C. Dhieb, A. Valkonen, M. Rzaigui, and W. Smirani (2017). J. Clust. Sci. 28, 3159–3174.

    Article  CAS  Google Scholar 

  14. S. Eppel, N. Fridman, and G. Frey (2015). Cryst. Growth Des. 15, 4363–4371.

    Article  CAS  Google Scholar 

  15. G. N. Liu, R. D. Xu, R. Y. Zhao, Y. Sun, Q. B. Bo, Z. Y. Duan, Y. H. Li, Y. Y. Wang, Q. Xu, and C. Li (2019). ACS Sustain. Chem. Eng. 7, 18863–18873.

    Article  CAS  Google Scholar 

  16. G. N. Liu, R. Y. Zhao, R. D. Xu, X. Zhang, X. N. Tang, Q. J. Dan, Y. W. Wei, Y. Y. Tu, Q. B. Bo, and C. Li (2018). Cryst. Growth Des. 18, 5441–5448.

    Article  CAS  Google Scholar 

  17. J. Conesa-Egea, F. Zamora, and P. Amo-Ochoa (2019). Coord. Chem. Rev. 381, 65–78.

    Article  CAS  Google Scholar 

  18. W. Liu, Y. Fang, and J. Li (2018). Adv. Funct. Mater. 28, 170593(1–24).

  19. A. Vacher, A. A. F. Camerel, Y. Molard, C. Latouche, T. Roisnel, V. Dorcet, A. Boucekkine, H. Akdas-Kilic, and M. Achard (2019). Dalton Trans. 48, 2128–2134.

    Article  CAS  Google Scholar 

  20. F. Juvenal, D. Fortin, and P. D. Harvey (2018). Inorg. Chem. 57, 7208–7221.

    Article  CAS  Google Scholar 

  21. H. E. Moll, M. Cordier, G. Nocton, F. Massuyeau, C. Latouche, C. Martineau-Corcos, and S. Perruchas (2018). Inorg. Chem. 57, 11961–11969.

    Article  Google Scholar 

  22. J. H. Liu, Y. J. Qi, D. Zhao, H. H. Li, and S. T. Zheng (2019). Inorg. Chem. 58, 516–523.

    Article  CAS  Google Scholar 

  23. A. M. Wheaton, M. E. Streep, C. M. Ohlhaver, A. D. Nicholas, F. H. Barnes, H. H. Patterson, and R. D. Pike (2018). ACS Omega 3, 15281–15292.

    Article  CAS  Google Scholar 

  24. A. Schlachter, L. Viau, D. Fortin, L. Knauer, C. Strohmann, M. Knorr, and P. Harvey (2017). Inorg. Chem. 57, 13564–13567.

    Article  Google Scholar 

  25. W. Liu, K. Zhu, S. J. Teat, G. Dey, Z. Shen, L. Wang, D. M. O′Carroll, and J. Li (2017). J. Am. Chem. Soc. 139, 9281–9290.

    Article  CAS  Google Scholar 

  26. Z. Wu, L. Li, C. Ji, G. Lin, S. Wang, Y. Shen, Z. Sun, S. Zhao, and J. Luo (2017). Inorg. Chem. 56, 8776–8781.

    Article  CAS  Google Scholar 

  27. R. Y. Wang, X. Zhang, J. H. Yu, and J. Q. Xu (2019). J. Solid State Chem. 269, 239–245.

    Article  CAS  Google Scholar 

  28. R. Y. Wang, X. Zhang, J. H. Yu, and J. Q. Xu (2018). RSC Adv. 8, 36150–36160.

    Article  CAS  Google Scholar 

  29. R. Y. Wang, J. H. Yu, and J. Q. Xu (2019). Dalton Trans 48, 5674–5682.

    Article  CAS  Google Scholar 

  30. R. Y. Wang, X. Zhang, J. H. Yu, and J. Q. Xu (2019). Photochem. Photobiol. Sci. 18, 477–486.

    Article  CAS  Google Scholar 

  31. G. M. Sheldrick (2008). Acta Crystallogr. Sect. A Found. Crystallogr. 64, 112–122.

    Article  CAS  Google Scholar 

  32. C. Y. Yue, H. X. Sun, Q. X. Liu, X. M. Wang, Z. S. Yuan, J. Wang, J. H. Wu, B. Hu, and X. W. Lei (2019). Inorg. Chem. Front. 6, 2709–2717.

    Article  CAS  Google Scholar 

  33. B. D. Ge, Q. Wei, A. H. Sun, C. Y. Lin, X. F. Duan, J. H. Li, and G. M. Wang (2019). Chem. Asian. J. 14, 2086–2090.

    Article  CAS  Google Scholar 

  34. Q. Wei, B. D. Ge, J. Zhang, A. H. Sun, J. H. Li, S. D. Han, and G. M. Wang (2019). Chem. Asian. J. 14, 269–277.

    Article  CAS  Google Scholar 

  35. Z. Y. Chen, S. Lin, Y. L. Huang, and B. G. Chen (2017). J. Clust. Sci. 28, 1551–1564.

    Article  CAS  Google Scholar 

  36. J. Q. Cui, T. S. Guo, K. B. Chu, C. Wu, G. Yang, J. L. Song, and C. Zhang (2017). Z. Anorg. Allg. Chem. 643, 483–487.

    Article  CAS  Google Scholar 

  37. R. Y. Wang, X. Zhang, Q. S. Huo, J. H. Yu, and J. Q. Xu (2017). RSC Adv. 7, 19073–19080.

    Article  CAS  Google Scholar 

  38. F. Liu, P. Hao, T. Yu, Q. Guan, and Y. Fu (2016). J. Mol. Struct. 1119, 431–436.

    Article  CAS  Google Scholar 

  39. A. M. Kirillov, P. Smoleński, Z. Ma, M. F. C. G. D. Silva, M. Haukka, and A. J. L. Pombeiro (2009). Organometallics 28, 6425–6431.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors are grateful to the financial aid from the National Natural Science Foundation of China (Grant No. 21771076).

Author information

Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130012, Jilin, China

    Rong-Yan Wang, Xue-Jian Qu, Jie-Hui Yu & Ji-Qing Xu

Authors
  1. Rong-Yan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xue-Jian Qu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jie-Hui Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ji-Qing Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jie-Hui Yu.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, RY., Qu, XJ., Yu, JH. et al. A Chained Iodocuprate(I) and its Photoluminescence Behavior. J Clust Sci 32, 193–197 (2021). https://doi.org/10.1007/s10876-020-01777-9

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-020-01777-9

Keywords

Search

Navigation