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Metal–Ligand Ratio Controlled Assembly Of Two Heterometallic CuEr Cluster Complexes: Syntheses, Structures and Magnetism

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Abstract

Two new heterometallic CuEr cluster complexes based on 3,5-dichlorobenzoic acid (HL) and 2,2′:6′,2″-terpyridine (TPY), [Cu(L)(TPY)][Er(L)4]·H2O (1) and [Cu(L)(TPY)][Er2(L)7] (2), have been hydrothermally prepared by controlling the metal–ligand ratios. Comparative study revealed that metal–ligand ratios affected the coordination modes of L− and thus generate two distinct structures. Both complexes display as ion-pair bicomponent structures. The cationic [Cu(L)(TPY)]+ components show the similar binuclear cluster structure in two complexes, while the two anionic parts are very different. In 1, two Er(III) centers are coordinated by four bridging and four chelating L− ligands to form the binuclear anionic [Er2(L)8]2− cluster. While in 2, all L− ligands show the bridging modes and connect the Er(III) centers into an extended one-dimensional (1D) chain. So the overall structures of 1 and 2 are bicomponent 0D + 0D and 0D + 1D structures, respectively. Direct current magnetic susceptibility measurements were performed for two complexes and they both showed antiferromagnetic behavior.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 21601105) and the Scientific Research Foundation of Qufu Normal University (No. 6106).

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  1. College of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, 273165, China

    Fang-Hua Zhao, Zhong-Lin Li, Ya-Hua Yu, Shi-Ying Fan, Xiao-Wen Guo & Zi-Hao Zhao

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Zhao, FH., Li, ZL., Yu, YH. et al. Metal–Ligand Ratio Controlled Assembly Of Two Heterometallic CuEr Cluster Complexes: Syntheses, Structures and Magnetism. J Clust Sci 32, 45–54 (2021). https://doi.org/10.1007/s10876-019-01757-8

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