Isolation and Structures of One- and Two-Dimensional High-Nuclearity Silver(I) Clusters from a Silver Propane-2-thiolate Chain

Abstract

Interaction of [Ag(SiPr)]n and CF3CO2Ag in methanol led to isolation of a one-dimensional chain silver cluster {[Ag24(μ-OH2)2(μ-O2CCF3)101-O2CCF3)24-SiPr)12(OH2)4(HOCH3)6]·(H2O)4}n (1). Reaction of [Ag(SiPr)]n and Et4N·I in dimethylformide gave a tubular cluster [Ag368-I)63-SiPr)30]n (2). Treatment of a mixed suspension of [Ag(SiPr)]n/AgI in methanol with HSiPr in the presence of Et3N resulted in formation of a two-dimensional anionic cluster {(HNEt3)4[Ag362-I)43-I)84-I)123-SiPr)16]}n (3). Structures of three clusters were established by single crystal X-ray diffraction and their solid ultraviolet properties were also investigated.

Graphic Abstract

Three polymeric frameworks of high-nuclearity silver(I) thiolate clusters have been isolated employing [Ag(SiPr)]n as a starting material and their structures were characterized by single-crystal X-ray diffraction.

This is a preview of subscription content, access via your institution.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

References

  1. 1.

    Z. Wang, H.-F. Su, M. Kurmoo, C.-H. Tung, D. Sun, and L.-S. Zheng (2018). Nat. Commun. 9, 2094.

    Article  Google Scholar 

  2. 2.

    X. Meng, F. Wang, and G.-X. Jin (2010). Coord. Chem. Rev. 254, 1260.

    CAS  Article  Google Scholar 

  3. 3.

    B. S. Bassil, M. Ibrahim, R. Al-Oweini, M. Asano, Z. X. Wang, J. van Tol, N. S. Dalal, K. Y. Choi, R. N. Biboum, B. Keita, L. Nadjo, and U. Kortz (2011). Angew. Chem. Int. Ed. 50, 5961.

    CAS  Article  Google Scholar 

  4. 4.

    T. Wu, F. Zuo, L. Wang, X. H. Bu, S. T. Zheng, R. Ma, and P. Y. Feng (2011). J. Am. Chem. Soc. 133, 15886.

    CAS  Article  Google Scholar 

  5. 5.

    S. P. Argent, A. Greenaway, M. D. C. Gimenez-Lopez, W. Lewis, H. Nowell, A. N. Khlobystov, A. J. Blake, N. R. Champness, and M. Schröder (2012). J. Am. Chem. Soc. 134, 55.

    CAS  Article  Google Scholar 

  6. 6.

    Q.-M. Wang, Y.-M. Lin, and K.-G. Liu (2015). Acc. Chem. Res. 48, 1570.

    CAS  Article  Google Scholar 

  7. 7.

    Z. Li, X.-X. Li, T. Yang, Z.-W. Cai, and S.-T. Zheng (2017). Angew. Chem. Int. Ed. 56, 2664.

    CAS  Article  Google Scholar 

  8. 8.

    O. Fuhr, S. Dehnen, and D. Fenske (2013). Chem. Soc. Rev. 42, 1871.

    CAS  Article  Google Scholar 

  9. 9.

    H. Y. Yang, Y. Wang, H. Q. Huang, L. Gell, L. Lehtovaara, S. Malola, H. Häkkinen, and N. F. Zheng (2013). Nat. Commun. 4, 2422.

    Article  Google Scholar 

  10. 10.

    X.-L. Pei, Y. Yang, Z. Lei, and Q.-M. Wang (2013). J. Am. Chem. Soc. 135, 6435.

    CAS  Article  Google Scholar 

  11. 11.

    Z. Wang, X.-Y. Li, L.-W. Liu, S.-Q. Yu, Z.-Y. Feng, C.-H. Tung, and D. Sun (2016). Chem. Eur. J. 22, 6830.

    CAS  Article  Google Scholar 

  12. 12.

    S. Li, X.-S. Du, J.-Y. Wang, G.-P. Li, G.-G. Gao, and S.-Q. Zang (2018). J. Am. Chem. Soc. 140, 594.

    CAS  Article  Google Scholar 

  13. 13.

    V. W.-W. Yam and K. M.-C. Wong (2011). Chem. Commun. 47, 11579.

    CAS  Article  Google Scholar 

  14. 14.

    X.-D. Wang, O. S. Wolfbeis, and R. J. Meier (2013). Chem. Soc. Rev. 42, 7834.

    CAS  Article  Google Scholar 

  15. 15.

    Y.-L. Li, W.-M. Zhang, J. Wang, Y. Tian, Z. Y. Wang, C. X. Du, S.-Q. Zang, and T. C. W. Mak (2018). Dalton Trans. 47, 14884.

    CAS  Article  Google Scholar 

  16. 16.

    S. Bestgen, O. Fuhr, B. Breitung, V. S. Kiran, G. Chakravadhanula, F. Guthausen, W. Hennrich, M. M. Yu, P. W. Kappes, and D. Fenske Roeskya (2017). Chem. Sci. 8, 2235.

    CAS  Article  Google Scholar 

  17. 17.

    M. Hailmann, N. Wolf, R. Renner, T. C. Schäfer, B. Hupp, A. Steffen, and M. Finze (2016). Angew. Chem. Int. Ed. 55, 10507.

    CAS  Article  Google Scholar 

  18. 18.

    A. M. Polgar, F. Weigend, A. Zhang, M. J. Stillman, and J. F. Corrigan (2017). J. Am. Chem. Soc. 139, 14045.

    CAS  Article  Google Scholar 

  19. 19.

    J.-W. Liu, L. Feng, H. Su, Z. Wang, Q.-Q. Zhao, X. Wang, C.-H. Tung, D. Sun, and L.-S. Zheng (2018). J. Am. Chem. Soc. 140, 1600.

    CAS  Article  Google Scholar 

  20. 20.

    M. S. Bootharaju, C. P. Joshi, M. J. Alhilaly, and O. M. Bakr (2016). Chem. Mater. 28, 3292.

    CAS  Article  Google Scholar 

  21. 21.

    Y. Liu, B. K. Najafabadi, M. A. Fard, and J. F. Corrigan (2015). Angew. Chem. Int. Ed. 54, 4832.

    CAS  Article  Google Scholar 

  22. 22.

    D. Rais, J. Yau, D. M.-P. Mingos, R. Vilar, A. J.-P. White, and D. J. Williams (2001). Angew. Chem. Int. Ed. 40, 3464.

    CAS  Article  Google Scholar 

  23. 23.

    Y.-P. Xie, J.-L. Jin, G.-X. Duan, X. Lu, and T. C. W. Mak (2017). Coord. Chem. Rev. 331, 54.

    CAS  Article  Google Scholar 

  24. 24.

    Y.-P. Xie, J.-L. Jin, X. Lu, and T. C. W. Mak (2015). Angew. Chem. Int. Ed. 54, 15176.

    CAS  Article  Google Scholar 

  25. 25.

    J.-L. Jin, Y.-P. Xie, H. Cui, G.-X. Duan, and T. C. W. Mak (2017). Inorg. Chem. 56, 10412.

    CAS  Article  Google Scholar 

  26. 26.

    S. Li, Z.-Y. Wang, G.-G. Gao, B. Li, P. Luo, Y.-J. Kong, H. Liu, and S.-Q. Zang (2018). Angew. Chem. Int. Ed. 57, 1.

    CAS  Article  Google Scholar 

  27. 27.

    J.-H. Liao, C. Latouche, B. Li, S. Kahlal, J.-Y. Saillard, and C. W. Liu (2014). Inorg. Chem. 53, 2260.

    CAS  Article  Google Scholar 

  28. 28.

    X.-Y. Li, H.-F. Su, K. Yu, Y.-Z. Tan, X.-P. Wang, Y.-Q. Zhao, D. Sun, and L.-S. Zheng (2015). Nanoscale 7, 8284.

    CAS  Article  Google Scholar 

  29. 29.

    Z. Wang, H.-F. Su, Y.-Z. Tan, S. Schein, S.-C. Lin, W. Liu, S.-A. Wang, W.-G. Wang, C.-H. Tung, D. Sun, and L.-S. Zheng (2017). PNAS 114, 12132.

    CAS  Article  Google Scholar 

  30. 30.

    Y.-J. Li, C. Latouche, S. Kahlal, J.-H. Liao, R. S. Dhayal, J.-Y. Saillard, and C. W. Liu (2012). Inorg. Chem. 51, 7439.

    CAS  Article  Google Scholar 

  31. 31.

    B. Li, J.-H. Liao, Y.-J. Li, and C. W. Liu (2013). CrystEngComm 15, 6140.

    CAS  Article  Google Scholar 

  32. 32.

    J.-H. Liao, H.-W. Chang, Y.-J. Li, C.-S. Fang, B. Sarkar, W. E. van Zyl, and C. W. Liu (2014). Dalton Trans. 43, 12380.

    CAS  Article  Google Scholar 

  33. 33.

    I. G. Dance, K. J. Fisher, R. M. H. Banda, and M. L. Scudder (1991). Inorg. Chem. 30, 183.

    CAS  Article  Google Scholar 

  34. 34.

    G. M. Sheldrick SADABS (University of Göttingen, Germany, 1996).

    Google Scholar 

  35. 35.

    G. M. Sheldrick, SHELXTL Software Reference Manual (Version 5.1) (Bruker AXS Inc., Madison, 1997).

  36. 36.

    G. M. Sheldrick (2008). Acta Crystallogr. A 64, 112.

    CAS  Article  Google Scholar 

  37. 37.

    A. L. Spek (2015). Acta Cryst. C 71, 9.

    CAS  Article  Google Scholar 

  38. 38.

    S.-Z. Zhan, M. Li, X.-P. Zhou, J.-H. Wang, J.-R. Yang, and D. Li (2011). Chem. Commun. 47, 12441.

    CAS  Article  Google Scholar 

  39. 39.

    G. Li, Z. Lei, and Q.-M. Wang (2010). J. Am. Chem. Soc. 132, 17678.

    CAS  Article  Google Scholar 

  40. 40.

    K. Zhou, X.-L. Wang, C. Qin, H.-N. Wang, G.-S. Yang, Y.-Q. Jiao, P. Huang, K.-Z. Shao, and Z.-M. Su (2013). Dalton Trans. 42, 1352.

    CAS  Article  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (90922008) and Young Wanjiang Scholar program of Anhui Province.

Author information

Affiliations

Authors

Corresponding author

Correspondence to Qian-Feng Zhang.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Jia, AQ., Sheng, MM., Che, G. et al. Isolation and Structures of One- and Two-Dimensional High-Nuclearity Silver(I) Clusters from a Silver Propane-2-thiolate Chain. J Clust Sci 31, 1233–1240 (2020). https://doi.org/10.1007/s10876-019-01730-5

Download citation

Keywords

  • Poly-nuclear silver(I) complex
  • Polymer
  • Thiolate
  • Coordination assembly
  • Crystal structure