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Highly Selective Sensing of Cd(II) Ion by Hexanuclear Functionalized Zn(II) Cluster

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Abstract

The organic ligand 1,10-phenanthroline-2,9-dicarboxylic acid (H2L) was used to react with ZnSO4·7H2O at 140 °C for two days to obtain the complex [Zn6(L)6(H2SO4)]·3CH3CN·Et3N (1). The structure of complex is confirmed by X-ray crystallography, TG and PXRD. The structure suggested that six ligands chelated with six Zn2+ ions. Every five-coordinated Zn(II) ion is surrounded by two N atoms and three O atoms (one sulfate radical or three ligands) with the N2O3 coordination environment. Each Zn(II) ion in the structure of complex 1 binds only one L2− ligand. The metal center Zn2 and Zn3 are bridged by SO42−. The photoluminescence of complex 1 is obvious. Moreover, in the presence of Cd2+ ions, the complex exhibits an efficient recognition ability, and it realizes the recognition of toxic metal ions.

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Acknowledgements

This work was supported by the Foundation of Key Laboratory of Functional Metal-Organic Compounds of Hunan Province (M018K05).

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Authors and Affiliations

  1. Key Laboratory of Functional Metal-Organic Compounds of Hunan Province, Hunan Province Universities Key Laboratory of Functional Organometallic Materials, College of Chemistry and Material Science, Hengyang Normal University, Hengyang, 421008, Hunan, People’s Republic of China

    Liang-Bing Sheng, Meng-Qin Liu & Man-Sheng Chen

  2. School of Chemical Engineering and Resource Recycling, Wuzhou University, Wuzhou, Guangxi, 543002, People’s Republic of China

    Shi-Xiong Li

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  1. Liang-Bing Sheng
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  2. Meng-Qin Liu
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  3. Shi-Xiong Li
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Correspondence to Liang-Bing Sheng, Shi-Xiong Li or Man-Sheng Chen.

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Sheng, LB., Liu, MQ., Li, SX. et al. Highly Selective Sensing of Cd(II) Ion by Hexanuclear Functionalized Zn(II) Cluster. J Clust Sci 31, 429–434 (2020). https://doi.org/10.1007/s10876-019-01656-y

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