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2-Chlorobenzoate Complex of Cu(II): Unexpected Appearance of Halogen···Halogen Contacts in Solid State

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Abstract

Complex of copper [Cu2(2-ClBenz)4((acetone)2] (2-ClBenz = 2-chlorobenzoate) was prepared and characterized by X-ray diffractometry. In the crystal structure, the binuclear complex fragments are connected via Cl···Cl contacts (3.440 Å); their energies were estimated by theoretical methods.

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Fig. 1
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Notes

  1. 100 mg of [Cu2(2-ClBenz)4(H2O)2] were dissolved in 10 ml of boiling acetone. The solution was slowly cooled to room temperature; partial evaporation resulted in precipitation of blue crystals of 1. Yield 95%. For C34H28O10Cu2Cl4 calcd,  %: C, 47.3; H, 3.3; found,  %: C, 47.5; H, 3.4.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva St. 3, Novosibirsk, Russia, 630090

    Sergey A. Adonin, Mikhail D. Petrov, Maxim N. Sokolov & Vladimir P. Fedin

  2. Novosibirsk State University, Pirogova St. 2, Novosibirsk, Russia, 630090

    Sergey A. Adonin, Maxim N. Sokolov & Vladimir P. Fedin

  3. Institute of Chemistry, Saint Petersburg State University, Universitetskaya Nab. 7-9, Saint Petersburg, Russia, 199034

    Alexander S. Novikov

  4. Ufa State Petroleum Technological University, Ufa, Russia

    Rishat R. Shiriyazdanov

  5. Alexander Butlerov Institute of Chemistry, Kazan Federal University, Lobachevskogo str. 1/29, Kazan, Russia, 420008

    Maxim N. Sokolov

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  1. Sergey A. Adonin
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Adonin, S.A., Petrov, M.D., Novikov, A.S. et al. 2-Chlorobenzoate Complex of Cu(II): Unexpected Appearance of Halogen···Halogen Contacts in Solid State. J Clust Sci 30, 857–861 (2019). https://doi.org/10.1007/s10876-019-01574-z

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