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Two α2-Monozirconium-Substituted Dimeric Silicotungstates: Hydrothermal Synthesis, Structural Characterization and Catalytic Oxidation of Thioethers

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Abstract

A novel di-ZrIV-substituted sandwich-type silicotungstate (NH4)2(TMA)6[Zr2(μ-OH)2(α-HSiW11O39)2]·18H2O (1, TMA = tetramethylammonium) and a previously unknown EDTA bridging mono-ZrIV-substituted silicotungstate dimeric cluster (NH4)2(TMA)6[(Zr2EDTA)(α-HSiW11O39)2]·26H2O (2, EDTA = C10H14N2O8) have been synthesized under mild hydrothermal conditions and characterized by FTIR spectroscopy, elemental analysis, thermogravimetric analysis, single-crystal and powder X-ray diffraction. 1 and 2 contain a centrosymmetric polyoxoanion structures with two [α-SiW11O39]8− units sandwiching a [Zr2(μ-OH)2]6+ cluster and [Zr2EDTA]6+ moiety, respectively. The catalytic activities of 1 and 2 on oxygenation of thioethers by H2O2 were evaluated, showing that both 1 and 2 are excellent catalysts for the catalytic oxidation of thioethers to sulfoxides/sulfones.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 21571016 and 91122028) and the NSFC for Distinguished Young Scholars (No. 20725101).

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  1. MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

    Yue-Lin Wang & Guo-Yu Yang

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  1. Yue-Lin Wang
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  2. Guo-Yu Yang
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Correspondence to Guo-Yu Yang.

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Wang, YL., Yang, GY. Two α2-Monozirconium-Substituted Dimeric Silicotungstates: Hydrothermal Synthesis, Structural Characterization and Catalytic Oxidation of Thioethers. J Clust Sci 30, 1115–1121 (2019). https://doi.org/10.1007/s10876-019-01572-1

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