Skip to main content
SpringerLink
Log in

Synthesis, Structure and Magnetic Properties of a Fe(III) [24-azaMC-8] Azametallacrown Nanocluster with Diacylhydrazine Ligand

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

A novel Fe(III) cluster formulated as [\({\text{Fe}}^{\text{III}}_{8}\)(schhz)4(Py)6(H2O)2]∙2H2O (1) was synthesized by the hydrothermal reaction of FeCl2 and a symmetrical diacylhydrazine ligand N,N′-bissalicyl-1,3-cyclohexanedicarbohydrazide (H6schhz) in the presence of pyridine (Py) and pyrazine (Pz). It displays a nano-sized [24-MC-8] azametallacrown (azaMC) structure that eight Fe(III) ions are linked together by N–N bridges from four schhz6− ligands. To the best of our knowledge, it is the second case of Fe(III) [24-MC-8] azaMC up to now. The magnetic investigations reveal that the N–N bridges convey antiferromagnetic couplings between the Fe(III) centers in the system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. G. R. C. Hamilton, S. K. Sahoo, S. Kamila, N. Singh, N. Kaur, B. W. Hyland, and J. F. Callan (2015). Chem. Soc. Rev. 44, 4415.

    Article  CAS  PubMed  Google Scholar 

  2. P. Happ, C. Plenk, E. Rentschler (2015). Coord. Chem. Rev. 289, 238.

    Article  CAS  Google Scholar 

  3. M. Ostrowska, I. O. Fritsky, E. Gumienna-Kontecka, A. V. Pavlishchuk (2016). Coord. Chem. Rev. 327, 304.

    Article  CAS  Google Scholar 

  4. A. C. Jahnke, K. Proepper, C. Bronner, J. Teichgraeber, S. Dechert, M. John, O. S. Wenger, F. Meyer, and J. Am (2012). Chem. Soc. 134, 2938.

    Article  CAS  Google Scholar 

  5. J. J. Bodwin, A. D. Cutland, R. G. Malkani, and V. L. Pecoraro (2001). Coord. Chem. Rev. 489, 216.

    Google Scholar 

  6. B. Kwak, H. Rhee, and M. S. Lah (1998). Inorg. Chem. 37, 3599.

    Article  CAS  PubMed  Google Scholar 

  7. S. Wang, L. Q. Kong, H. Yang, Z. T. He, Z. Jiang, D. C. Li, S. Y. Zeng, M. J. Niu, Y. Song, and J. M. Dou (2011). Inorg. Chem. 50, 2705.

    Article  CAS  PubMed  Google Scholar 

  8. C. Atzeri, V. Marzaroli, M. Quaretti, J. R. Travis, L. D. Bari, C. M. Zaleski, and M. Tegoni (2017). Inorg. Chem. 56, 8257.

    Article  CAS  PubMed  Google Scholar 

  9. C. S. Lim, M. Tegoni, T. Jakusch, J. W. Kampf, and V. L. Pecoraro (2012). Inorg. Chem. 51, 11533.

    Article  CAS  PubMed  Google Scholar 

  10. L. F. Jin, H. Yu, S. X. Wu, F. P. Xiao (2009). Dalton Trans. 1, 197.

    Article  Google Scholar 

  11. H. Yang, Q. X. Yao, Y. W. Li, D. C. Li, and J. M. Dou (2014). Dalton Trans. 43, 16986.

    Article  CAS  PubMed  Google Scholar 

  12. S. Lin, S. X. Liu, Z. Chen, B. Z. Lin, and S. Gao (2004). Inorg. Chem. 43, 2222.

    Article  CAS  PubMed  Google Scholar 

  13. R. P. John, K. Lee, B. J. Kim, B. J. Suh, H. Rhee, and M. S. Lah (2005). Inorg. Chem. 44, 7109.

    Article  CAS  PubMed  Google Scholar 

  14. X. Liu, W. Liu, K. Lee, M. Park, H. C. Ri, G. H. Kim, M. S. Lah (2008). Dalton Trans. 46, 6579.

    Article  CAS  Google Scholar 

  15. W. Liu, K. Lee, M. Park, R. P. John, D. Moon, Y. Zou, X. Liu, H. C. Ri, G. H. Kim, and M. S. Lah (2008). Inorg. Chem. 47, 8807.

    Article  CAS  PubMed  Google Scholar 

  16. J. L. Pan, Q. Guo, B. Yang, Y. Y. Li, J. G. Cao, X. G. Meng, and F. P. Xiao (2016). CrystEngComm. 18, 6143.

    Article  CAS  Google Scholar 

  17. S. X. Liu, S. Lin, B. Z. Lin, C. C. Lin, and J. Q. Huang (2001). Angew. Chem. Int. Ed. 40, 1084.

    Article  CAS  Google Scholar 

  18. J. M. Dou, M. L. Liu, D. C. Li, D. Q. Wang (2006). Eur. J. Inorg. Chem. 23, 4866.

    Article  CAS  Google Scholar 

  19. K. Wang, Z. L. Chen, H. H. Zou, S. H. Zhang, Y. Li, X. Q. Zhang, W. Y. Sun, and F. P. Liang (2018). Dalton Trans. 47, 2337.

    Article  CAS  PubMed  Google Scholar 

  20. K. Wang, Z. L. Chen, H. H. Zou, K. Hu, H. Y. Li, Z. Zhang, W. Y. Sun, and F. P. Liang (2016). Chem. Commun. 52, 8297.

    Article  CAS  Google Scholar 

  21. Z. L. Chen, Y. L. Shen, L. L. Li, H. H. Zou, X. X. Fu, Z. Y. Liu, K. Wang, and F. P. Liang (2017). Dalton Trans. 46, 15032.

    Article  CAS  PubMed  Google Scholar 

  22. K. Wang, S. Tang, Z. B. Hu, H. H. Zou, X. L. Wang, S. H. Zhang, Y. Li, Z. L. Chen, and F. P. Liang (2018). RSC Adv. 8, 6218.

    Article  CAS  Google Scholar 

  23. G. M. Sheldrick SHELX-2014: Programs for Crystal Structure Analysis (University of Göttingen, Göttingen, 2014).

    Google Scholar 

  24. G. M. Sheldrick (2015). Acta Crystallogr. 71, 3.

    Google Scholar 

  25. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann (2009). J. Appl. Crystallogr. 42, 339.

    Article  CAS  Google Scholar 

  26. L. J. Bourhis, O. V. Dolomanov, R. J. Gildea, J. A. K. Howard, and H. Puschmann (2015). Acta Crystallogr. 71, 59.

    CAS  Google Scholar 

  27. A. L. Spek (2015). Acta Crystallogr. 71, 9.

    CAS  Google Scholar 

  28. J. Goura, P. Bag, V. Mereacre, A. K. Powell, and V. Chandrasekhar (2015). Inorg. Chem. 53, 8147.

    Article  CAS  Google Scholar 

  29. Y. Y. Zhu, T. T. Yin, S. D. Jiang, A. L. Barra, W. Wernsdorfer, P. Neugebauer, R. Marx, M. Dörfel, B. W. Wang, Z. Q. Wu, J. Slageren, and S. Gao (2014). Chem. Commun. 50, 5090.

    Google Scholar 

  30. M. Llunell, D. Casanova, J. Cirera, P. Alemany, S. Alvarez (2013). SHAPE, Version 2.1. Department of Chemistry, University of Barcelona.

  31. N. Ahmed, A. Upadhyay, T. Rajeshkumar, S. Vaidya, J. Schnack, G. Rajaraman, and M. Shanmugam (2015). Dalton Trans. 44, 18743.

    Article  CAS  PubMed  Google Scholar 

  32. O. L. Sydora, P. T. Wolczanski, and E. B. Lobkovsky (2003). Angew. Chem. Int. Ed. 42, 2685.

    Article  CAS  Google Scholar 

  33. K. L. Taft, C. D. Delfs, G. C. Papaefthymiou, S. Foner, D. Gatteschi, and S. J. Lippard (1984). J. Am. Chem Soc. 116, 823.

    Article  Google Scholar 

  34. O. Botezat, J. van Leusen, P. Kögerler, and S. G. Bac (2018). Inorg. Chem. 57, 7904.

    Article  CAS  PubMed  Google Scholar 

  35. S. J. Liu, S. D. Han, J. M. Jia, L. Xue, Y. Cui, S. M. Zhang, and Z. Chang (2014). CrystEngComm. 16, 5212.

    Article  CAS  Google Scholar 

  36. N. F. Chilton, R. P. Anderson, L. D. Turner, A. Soncini, and K. S. Murray (2013). J. Comput. Chem. 34, 1164.

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 21771043 and 51572050), the Guangxi Natural Science Foundation (No. 2018GXNSFAA138123) and the Program of the Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi (No. GXYSXTZX2017-II-3).

Author information

Author notes

  1. Sen-Da Su and Xiao-Ming Ou-Yang have contributed equally to this work.

Authors and Affiliations

  1. Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, China

    Sen-Da Su, Xiao-Ming Ou-Yang, Ke-Ke Guo, Yan Li, Kai Wang, Shu-Ying Luo & Fu-Pei Liang

  2. State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, China

    Qing-Mei Lin

Authors
  1. Sen-Da Su
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xiao-Ming Ou-Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ke-Ke Guo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Qing-Mei Lin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yan Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Kai Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Shu-Ying Luo
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Fu-Pei Liang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Kai Wang, Shu-Ying Luo or Fu-Pei Liang.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Electronic supplementary material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Su, SD., Ou-Yang, XM., Guo, KK. et al. Synthesis, Structure and Magnetic Properties of a Fe(III) [24-azaMC-8] Azametallacrown Nanocluster with Diacylhydrazine Ligand. J Clust Sci 30, 863–868 (2019). https://doi.org/10.1007/s10876-019-01545-4

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-019-01545-4

Keywords

Search

Navigation