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RETRACTED ARTICLE: A Bifunctional Metal–Organic Framework Based on Linear Trinuclear Clusters for Solvent-Free Aldehyde Cyanosilylation and Growth Inhibition of Human Breast Cancer Cells

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This article was retracted on 29 January 2024

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Abstract

By using a rigid Y-shaped biphenyl-3,4′,5-tricarboxylic acid (H3bpt) organic ligand, a new cluster-based metal-organic framework (MOF) with the chemical formula of {[Cu3(bpt)2(H2O)4](DMA)(MeOH)2}n (1, DMA = N,N-dimethylacetamide) was synthesized under solvothermal condition. The structure of 1 was determined by single-crystal X-ray diffraction analyses (SCXRD) and further characterized by elemental analyses, IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric (TG) analyses and gas sorption measurements. The SCXRD result reveals that complex 1 exhibits a 3D framework with 1D channels which contains opposite-handedness helical chains based on the trinuclear Cu(II) clusters. Considering its high pore volume and accessible open metal sites, complex 1 as well as its activated form (1a) was studied for cyanosilylation of aldehydes under solvent-free conditions, which reveals that 1a shows much better catalytic performance than that of 1, indicating the open metal sites play important roles in the catalytic process. Furthermore, the anticancer activates of complex 1 and 1a has been evaluated on three human breast cancer cells (MDA-MB-231, MDA-MB-468 and Hst578) via the MTT assay.

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Authors and Affiliations

  1. Department of Oncology, The First Affiliated Hospital of Zhengzhou University, Zhengzhou, 450052, China

    Zhi-Jun Ma & Shih-Hsin Lu

  2. Cancer Institute and Hospital, Chinese Academy of Medical Sciences, Beijing, 100021, China

    Shih-Hsin Lu

Authors
  1. Zhi-Jun Ma
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  2. Shih-Hsin Lu
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Correspondence to Shih-Hsin Lu.

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This article has been retracted. Please see the retraction notice for more detail: https://doi.org/10.1007/s10876-024-02543-x

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Ma, ZJ., Lu, SH. RETRACTED ARTICLE: A Bifunctional Metal–Organic Framework Based on Linear Trinuclear Clusters for Solvent-Free Aldehyde Cyanosilylation and Growth Inhibition of Human Breast Cancer Cells. J Clust Sci 30, 243–249 (2019). https://doi.org/10.1007/s10876-018-1483-2

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  • DOI: https://doi.org/10.1007/s10876-018-1483-2

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